Geology, geochemistry, and mineralogy of sediments from the Trans Indian Ocean Geotraverse

The monograph is devoted to the main results of research on the Trans Indian Ocean Geotraverse from the Maskarene Basin to the north-western margin of Australia. These results were obtained by Russian specialists and together with Indian specialists during 15 years of cooperation in investigation of geological structure and mineral resources of the Indian Ocean. The monograph includes materials on information support of marine geological and geophysical studies, composition and structure of information resources on the Indian Ocean, bathymetry and geomorphology, structure and geological nature of the magnetic field, gravity field, plate tectonics, crustal structure and sedimentary cover, seismic stratigraphy, perspectives for detecting oil and gas, solid minerals, sediment composition, composition and properties of clay minerals, stratigraphy and sediment age, chemical composition of sediments, composition of and prospects for solid minerals.

Chemical composition of bottom waters and interstitial waters from sediments and deposits within and outside the Haakon Mosby submarine mud volcano in the Norwegian Sea

On the base of data of Cruise 40 of R/V Akademik Keldysh features of formation of saline composition of interstitial waters from sediments containing free hydrocarbons (methane) and gas hydrates (CH4 x 6H2O) were considered. Chemical composition of the interstitial waters is presented for three zones of sediments from the Haakon Mosby submarine mud volcano: (1) zone of kettles containing free hydrocarbons, (2) gas hydrate sediments, and (3) periphery of the volcano. Abnormally high concentrations of bromine and especially iodine characteristic of the interstitial and particularly of the oil-field waters were found. Because of a great interest in natural gas hydrates found in marine sediments, we obtained a possibility to supplement scarce of available published data with some new information.

Basalt density, basement age, and intrusive/extrusive relations from DSDP Legs 2 through 7, 9, and 14

Densities of layer 2 basalt recovered during the Deep Sea Drilling Project have been found to decrease steadily with age, a finding ascribed to progressive submarine weathering in the context of sea-floor spreading. The least-squares solution for 52 density measurements gives a rate of decrease in density of (Delta p)/(Delta t) = -0.0046 g per ccm m.y. = -16 percent per 100 m.y., which is in excellent agreement with earlier estimates based on observed chemical depletion rates of dredged oceanic basalt. Weathering of sea-floor basalt, should it penetrate to any considerable depth in layer 2, will decrease layer 2 seismic refraction velocities, act as a source of geothermal heat, and substantially influence the chemistry of sea water and the overlying column of sediment.

Ikaite of sediment cores from the Zaire deep-sea fan

Most concentration profiles of sulfate in continental margin sediments show constant or continuously increasing gradients from the benthic boundary layer down to the deep sulfate reduction zone. However, a very marked change in this gradient has been observed several meters below the surface at many locations, which has been attributed to anoxic sulfide oxidation or to non-local transport mechanisms of pore waters. The subject of this study is to investigate whether this feature could be better explained by non-steady state conditions in the pore-water system. To this end, data are presented from two gravity cores recovered from the Zaire deep-sea fan. The sediments at this location can be subdivided into two sections. The upper layer, about 10 m thick, consists of stratified pelagic deposits representing a period of continuous sedimentation over the last 190 kyr. It is underlain by a turbidite sequence measuring several meters in thickness, which contains large crystals of authigenic calcium carbonate (ikaite: CaCO3·6H2O). Ikaite delta13C values are indicative of a methane carbon contribution to the CO2 pool. Radiocarbon ages of these minerals, as well as of the adjacent bulk sediments, provide strong evidence that the pelagic sediments have overthrust the lower section as a coherent block. Therefore, the emplacement of a relatively undisturbed sediment package is postulated. Pore-water profiles show the depth of the sulfate-methane transition zone within the turbiditic sediments. By the adaptation of a simple transport-reaction model, it is shown that the change in the geochemical environmental conditions, resulting from this slide emplacement, and the development towards a new steady state are fully sufficient to explain all features related to the pore-water profiles, particularly, [SO4]2- and dissolved inorganic carbon (DIC). The model shows that the downslope transport took place about 300 yr ago.

