Composition of bottom sediments, rocks, and ores from the Tropical Atlantic

Geological features of some areas of the Tropical Atlantic (stratigraphy, tectonic structure, lithology, distribution of ore components in bottom sediments, petrography of bedrocks, etc.) are under consideration in the book. Regularities of concentration of trace elements in iron-manganese nodules, features of these nodules in bottom sediments, distribution of phosphorite nodules and other phosphorites have been studied. Much attention is paid to rocks of the ocean crust. A wide range of mineralization represented by magnetite, chromite, chalcopyrite, pyrite, pentlandite, and other minerals has been found.

Geochemistry of sediments cores in the Mediterranean Sea

We investigated five time-equivalent core sections (180-110 kyr BP) from the Balearic Sea (Menorca Rise), the easternmost Levantine Basin and southwest, south, and southeast of Crete to reconstruct spatial patterns of productivity during deposition of sapropels S5 and S6 in the Mediterranean Sea. Our indicators are Ba, total organic carbon and carbonate contents. We found no indications of Ba remobilization within the investigated core intervals, and used the accumulation rate of biogenic Ba to compute paleoproductivity. Maximum surface water productivity (up to 350 g C/m2/yr) was found during deposition of S5 (isotope stage 5e) but pronounced spatial variability is evident. Coeval sediment intervals in the Balearic Sea show very little productivity change, suggesting that chemical and biological environments in the eastern and western Mediterranean basins were decoupled in this interval. We interpret the spatial variability as the result of two different modes of nutrient delivery to the photic zone: riverderived nutrient input and shoaling of the pycnocline/nutricline to the photic zone. The productivity increase during the formation of S6 was moderate compared to S5 and had a less marked spatial variability within the study area of the eastern Mediterranean Sea. Given that S6 formed during a glacial interval, glacial boundary conditions such as high wind stress and/or cooler surface water temperatures apparently favored lateral and vertical mixing and prevented the development of the spatial gradients within the Eastern Mediterranean Sea (EMS) observed for S5. A non-sapropel sediment interval with elevated Ba content and depleted 18O/16O ratios in planktonic foraminifer calcite was detected between S6 and S5 that corresponds to the weak northern hemisphere insolation maximum at 150 kyr. At this time, productivity apparently increased up to five times over surrounding intervals, but abundant benthic fauna show that the deep water remained oxic. Following our interpretation, the interval denotes a failed sapropel, when a weaker monsoon did not force the EMS into permanent stratification. The comparison of interglacial and glacial sapropels illustrates the relevance of climatic boundary conditions in the northern catchment in determining the facies and spatial variability of sapropels within the EMS.

Calcium isotope ratios of pore fluids and solid phase of organic rich sediments

Pore fluid calcium isotope, calcium concentration and strontium concentration data are used to measure the rates of diagenetic dissolution and precipitation of calcite in deep-sea sediments containing abundant clay and organic material. This type of study of deep-sea sediment diagenesis provides unique information about the ultra-slow chemical reactions that occur in natural marine sediments that affect global geochemical cycles and the preservation of paleo-environmental information in carbonate fossils. For this study, calcium isotope ratios (d44/40Ca) of pore fluid calcium from Ocean Drilling Program (ODP) Sites 984 (North Atlantic) and 1082 (off the coast of West Africa) were measured to augment available pore fluid measurements of calcium and strontium concentration. Both study sites have high sedimentation rates and support quantitative sulfate reduction, methanogenesis and anaerobic methane oxidation. The pattern of change of d44/40Ca of pore fluid calcium versus depth at Sites 984 and 1082 differs markedly from that of previously studied deep-sea Sites like 590B and 807, which are composed of nearly pure carbonate sediment. In the 984 and 1082 pore fluids, d44/40Ca remains elevated near seawater values deep in the sediments, rather than shifting rapidly toward the d44/40Ca of carbonate solids. This observation indicates that the rate of calcite dissolution is far lower than at previously studied carbonate-rich sites. The data are fit using a numerical model, as well as more approximate analytical models, to estimate the rates of carbonate dissolution and precipitation and the relationship of these rates to the abundance of clay and organic material. Our models give mutually consistent results and indicate that calcite dissolution rates at Sites 984 and 1082 are roughly two orders of magnitude lower than at previously studied carbonate-rich sites, and the rate correlates with the abundance of clay. Our calculated rates are conservative for these sites (the actual rates could be significantly slower) because other processes that impact the calcium isotope composition of sedimentary pore fluid have not been included. The results provide direct geochemical evidence for the anecdotal observation that the best-preserved carbonate fossils are often found in clay or organic-rich sedimentary horizons. The results also suggest that the presence of clay minerals has a strong passivating effect on the surfaces of biogenic carbonate minerals, slowing dissolution dramatically even in relation to the already-slow rates typical of carbonate-rich sediments.

