Physical properties, mineral and chemical compositions, and accumulation rates of Holocene and Upper Pleistocene bottom sediments from the Sea of Okhotsk

Mineral and chemical compositions and physical properties of diatomaceous clayey-siliceous sediments from the Sea of Okhotsk are studied. Accumulation rates of silica are determined. Their compositional model based on silica content is similar to that of Late Jurassic and Olenekian-Middle Anisian cherts from the Sikhote Alin region. Thickness of Holocene siliceous unit and accumulation rates of siliceous deposits depended on bioproductivity in the upper water layer and seafloor topography. Accumulation rates of amorphous SiO2 (0.05-5.7 g/cm**2/ka) and free SiO2 (0.5-11.6 g/cm**2/ka) are minimal on seamounts and maximal in depressions near foothills. These values match accumulation rates of free SiO2 in Triassic and Late Jurassic basins of the Sikhote Alin region (0.33-3 g/cm**2/ka). Comparison of composition and accumulation rates of silica shows that Triassic and Late Jurassic siliceous sequences of Sikhote Alin could accumulate in a marginal marine basin near a continent.

K-Ag age of volcanites from underwater rises of the Sea of Okhotsk and the Sea of Japan

New K-Ar datings of Meso-Cenozoic volcanites from the Sea of Japan and the Sea of Okhotsk were obtained. They enabled to reason age of different volcanic complexes. Basalts from volcanic edifices of the Sea of Japan Basin were determined as Middle Miocene - Pliocene (13.1-4.5 Ma) in age, which correlates well with geological evolution of the Sea of Japan. New datings for basalts from the continental slope of the South Primorye (11.1 Ma) confirm their age being similar to volcanites from Neogene basalt plateaus of the South Primorye; they are very similar not only in age but also in mineral and chemical compositions. Datings for rocks from the andesite series of the Northern Yamato Rise (24.7, 21.5 Ma) show that they are coeval with volcanites of the trachyandesite complex; this allows to combine them into one Oligocene - Early Miocene complex. In the Sea of Okhotsk datings of volcanite samples from three complexes were obtained: Cretaceous, Paleogene, and Pliocene-Pleistocene. Cretaceous magmatic rocks make part of basements of large rises in the Sea of Okhotsk, and Paleogene and Pliocene - Pleistocene complexes illustrate stages of Cenozoic tectono-magmatic activation of the region.

Geochemical records of sediment cores from the Sea of Japan

Intervals of organic C- and carbonate-rich laminated sediments occur in the Sea of Japan with roughly the same frequency as temperature changes observed in Greenland ice cores, providing clear evidence of rapid oceanographic change during the past 36 kyr. Planktonic foraminiferal d18O data suggest that only the laminated sediments deposited during the Last Glacial Maximum (LGM), and perhaps one other interval formed during a period of increased water column stratification. Sedimentary Re and Mo data are consistent with bottom waters that were sulfidic during the LGM and suboxic during other laminated intervals. Results of a numerical model of Corg and Re burial are consistent with a mechanism whereby an increased Corg flux to the seafloor drove oxygen concentrations toward depletion during times of deposition of the suboxic laminated intervals. Such a process could have resulted from increased upwelling driven either by increased deep water formation due to colder and/or more saline surface waters or by stronger northeasterly monsoonal winds.

Chemical compositions of monomineral fractions from Fe-Mn crusts and of their host rocks, seamounts of the Sea of Japan

It has been established (with use of analytical electron microscopy) that Fe-Mn crusts from two seamounts of the Sea of Japan consist predominantly of an association of birnessite minerals including Ca-birnessite and clinobirnessite. The latter is represented by twins, which form regular integrowths with 14 Å Ca-birnessite. Ore material from the third seamount (Tarasov submarine volcano) consists only of fibrous todorokite, which forms spherulitic nodules, blocks, and laminar formations. Its chemical composition is close to that of todorokite from the Galapagos rift zone.

Data on mineral composition of volcanic glass and radiocarbon age of Upper Quaternary sediments from the Sea of Okhotsk

Lithological horizons have been distinguished in sediments cores from different parts of the Sea of Okhotsk based on primary descriptions of sediments and smear slides, and analyses of contents of both calcium carbonate and organic carbon, and opal. Sediment lithology has been correlated with oxygen isotope records and the standard isotope scale and radiocarbon data by AMS method for three cores studied in detail. This allowed to determine in detail periods of carbonaceous and diatomaceous ooze accumulation in the Sea of Okhotsk. Changes in magnetic susceptibility and grain size composition of sediments have been also compared with oxygen-isotope curves and radiocarbon datings. Obtained results confirm that variations in magnetic susceptibility are related with oxygen-isotope stages and influenced by climatic changes. Tephra interlayers K0, TR, K2, K3 have been identified by mineralogical analyses in all studied cores. Stratigraphic location of these tephra interlayers in detailed studied cores and their radiocarbon ages (8.1, 8.05, 26.8, and about 60 ka, respectively) provided base correlation between the interlayers and volcanic eruptions on the Kamchatka Peninsula and the Kuril Islands. This allows to use the former ones as time markers for deep-sea sediments of the Sea of Okhotsk. New lithostratigraphic and tephrochronologic data obtained allowed to correlate Upper Quaternary sediments from the Sea of Okhotsk.

