Magnetic measurements of ODP Hole 178-1095B on the Pacific continental rise of the West Antarctic Peninsula

In this study we present a late Miocene - early Pliocene record of sixty-four zones with prominent losses in the magnetic susceptibility signal, taken on a sediment drift (ODP Site 1095) on the Pacific continental rise of the West Antarctic Peninsula. The zones are comparable in shape and magnitude and occur commonly at glacial-to-interglacial transitions. High resolution records of organic matter, magnetic susceptibility and clay mineral composition from early Pliocene intervals demonstrate that neither dilution effects nor provenance changes of the sediments have caused the magnetic susceptibility losses. Instead, reductive dissolution of magnetite under suboxic conditions seems to be the most likely explanation. We propose that during the deglaciation exceptionally high organic fluxes in combination with weak bottom water currents and prominent sediment draping diatom ooze layers produced temporary suboxic conditions in the uppermost sediments. It is remarkable that synsedimentary suboxic conditions can be observed in one of the best ventilated open ocean regions of the World.

In-situ geotechnical measurements with the dynamic penetrometer Nimrod on the continental shelf off the Coromandel Peninsula, New Zealand

We tested the ability of a small dynamic penetrometer, Nimrod, to infer geotechnical properties of sediment mixtures in the inner shelf. The penetrometer is light and easy to operate, and its operation by scuba divers ensures a greater degree of precision than ship-based penetrometer deployments. We have studied selected positions along a sorted bedform (~ 100 m wide) on the continental shelf off the Coromandel Peninsula close to Tairua, North Island of New Zealand, and additionally took sediment samples at the exact positions of penetrometer impact, also by scuba divers. The derived dynamic penetrometer signatures (i) measured deceleration of the probe and estimated quasi-static bearing capacity as a measure of sediment strength, (ii) reflected changes in grain-size distribution ranging from very fine to very coarse sands, and (iii) revealed the uppermost seafloor stratification (top layer 2-6 cm) potentially being an indicator for sediment dynamics. In this manner, the device proved to be suitable for spatially fine-scaled surveys using divers' support and might deliver complementary information about sediment dynamics, in this case sorted-bedform maintenance.

Halogene concentrations and iodine isotopic composition in pore water on Hydrare Ridge, Cascadia continental margin

We report iodine and bromine concentrations in a total of 256 pore water samples collected from all nine sites of Ocean Drilling Program Leg 204, Hydrate Ridge. In a subset of these samples, we also determined iodine ages in the fluids using the cosmogenic isotope 129I (T1/2 = 15.7 Ma). The presence of this cosmogenic isotope, combined with the strong association of iodine with methane, allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly with depth from values close to that of seawater (0.0004 mM) to concentrations >0.5 mM. Several of the cores taken from the northwest flank of the southern summit show a pronounced maximum in iodine concentrations at depths between 100 and 150 meters below seafloor in the layer just above the bottom-simulating reflector. This maximum is especially visible at Site 1245, where concentrations reach values as high as 2.3 mM, but maxima are absent in the cores taken from the slope basin sites (Sites 1251 and 1252). Bromine concentrations follow similar trends, but enrichment factors for Br are only 4-8 times that of seawater (i.e., considerably lower than those for iodine). Iodine concentrations are sufficient to allow isotope determinations by accelerator mass spectrometry in individual pore water samples collected onboard (~5 mL). We report 129I/I ratios in a few samples from each core and a more complete profile for one flank site (Site 1245). All 129I/I ratios are below the marine input ratio (Ri = 1500x10**-15). The lowest values found at most sites are between 150 and 250x10**-15, which correspond to minimum ages between 40 and 55 Ma, respectively. These ages rule out derivation of most of the iodine (and, by association, of methane) from the sediments hosting the gas hydrates or from currently subducting sediments. The iodine maximum at Site 1245 is accompanied by an increase in 129I/I ratios, suggesting the presence of an additional source with an age younger than 10 Ma; there is indication that younger sources also contribute at other sites, but data coverage is not yet sufficient to allow a definitive identification of sources there. Likely sources for the older component are formations of early Eocene age close to the backstop in the overriding wedge, whereas the younger sources might be found in recent sediments underlying the current locations of the gas hydrates.

Spatial distribution of isotopic compositions of Globigerina bulloides and Neogloboquadrina pachyderma (dex.) and the faunal assemblages of planktic foraminifera in surface sediment samples along the Chilean continental slope between 23°S and 44°S

We report on the spatial distribution of isotopic compositions of the two planktic foraminifera species Globigerina bulloides and Neogloboquadrina pachyderma (dex.), and the faunal assemblages of planktic foraminifera in 91 surface sediment samples along the Chilean continental slope between 23°S and 44°S. Both d13C and d18O data of N. pachyderma (dex.) show little variability in the study area. North of 39°S, the isotopic values of N. pachyderma (dex.) are heavier than those of G. bulloides, whereas south of 39°S, this relation inverses. This is indicative for a change from a well-mixed, deep thermocline caused by coastal upwelling north of 39°S to well-stratified water masses in a non-upwelling environment south of 39°S. In addition, the faunal composition of planktic foraminifera marks this change by transition from an upwelling assemblage north of 39°S to a high-nutrient-non-upwelling assemblage south of 39°S, which is characterized by decreased contributions of upwelling indicators such as G. bulloides, N. pachyderma (sin.), and Globigerinita glutinata. In general, we can conclude that food and light rather than temperature are the primary control of the planktic foraminiferal assemblage between 23°S and 44°S off Chile. Our data point to higher marine productivity at upwelling centers north of 25°S and at 30-33°S. South of 39°S, significant supply of nutrients by fluvial input most likely boosts the productivity.