Bulk chemical analysis of sediments ODP Hole 110-671B and 110-672A

Chemical analyses for calcium carbonate, organic carbon, and major constituents (Al, Ti, Ca, Mg, K, Fe) of bulk sediments collected in Hole 671B have been carried out. Organic carbon contents in Pleistocene through middle Miocene sediments above the zone of decollement are very low (<0.1%); below the decollement considerably higher concentrations of organic carbon occur (up to 1 %). Changes in Ti/Al and Fe/Al ratios are minor, but K/Al and Mg/Al ratios show clear trends with the age of the sediments. Preliminary comparisons of these ratios with mineralogic information on clays indicate good correspondence with clay abundances. Calculations of the mass flux of magnesium from the overlying ocean into the pore fluids suggest that addition of magnesium to the sediments is difficult to detect, especially in the absence of a background reference concentration.

Seawater carbonate chemistry, growth rate and processes during experiments with Coccolithus pelagicus and Calcidiscus leptoporus, 2006

Uptake of half of the fossil fuel CO2 into the ocean causes gradual seawater acidification. This has been shown to slow down calcification of major calcifying groups, such as corals, foraminifera, and coccolithophores. Here we show that two of the most productive marine calcifying species, the coccolithophores Coccolithus pelagicus and Calcidiscus leptoporus, do not follow the CO2-related calcification response previously found. In batch culture experiments, particulate inorganic carbon (PIC) of C. leptoporus changes with increasing CO2 concentration in a nonlinear relationship. A PIC optimum curve is obtained, with a maximum value at present-day surface ocean pCO2 levels (?360 ppm CO2). With particulate organic carbon (POC) remaining constant over the range of CO2 concentrations, the PIC/POC ratio also shows an optimum curve. In the C. pelagicus cultures, neither PIC nor POC changes significantly over the CO2 range tested, yielding a stable PIC/POC ratio. Since growth rate in both species did not change with pCO2, POC and PIC production show the same pattern as POC and PIC. The two investigated species respond differently to changes in the seawater carbonate chemistry, highlighting the need to consider species-specific effects when evaluating whole ecosystem responses. Changes of calcification rate (PIC production) were highly correlated to changes in coccolith morphology. Since our experimental results suggest altered coccolith morphology (at least in the case of C. leptoporus) in the geological past, coccoliths originating from sedimentary records of periods with different CO2 levels were analyzed. Analysis of sediment samples was performed on six cores obtained from locations well above the lysocline and covering a range of latitudes throughout the Atlantic Ocean. Scanning electron micrograph analysis of coccolith morphologies did not reveal any evidence for significant numbers of incomplete or malformed coccoliths of C. pelagicus and C. leptoporus in last glacial maximum and Holocene sediments. The discrepancy between experimental and geological results might be explained by adaptation to changing carbonate chemistry.

Sediment grain size and carbon/carbonate at DSDO Leg 55 Holes

CaCO3 content was determined on board ship by the "Karbonat Bomb" technique (Müller and Gastner, 1971). In this simple procedure, a sample is powdered and treated with HCl in a closed cylinder. Any resulting CO2 pressure is proportional to the CaCO3 content of the sample. Application of the calibration factor to the manometer reading (x 100) yields per cent CaCO3. The error can be as low as 1 per cent for sediments high in CaCO3, and in general an accuracy of ±2 to 5 per cent can be obtained.

