Diagenetic dolomite formation in Quaternary anoxic diatomaceous muds at DSDP Leg 64 Holes

During drilling in the Gulf of California, diagenetic carbonate rocks were recovered at 7 out of 8 sites. These are primarily dolomites which record 13C isotopic evidence of the incorporation of carbon derived from the decomposition of organic matter. In Hole 479, drilled to a sub-bottom depth of 440 meters on the Guaymas Slope, under a fertile upwelling belt, we recognized an excellent example of deep sea dolomitization in progress. This Quaternary section of organic-carbon- rich, low-carbonate, hemipelagic diatomaceous oozes contains numerous fine-grained, decimeter-thin, episodic beds of dolomite, which show sedimentologic, geochemical, and isotopic evidence of accretion by precipitation below 40 meters sub-bottom in zones of high alkalinity and low sulfate. The beds preserve original sedimentary structures. Carbon-13 varies from +3 to +14 per mil, indicating biogenic CO2 reservoirs related to active methanogenesis. In single beds, 18O values range outwardly from +5 to -7 per mil, reflecting increasing temperature with progressive accretion of dolomite with depth; the values parallel progressive trends in lithification, texture, mineralogy, and fossil preservation. We estimate slow accretion rates on the order of 0.1-0.7 mm/10**3 yr. with burial. Dolomitization does not proceed merely at the expense of nearby nannofossils. Ca and Mg ions must be derived from interstitial waters. The episodic appearance of beds in the sequence seems partly a reflection of latent climate signals. This process of deep sea dolomitization carries implications for hydrocarbon migration, as well as an interpretation of the presence of dolomite in other modern and ancient pelagic to hemipelagic sediment sequences.

Past circulation along the western Iberian margin

Fifteen Iberian margin sediment cores, distributed between 43°12'N and 35°53'N, have been used to reconstruct spatial and temporal (sub)surface circulation along the Iberian margin since the Last Glacial period. Time-slice maps of planktonic foraminiferal derived summer sea surface temperature (SST) and export productivity (Pexp) were established for specific time intervals within the last 35 ky: the Holocene (Recent and last 8 ky), Younger Dryas (YD), Heinrich Stadials (HS) 1, 2a, 2b, 3, and the Last Glacial Maximum (LGM). The SST during the Holocene shows the same latitudinal gradient along the western Iberian margin as present-day with cold but productive areas that reflect the influence of coastal upwelling centers. The LGM appears as a slightly less warm, but more productive period relative to the Holocene and present-day conditions, suggesting that sea-level minima forced a westward displacement of the coastal upwelling centers possibly accompanied by a strengthening of northward winds. During the YD, a longitudinal thermal front is depicted at 10°W, with cold polar waters offshore and warmer subtropical waters inshore, suggesting that the subtropical Paleo-Iberian Poleward Current more likely flowed at a more inshore location masking the local SST signal and amplitude of variation. A substantial cooling and drop in productivity is observed during all HS, in particular HS1 and HS3, reflecting the penetration of icebergs-derived meltwater. These most extreme southward extensions of very cold waters define a strong SST gradient that marks a possible Paleo-Azores Front. Higher production south of this front was likely fed by frontal nutrient advection.

Occurrence of Selenopemphix undulata sp. nov in late Quaternary sediments of the Pacific Ocean

Detailed palynological studies in the northeast (NE) Pacific, Strait of Georgia (BC, Canada), southeast (SE) Pacific and northwest Pacific (Dongdo Bay, South Korea) resulted in the recognition of the new dinoflagellate cyst species Selenopemphix undulata sp. nov. This species is restricted to cool temperate to sub-polar climate zones, where it is found in highest relative abundances in highly productive non- to reduced upwelling regions with an annual mean sea-surface temperature (aSST) below 16 °C and an annual mean sea-surface salinity (aSSS) between 20 and 35 psu. Those observations are in agreement with the late Quaternary fossil records from Santa Barbara Basin (ODP 893; 34°N) and offshore Chile (ODP 1233; 41°S), where this species thrived during the last glacial. This period was characterised by high nutrient availability and the absence of species favouring upwelling conditions. The indirect dependence of S. undulata sp. nov. abundances on nutrient availability during reduced or non-upwelling periods is expressed by the synchronous fluctuations with diatom abundances, since the distribution and growth rates of the latter are directly related with the availability of macronutrients in the surface waters.