Age of samples from the sedimentary cover of the Primorye continental slope and from the submarine Bogorov Rise

Results of a complex study of the sedimentary cover (continuous seismic profiling and diatom analysis) in the northeastern Sea of Japan including the Bogorov Rise an adjacent part of the Japan Basin and the continental slope, are presented. Two varied-age complexes were distinguished in the sedimentary cover of the continental slope of Primorye: Middle Miocene and Late Miocene - Pleistocene. These complexes formed in a stable tectonic setting with no significant vertical movements. A depression in the acoustic basement is located along the continental slope and it is divided from the Japan Basin by a group of volcanic structures, the most uplifted part of which forms the Bogorov Rise. The depression probably formed before Middle Miocene. In Middle Miocene the Bogorov Rise was already at depths close to modern ones. In the sedimentary cover near the Bogorov Rise buried zones were found. Probably they were channels for gas transportation in pre-Pleistocene. Deformations of sediments that occurred in the beginning of Pleistocene are established in the basin.

Multiproxy sedimentation patterns of sediment cores from the continental margin off northeast Brazil

Tropical regions have been reported to play a key role in climate dynamics. To date, however, there are uncertainties in the timing and the amplitude of the response of tropical ecosystems to millennial-scale climate change. We present evidence of an asynchrony between terrestrial and marine signals of climate change during Heinrich events preserved in marine sediment cores from the Brazilian continental margin. The inferred time lag of about 1000 to 2000 years is much larger than the ecological response to recent climate change and appears to be related to the nature of hydrological changes.

Volcanic ash from the Peru continental margin

During Leg 112 off Peru, volcanic material was recorded from middle Eocene to Holocene time. The petrographical and chemical composition of tephra is consistent with an origin from the Andean volcanic arc. The amount and thickness of ash layers provide valuable evidence for explosive volcanic episodicity. The first indication of volcanism was found in mid-Eocene sediments. Three volcanic pulses date from Miocene time. Two intense episodes took place in upper Pliocene and from Pleistocene to Holocene time. Pliocene-Pleistocene tephra are restricted to the southern upper-slope and shelf sites, indicating a removal of the volcanic arc and the extinction of the northern Peru volcanoes. The Cenozoic tectonic phases of the Andean margin may be correlated with the Leg 112 volcanic records. The explosive supply of evolved magmatic products succeeded the Incaic and Quechua tectonic phases. Acidic glasses are related to both andesitic and shoshonitic series. The calc-alkaline factor (CAF) of these glasses exhibited moderate magmatic variations during middle and late Miocene time. A dramatic change occurred during the Pliocene-Pleistocene, reflected in a strong CAF increase and the appearance of potassium-rich evolved shoshonitic glasses. This took place when the Nazca Ridge subduction began. This change in the magma genesis and/or differentiation conditions is probably related to thickening of the upper continental plate and to a new configuration of the Benioff Zone.

Live benthic foraminifera in surface sediments of the Indo-Pakistan continental margin

The Indo-Pakistan Continental Margin represents an extreme habitat for benthic foraminifera since (1) high fluxes of organic matter offer a high food supply, (2) an intensified oxygen minimum Zone (OMZ) develops from the base of the euphotic Zone to water depths over 1000 m and (3) the monsoon causes seasonal oscillations within the biogeochemical cycle. At three stations from the uppermost (233 m), the central (658 m) and the deeper part (902 m) of the OMZ, living benthic foraminiferal assemblages were analyzed within the uppermost 10 cm of the sediment column. The ecologic structure of foraminiferal faunas is characterized by high abundances at the sediment surface and a rapid decrease within the uppermost 2 cm of the sediment column. Despite dysoxic to suboxic bottom-water conditions, stained benthic foraminifera occurred in all cores down to the base of the sampled interval. High surface abundances, a high dominance by few endobenthic calcareous taxa and a low diversity, which may result from specific physiological adaptations to almost anoxic conditions and the absence of predators, are recognized in the central part of the OMZ. The upper and lower margins of the OMZ are characterized by higher diversities and lower abundances. The shallowest part of the OMZ is dominated by calcareous foraminifera, whereas agglutinated species are the most common taxa in the deeper part. Comparisons with previous studies show that benthic foraminiferal assemblages, that are influenced by seasonal oscillations controlling food supply and/or the availability of oxygen, show variations in faunal density and species composition. Since there is strong evidence that oxygen is not a limiting factor for some taxa, it seems more likely that the distribution pattern of benthic foraminifera is preferentially controlled by trophic conditions.