Seawater carbonate chemistry and processes during experiments with Emiliania huxleyi (PML B93/11A)

The formation of calcareous skeletons by marine planktonic organisms and their subsequent sinking to depth generates a continuous rain of calcium carbonate to the deep ocean and underlying sediments. This is important in regulating marine carbon cycling and ocean-atmosphere CO2 exchange. The present rise in atmospheric CO2 levels causes significant changes in surface ocean pH and carbonate chemistry. Such changes have been shown to slow down calcification in corals and coralline macroalgae, but the majority of marine calcification occurs in planktonic organisms. Here we report reduced calcite production at increased CO2 concentrations in monospecific cultures of two dominant marine calcifying phytoplankton species, the coccolithophorids Emiliania huxleyi and Gephyrocapsa oceanica . This was accompanied by an increased proportion of malformed coccoliths and incomplete coccospheres. Diminished calcification led to a reduction in the ratio of calcite precipitation to organic matter production. Similar results were obtained in incubations of natural plankton assemblages from the north Pacific ocean when exposed to experimentally elevated CO2 levels. We suggest that the progressive increase in atmospheric CO2 concentrations may therefore slow down the production of calcium carbonate in the surface ocean. As the process of calcification releases CO2 to the atmosphere, the response observed here could potentially act as a negative feedback on atmospheric CO2 levels.

Uranium and radioactive isotopes in bottom sediments and Fe-Mn nodules and crusts of seas and oceans

The main stages of the sedimentary cycle of uranium in modern marine basins are under consideration in the book. Annually about 18 thousand tons of dissolved and suspended uranium enters the ocean with river runoff. Depending on a type of a marine basin uranium accumulated either in sediments of deep-sea basins, or in sediments of continental shelves and slopes. In the surface layer of marine sediments hydrogenic uranium is predominantly bound with organic matter, and in ocean sediments also with iron, manganese and phosphorus. In diagenetic processes there occurs partial redistribution of uranium in sediments, as well as its concentration in iron-manganese, phosphate and carbonate nodules and biogenic phosphate detritus. Concentration of uranium in marine sediments of various types depending on their composition, as well as on forms of its entering, degree of differentiation and of sedimentation rates, on hydrochemical regime and water circulation, and on intensity of diagenetic processes.

Chemical and isotopic compositions of authigenic carbonates from bottom sediments of Northwest Pacific marginal seas

The paper presents data on authigenic carbonate distribution in Holocene - Upper Pleistocene deposits of the Okhotsk, Japan, East China, Philippine and South China Seas. Description of carbonate samples, their chemical and isotope compositions are given. Chemical analysis of the samples indicates that almost all authigenic carbonates are composed of calcite or magnesian calcite; and only in one case, of siderite. Oxygen isotopic composition (d18O) ranges from +37.7 to +26.1 per mil (SMOW); it is, probably, connected with different temperatures of carbonate formation. A distinct geographic regularity is traced. Decrease in d18O values is observed from the cold Okhotsk Sea to the warm South China Sea. A very wide range of carbon isotopic composition (d13C from -42 to +3.8 per mil) indicates different sources of carbonic acid required for formation of these carbonates. As a basis for carbon isotopic composition we can distinguish three sources of carbonic acid in the studied sediments: microbiological methane oxidation, organic matter destruction during sediment diagenesis, and dissolved organogenic limestone. Thus, formation of authigenic carbonates in sediments from the marginal seas of the Northwest Pacific results from: 1) sediment diagenesis, 2) methane oxidation in zones of gas anomalies, 3) their precipitation from the supersaturated by carbonates sea shoal waters of tropical sea lagoons.