Planktonic foraminiferas in bottom sediments and Late Quaternary paleotemperatures of surface waters in the North Tropical Atlantic

Distribution of planktonic foraminiferal tests was studied in 15 Upper Quaternary sediment cores from the continental slope of Africa, the Canary and Cape Verde basins, and slopes of the Mid-Atlantic Ridge. In all the cores substantial variations were found in relationship between foraminiferal planktonic species reflecting fluctuations of mean annual temperatures of surface waters. Temperature difference in temperatures between present time and that of the maximum of the stadial of the last continental glaciation glacial stadial (about 18,000 yrs ago) ranges from 8.5°C in the Canary upwelling region to minimum values of 2.0°C in the central part of the ocean, i.e. the southern part of the subtropical gyre. Temperature difference the Holocene optimum and 18,000 yrs ago ranges from 10°C to 3°C. Age estimates are supported by radiocarbon dates.

Eocene to Quaternary planktonic foraminifers from the Northwest Pacific

Eocene through Quaternary planktonic foraminifers were identified in cores recovered during Leg 126. Turbidites and volcanic ash beds are intercalated with hemipelagic sediments. Preservation of foraminifers is variable, ranging from excellent to poor and appears to have been affected by fluctuations in the carbonate compensation depth (CCD), depth of burial, changes in bottom water temperature, current velocity, sediment accumulation rates and seafloor topography. Preservation of foraminifers in Quaternary sediments is generally good, however, species abundance varies by a factor of I05-106 and reflects dilution by volcanogenic as well as terrigenous constituents and cannot be used for paleoceanographic reconstructions. In pre-Quaternary deposits planktonic foraminiferal tests frequently exhibit dissolution effects; biostratigraphic zonation and placement of zonal boundaries is difficult owing to hiatuses, dissolution facies, extraneously deposited sediments, and discontinuous coring. The Eocene foraminiferal faunas include specimens of the Globorotalia cerroazulensis plexus, markers of Zone P16 as well as Globigerina senni and Globigerinatheka spp., which became extinct before the end of the Eocene. Six hiatuses and/or dissolution periods, probably reflecting global cooling events and/or changes in oceanic circulation patterns were recorded at Site 792. Recrystallized, poorly preserved, possibly reworked Eocene species (Globigerina senni and Globigerapsis sp.) were recorded in sediments at Site 793.

Quaternary through early Eocene benthic foraminifera off Peru

Stratigraphic assemblages of Quaternary through early Eocene benthic foraminifers were recovered among 10 Peru margin drill sites. Various hiatuses and intervals barren in foraminifers characterize the sections, but numerous samples contain abundant, well-preserved benthic foraminifers. Bathymetry of the extant species and California-based estimates of the paleobathymetry of the extinct species permit recognition of Quaternary sea-level fluctuations between shelf and upper bathyal depths that produced vertical migrations of oxygenated and low-oxygen habitats at the six shallow sites. Assemblages from lower-slope sites at about 9° and 11°S indicate a general subsidence of the continental margin from shelf or upper bathyal depths in Eocene time to the present lower bathyal depths. Data from 11°S suggest a major part of this subsidence occurred in late Oligocene to early Miocene time. Downslope-transported shelf specimens, particularly the small biserial species, Bolivina costata and B. vaughani, are major contributors to these lower bathyal assemblages from the middle Miocene through Quaternary time.

Sediments in Arctic sea ice

Despite the Arctic sea ice cover's recognized sensitivity to environmental change, the role of sediment inclusions in lowering ice albedo and affecting ice ablation is poorly understood. Sea ice sediment inclusions were studied in the central Arctic Ocean during the Arctic 91 expedition and in the Laptev Sea (East Siberian Arctic Region Expedition 1992). Results from these investigations are here combined with previous studies performed in major areas of ice ablation and the southern central Arctic Ocean. This study documents the regional distribution and composition of particle-laden ice, investigates and evaluates processes by which sediment is incorporated into the ice cover, and identifies transport paths and probable depositional centers for the released sediment. In April 1992, sea ice in the Laptev Sea was relatively clean. The sediment occasionally observed was distributed diffusely over the entire ice column, forming turbid ice. Observations indicate that frazil and anchor ice formation occurring in a large coastal polynya provide a main mechanism for sediment entrainment. In the central Arctic Ocean sediments are concentrated in layers within or at the surface of ice floes due to melting and refreezing processes. The surface sediment accumulation in central Arctic multi-year sea ice exceeds by far the amounts observed in first-year ice from the Laptev Sea in April 1992. Sea ice sediments are generally fine grained, although coarse sediments and stones up to 5 cm in diameter are observed. Component analysis indicates that quartz and clay minerals are the main terrigenous sediment particles. The biogenous components, namely shells of pelecypods and benthic foraminiferal tests, point to a shallow, benthic, marine source area. Apparently, sediment inclusions were resuspended from shelf areas before and incorporated into the sea ice by suspension freezing. Clay mineralogy of ice-rafted sediments provides information on potential source areas. A smectite maximum in sea ice sediment samples repeatedly occurred between 81°N and 83°N along the Arctic 91 transect, indicating a rather stable and narrow smectite rich ice drift stream of the Transpolar Drift. The smectite concentrations are comparable to those found in both Laptev Sea shelf sediments and anchor ice sediments, pointing to this sea as a potential source area for sea ice sediments. In the central Arctic Ocean sea ice clay mineralogy is significantly different from deep-sea clay mineral distribution patterns. The contribution of sea ice sediments to the deep sea is apparently diluted by sedimentary material provided by other transport mechanisms.