Chemical composition of nodules and crusts from the Sea of Japan

Iron-manganese mineralization on seamounts and rises in the Sea of Japan is represented by iron-manganese nodules and crusts. Their chemical composition (major elements and more than 30 trace elements) was studied by a series of analytical methods. According to geochemical comparisons hydrogenic, hydrothermal, and biogenic materials have participated in creation of this mineralization. Contents of Ba and Li, as well as Mo/Pb and Sb/As ratios can be used as indicators of genesis of iron-manganese nodules and crusts along with composition of the rare earth elements.

(Table 2) Ice rafted debris abundance and accumulation rate, sedimentation rate and dry bulk density of bottom sediments from the Sea of Okhotsk

Oxygen isotope records, radiocarbon AMS data, carbonate and opal stratigraphy, sediment magnetic susceptibility, tephrachronology, and paleontological results were used to obtain detailed sediment stratigraphy and an age model for the studied cores. For studying sea-ice sedimentation an analysis of lithogenic grain number in >0.15 mm grain size fraction of bottom sediments was carried out. For quantitative estimation of intensity ice-rafting debris sedimentation number of IRD particles per sq cm per ka was calculated. Obtained results allowed to plot IRD AR distribution for the first oxygen isotope stage (0-12.5 14C ka, 14C) and for the second stage (12.5-24 14C ka). The first stage was subdivided into the latest deglaciation and the beginning of Holocene (6-12.5 14C ka) (transitive period), when the sea level was changing significantly, and the second part of Holocene (0-6 14C ka), when climate conditions and the sea level were similar to modern estimates. Data clearly show strong increase in ice formation in the glacial Sea of Okhotsk and its extent in the middle part of the sea. Average annual duration of ice coverage during glaciation was longer than that for interglaciation. However the sea ice cover was not continuous all the year round and disappeared in summer time except the far northwestern part of the sea.

(Table 1) Age control points and dating methods for sediment cores of the Sea of Okhotsk

Marine- and terrestrial-derived biomarkers (alkenones, brassicasterol, dinosterol, and long-chain n-alkanes), as well as carbonate, biogenic opal, and ice-rafted debris (IRD), were measured in two sediment cores in the Sea of Okhotsk, which is located in the northwestern Pacific rim and characterized by high primary productivity. Down-core profiles of phytoplankton markers suggest that primary productivity abruptly increased during the global Meltwater Pulse events 1A (about 14 ka) and 1B (about 11 ka) and stayed high in the Holocene. Spatial and temporal distributions of the phytoplankton productivity were found to be consistent with changes in the reconstructed sea ice distribution on the basis of the IRD. This demonstrates that the progress and retreat of sea ice regulated primary productivity in the Sea of Okhotsk with minimum productivity during the glacial period. The mass accumulation rates of alkenones, CaCO3, and biogenic opal indicate that the dominant phytoplankton species during deglaciation was the coccolithophorid, Emiliania huxleyi, which was replaced by diatoms in the late Holocene. Such a phytoplankton succession was probably caused by an increase in silicate supply to the euphotic layer, possibly associated with a change in surface hydrography and/or linked to enhanced upwelling of North Pacific Deep Water.

Sediment thickness and distribution of facies types in the Kara Sea

We studied the impact of the last glacial (late Weichselian) sea level cycle on sediment architecture in the inner Kara Sea using high-resolution acoustic sub-bottom profiling. The acoustic lines were ground-truthed with dated sediment cores. Furthermore we refined the location of the eastern LGM ice margin, by new sub bottom profiles. New model results of post-Last Glacial Maximum (LGM) isostatic rebound for this area allow a well-constrained interpretation of acoustic units in terms of sequence stratigraphy. The lowstand (or regressive) system tract sediments are absent but are represented by an unconformity atop of Pleistocene sediments on the shelf and by a major incised dendritic paleo-river network. The subsequent transgressive and highstand system tracts are best preserved in the incised channels and the recent estuaries while only minor sediment accumulation on the adjacent shelf areas is documented. The Kara Sea can be subdivided into three areas: estuaries (A), the shelf (B) and (C) deeper lying areas that accumulated a total of 114 * 10**10 t of Holocene sediments.

Physical oceanography from eight Seaglider missions in the Mediterranean Sea, Eastern Basin

In 2008, the Oceanography Center at the University of Cyprus acquired two underwater gliders in the framework of a nationally-managed infrastructure upgrade program. The gliders were purchased from the Seaglider Fabrication Center at the University of Washington. Both gliders are rated to 1000 m and carry a typical sensor payload: non-pumped conductivity-temperature-depth sensors (CTD), a dissolved oxygen sensor, an optical triplet to measure optical backscatter at 400 nm, 700 nm, and chlorophyll-a fluorescence. Since March of 2009, the gliders have been used in a long-term observing program of the Cypriot EEZ, and by September 2015, have covered more than 15300 km over ground and 3500 dive cycles in 940 glider days. Butterfly patterns have been flown in two configurations, either on the western or eastern side of the EEZ south of Cyprus. The glider endurance lines criss-cross the region in order to more accurately locate and investigate the mesoscale structures south of Cyprus, and in particular the Cyprus eddy which is often the dominant feature. Based on the near real time observations, the glider mission was sometimes altered in order to more fully sample the Cyprus eddy, or to locate its center or extent. A summary of the raw and processed data collected, and the quality control procedures are presented, in order for future users to take advantage of this unique data set.