Benthic foraminifera in Northwest Indian Ocean surface sediments

The relationship between the distribution of benthic foraminifera and sediment type and depositional environment in the Arabian Sea is discussed. The benthic foraminiferal fauna were sampled in nineteen Recent surface sediment samples, and geochemical variables of the sediment of the same samples were measured. The water depths for the box core samples varies from 440 to 4040 m. A total of 103 species and six species-complexes were identified. The geochemical properties were found to correspond well to the sediment type and depositional environment and six different sediment/depositional environment types could be distinguished. Analysis of the benthic foraminiferal fauna reveals specific faunal assemblages that are closely related to these sediment/depositional environment types.

Empirical Evidence Reveals Seasonally Dependent Reduction in Nitrification in Coastal Sediments Subjected to Near Future Ocean Acidification

Research so far has provided little evidence that benthic biogeochemical cycling is affected by ocean acidification under realistic climate change scenarios. We measured nutrient exchange and sediment community oxygen consumption (SCOC) rates to estimate nitrification in natural coastal permeable and fine sandy sediments under pre-phytoplankton bloom and bloom conditions. Ocean acidification, as mimicked in the laboratory by a realistic pH decrease of 0.3, significantly reduced SCOC on average by 60% and benthic nitrification rates on average by 94% in both sediment types in February (pre-bloom period), but not in April (bloom period). No changes in macrofauna functional community (density, structural and functional diversity) were observed between ambient and acidified conditions, suggesting that changes in benthic biogeochemical cycling were predominantly mediated by changes in the activity of the microbial community during the short-term incubations (14 days), rather than by changes in engineering effects of bioturbating and bio-irrigating macrofauna. As benthic nitrification makes up the gross of ocean nitrification, a slowdown of this nitrogen cycling pathway in both permeable and fine sediments in winter, could therefore have global impacts on coupled nitrification-denitrification and hence eventually on pelagic nutrient availability.

Calcareous nannofossil abundance and datums of ODP Hole 194-1193A sediments, Marion Plateau, Australia

During Leg 194, a series of eight sites was drilled through Oligocene-Holocene mixed carbonate and siliciclastic sediments on the Marion Plateau, northeast Australia. The major objective was to constrain the magnitude and timing of sea level changes in the Miocene. Site 1193, located on the Marion Plateau in 348 m of water ~80 km from the south central Great Barrier Reef margin, is probably the most important site for constraining the major middle to late Miocene sea level drop and reconstructing the evolution history of the Marion Plateau during the Miocene (Isern, Anselmetti, Blum, et al., 2002, doi:10.2973/odp.proc.ir.194.2002). However, there is no biostratigraphic or other chronological data for the critical interval between 36 and 211 meters below seafloor (mbsf) (virtually the entire late and middle Miocene) due to poor core recovery and a virtual absence of planktonic microfossils in the core catcher samples examined aboard the ship (Isern, Anselmetti, Blum, et al., 2002, doi:10.2973/odp.proc.ir.194.2002). The main purpose of this report is to refine the shipboard nannofossil biostratigraphy through examination of new samples and more detailed examination of those samples reported on board the ship. This results in a refinement for most of the nannofossil datums and provides some useful age information to fill the critical data gap for the middle Miocene. Previous Neogene nannofossil biostratigraphic studies of the Marion Plateau and Queensland Plateau include Gartner et al. (1993, doi:10.2973/odp.proc.sr.133.213.1993) and Wei and Gartner (1993, doi:10.2973/odp.proc.sr.133.216.1993).

Geochemistry and granulometry of sediments obtained during R/V Professor Logachev cruise PL28, Mid Atlantic Ridge

The lithological-facies, biostratigraphic, and geochemical studies of ore-bearing and metalliferous sediments were carried out using original material from six cores taken in the MAR 16°38' N area during 28th Cruise of the R/V Professor Logachev.

Composition of bottom sediments and serpentinites from Core PS-846

A core of foraminiferal-coccolithic oozes filling a valley of the transform fault located at 29°40'S on the South Atlantic Ridge contains layers composed of angular fragments of igneous and metamorphic rocks. They include many serpentinites deriving from serpentinized ultrabasic rocks, probably exposed on the lower section of the southern slope of the fault valley. A mineral and chemical description of these serpentinites is given.