Calculated surface water paleotemperatures for the lower Pliocene at DSDP Site 18-173 from the California continental slope (Table I)

The oxygen isotope record of the planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma from Pliocene and early Pleistocene sediments at both DSDP site 173 and the Centerville Beach section in California suggests a large influx of isotopically light water in this area during late Pliocene and early Pleistocene time. Salinity may have been reduced by as much as 2 to 4 ?. Surface sea water paleotemperatures for the lower Pliocene range from 9.5°C to 15.5°C. The oxygen isotope record of the benthonic genus Uvigerina shows little variation indicating environmental stability at depth. At DSDP site 173 the small variation in Uvigerina is due to variation in the oxygen isotopic composition of the oceans as glaciers waxed and waned. At the Centerville Beach section the oxygen isotopic composition of Uvigerina reflects the gradual shoaling of the Humboldt Basin. Carbon and oxygen isotope ratios in G. bulloides and N. pachyderma are inversely correlated at the 95% confidence level. This may indicate that the oxygen and carbon isotopic composition of foraminifera are influenced by the same factors. On the other hand, the inverse correlation may be due to metabolic fractionation. No correlation was found between oxygen and carbon isotopic composition in Uvigerina.

Rock magnetic, element, and color data of three sediment cores along the Senegalese continental margin

We present a suite of new high-resolution records (0-135 ka) representing pulses of aeolian, fluvial, and biogenic sedimentation along the Senegalese continental margin. A multiproxy approach based on rock magnetic, element, and color data was applied on three cores enclosing the present-day northern limit of the ITCZ. A strong episodic aeolian contribution driven by stronger winds and dry conditions and characterized by high hematite and goethite input was revealed north of 13°N. These millennial-scale dust fluxes are synchronous with North Atlantic Heinrich stadials. Fluvial clay input driven by the West African monsoon predominates at 12°N and varies at Dansgaard-Oeschger time scales while marine productivity is strongly enhanced during the African humid periods and marine isotope stage 5. From latitudinal signal variations, we deduce that the last glacial ITCZ summer position was located between core positions at 12°26' and 13°40'N. Furthermore, this work also shows that submillennial periods of aridity over northwest Africa occurred more frequently and farther south than previously thought.

Pore water concentrations and solid phase concentrations of sediment cores from the Ligurian continental slope

In October 1979, a period of heavy rainfall along the French Riviera was followed by the collapse of the Ligurian continental slope adjacent to the airport of Nice, France. A body of slope sediments, which was shortly beforehand affected by construction work south of the airport, was mobilized and traveled hundreds of kilometers downslope into the Var submarine canyon and, eventually, into the deep Ligurian basin. As a direct consequence, the construction was destroyed, seafloor cables were torn, and a small tsunami hit Antibes shortly after the failure. Hypotheses regarding the trigger mechanism include (i) vertical loading by construction of an embankment south of the airport, (ii) failure of a layer of sensitive clay within the slope sequence, and (iii) excess pore fluid pressures from charged aquifers in the underground. Over the previous decades, both the sensitive clay layers and the permeable sand and gravel layers were sampled to detect freshened waters. In 2007, the landslide scar and adjacent slopes were revisited for high-resolution seafloor mapping and systematic sampling. Results from half a dozen gravity and push cores in the shallow slope area reveal a limited zone of freshening (i.e. groundwater influence). A 100-250 m wide zone of the margin shows pore water salinities of 5-50% SW concentration and depletion in Cl, SO4, but Cr enrichment, while cores east or west of the landslide scar show regular SW profiles. Most interestingly, the three cores inside the landslide scar hint towards a complex hydrological system with at least two sources for groundwater. The aquifer system also showed strong freshening after a period of several months without significant precipitation. This freshening implies that charged coarse-grained layers represent a permanent threat to the slope's stability, not just after periods of major rainfall such as in October 1979.

Aragonite distribution and preservation of sediment cores from the Brazilian Continental Slope

We present late Quaternary records of aragonite preservation determined for sediment cores recovered on the Brazilian Continental Slope (1790-2585 m water depth) where North Atlantic Deep Water (NADW) dominates at present. We have used various indirect dissolution proxies (carbonate content, aragonite/calcite contents, and sand percentages) as well as gastropodal abundances and fragmentation of Limacina inflata to determine the state of aragonite preservation. In addition, microscopic investigations of the dissolution susceptibility of three Limacina species yielded the Limacina Dissolution Index which correlates well with most of the other proxies. Excellent preservation of aragonite was found in the Holocene section, whereas aragonite dissolution gradually increases downcore. This general pattern is attributed to an overall increase in aragonite corrosiveness of pore waters. Overprinted on this early diagenetic trend are high-frequency fluctuations of aragonite preservation, which may be related to climatically induced variations of intermediate water masses.