Quaternary surface-water stable isotope signal from calcareous nannofossils at DSDP Site 90-593, South Tasman Sea

Oxygen isotope values from calcareous nannofossils in four cores spanning the Quaternary from DSDP Site 593 in Tasman Sea are compared with the delta18O signal of planktonic and benthic foraminifers from the same samples. The classic mid-late Quaternary isotope stages are exhibited with stage 12 particularly well developed. When delta18O values of nannofossils are adjusted for coccolithophore vital effects they indicate larger (by 1-6°C) surface to bottom paleotemperature gradients and greater (by 1-3°C) changes in mean sea-surface temperature between full glacial and interglacial conditions than do delta18O values from planktonic foraminifers. Along with the foraminifers, the nannofossils record a bimodal distribution of delta18O between the early and mid-late Quaternary, indicating a significant change in global ice budget. The delta13C of nannofossils also shows a bimodal distribution, but is opposite to that for the foraminifers. Nannofossil delta18O values record a shift of c. -0.8? at isotope stage 8 corresponding to a major reduction in abundance of the previously dominant gephyrocapsids. A shift in delta13C of c. -1.5? also occurs at stage 8, and a shift in delta13C of c. +1.2? at around stage 14. The delta18O shift in nannofossils is at least a Pacific-wide phenomenon; the delta13C shifts are possibly global. The delta13C signal of nannofossils exhibits an antipathetic relationship to that of benthic foraminifers back to isotope stage 18 but no significant correlation beyond this level to the base of the Quaternary. This is interpreted as reflecting local productivity dominating global influences on delta13C since stage 18 at DSDP Site 593. The difference between nannofossil and benthic foraminifer delta13C signals (Delta13C) tends to be maximum during glacial stages and minimum during interglacials throughout the section, showing a strong correlation with the nannofossil delta180 signal. The increased partitioning of 13C between surface and bottom waters during the glacial periods may indicate heightened productivity in surface waters in the southern Tasman Sea at these times.

Tertiary and Quaternary calcareous nannoplankton biostratigraphy of ODP Leg 112 holes

Positions of all cores recovered during Ocean Drilling Program (ODP) Leg 112 off Peru are shown in the standard calcareous nannoplankton zonation. Stratigraphic and regional occurrences and preservation of calcareous nannoplankton are discussed for all sites, and fossil lists are presented for selected samples. Late Miocene to Holocene nannoplankton assemblages in the upwelling systems off Peru and scattered blooms, especially of Gephyrocapsa species and Helicosphaera carteri, are described. Scyphosphaera assemblages found in late Miocene Zone NN9 {Discoaster hamatus Zone) at Site 684 are compared with similar assemblages from Gabon on the west coast of Africa. Remarkable subsidence is indicated by early and middle Eocene nearshore and shallow-water nannoplankton assemblages for Sites 682, 683, and 688. Besides several local hiatuses, major regional hiatuses were noted at Site 682 (upper Eocene, uppermost middle Eocene, and part of the lower and middle Oligocene missing), Site 683 (uppermost middle Eocene to lower part of the middle Miocene missing), and Site 688 (part of the middle Eocene, uppermost middle Eocene to upper Oligocene, and parts of the lower and middle Miocene missing).

Microfossil occurrence in Pliocene-Quaternary sediments of the North Atlantic

Planktonic foraminiferal and nannoplankton stratigraphy of the Pliocene-Quatemary Sediments of the northern half of the Atlantic Ocean from the equator up to the Rockall Plateau and the Norwegian Sea, is considered. Lowlatitude zonations were used for the subdivision of the Pliocene and Quaternary Sediments of different climatic belts, and certain subglobal zonal units were recognized. Variations in the degree of resolution of the zonation in different latitudes were revealed; the resolution of zonal scales based on calcareous plankton diminishes northwards. Changes of taxonomic composition of the zonal foraminifer and nannoplankton assemblages within various latitudinal belts of the Atlantic were analyzed taking into consideration the influence of climatic factors and of local bionomic conditions. Correlation with the magnetostratigraphic time-scale permitted the establishment of the most reliable appearance and disappearance datums (datum planes) of planktonic foraminifer and nannoplankton species. Paleontologic plates demonstrate some guide forms of two groups of calcareous plankton, and a short description of the taxa is given in the text. Major stratigraphic problems of Pliocene and Quaternary marine deposits are discussed. The monograph can be used in different geological investigations by specialists in geology, paleontology, and oceanology.