Stratigraphic first occurrence of Emiliania huxleyi in sediments of the Chatham Rise (Table 2)

A quantitative analysis was carried out of planktonic diatoms (biogenic opal) and calcareous nannofossils (biogenic calcite) in late Quaternary sediments (MIS 1-6) from four cores along a N-S transect east of New Zealand from 39°50'S to 50°04'S across the E-W-trending submarine ridge, the Chatham Rise. This was done to trace movements of oceanic fronts and to improve calcareous nannofossil stratigraphy for the last 130 000 yr in the SW Pacific. Sites ODP 1123 and Q 858 are below present day subtropical surface waters north of Chatham Rise. Site DSDP 594 is below present-day mixed temperate-subantarctic surface water south of the rise, and site ODP 1120 is below subantarctic surface water. The more diverse and opportunistic planktonic diatoms provided marker species for subtropical surface waters (Alveus marina, Fragilariopsis doliolus, Rhizosolenia bergonii and Azpeitia nodulifer) and others for subantarctic surface waters (Nitzschia kerguelensis, Thalassiosira lentiginosa). Application of these tracers permits the following conclusions: (1) subtropical conditions persisted north of Chatham Rise throughout the past 130 000 yr, in spite of the cooling of surface waters during colder periods; (2) during warm times (MIS 5 and MIS 3, and in MIS 1), the sporadic occurrence of subtropical species south of Chatham Rise indicates occasional admixture of subtropical surface waters that far south; (3) subantarctic waters extended to the southern slopes of the Chatham Rise during MIS 5b, late MIS 5a to early MIS 4, during the warmer time intervals in early MIS 3, and during latest MIS 3 to early MIS 2; (4) subantarctic frontal conditions existed over southern Chatham Rise during early MIS 4 and late MIS 3 to early MIS 2; and (5) it is probable that during cooler times, MIS 6, MIS 5b, and in MIS 2, intensified particle transport from the Bounty Trough to the northern flank of Chatham Rise occurred by intensified boundary currents. The larger abundance fluctuations in both microfossil groups at the sites south of Chatham Rise than north of Chatham Rise reflect northward shifts of the Circumpolar Subantarctic Water (CSW) and a contemporaneous disappearance of Australasian Subantarctic Water (ASW), implying an elevated temperature gradient between the surface water masses north and south of the Chatham Rise at the times of such northward shifts of CSW. Calcareous nannofossils are less diverse than diatoms, and are less specialised. Some calcareous nannofossil species show abundance shifts at the same time at different latitudes. Two of these abundance shifts can be used for correlation between subtropical and subantarctic sediments in the SW Pacific: (1) reversal in the relative abundance of Calcidiscus leptoporus and Coccolithus pelagicus associated with the MIS 2/1 boundary; and (2) drop in abundance of Gephyrocapsa muellerae or medium-sized Gephyrocapsa at the MIS 4/3 boundary. An additional abundance shift seems to be restricted to subtropical to mixed temperate-subtropical-subantarctic surface waters: (3) increase in abundance of G. muellerae or medium-sized Gephyrocapsa at the beginning of MIS 2 below the Okareka tephra.

(Supplemet S1) Silicon oxide and Potassium + Sodium oxide from the PACManus hydrothermal area

This study presents a systematic analysis and interpretation of autonomous underwater vehicle-based microbathymetry combined with remotely operated vehicle (ROV) video recordings, rock analyses and temperaturemeasurements within the PACManus hydrothermal area located on Pual Ridge in the Bismarck Sea of eastern Manus Basin. The data obtained during research cruise Magellan-06 and So-216 provides a framework for understanding the relationship between the volcanism, tectonismand hydrothermal activity. PACManus is a submarine felsic vocanically-hosted hydrothermal area that hosts multiple vent fields locatedwithin several hundredmeters of one another but with different fluid chemistries, vent temperatures and morphologies. The total area of hydrothermal activity is estimated to be 20,279m**2. Themicrobathymetrymaps combinedwith the ROV video observations allow for precise high-resolution mapping estimates of the areal extents of hydrothermal activity.We find the distribution of hydrothermal fields in the PACManus area is primarily controlled by volcanic features that include lava domes, thick andmassive blocky lava flows, breccias and feeder dykes. Spatial variation in the permeability of local volcanic facies appears to control the distribution of venting within a field.We define a three-stage chronological sequence for the volcanic evolution of the PACManus based on lava flow morphology, sediment cover and lava SiO2 concentration. In Stage-1, sparsely to moderately porphyritic dacite lavas (68-69.8 wt.% SiO2) erupted to form domes or cryptodomes. In Stage-2, aphyric lava with slightly lower SiO2 concentrations (67.2-67.9 wt.% SiO2) formed jumbled and pillowed lava flows. In the most recent phase Stage-3, massive blocky lavaswith 69 to 72.5wt.% SiO2were erupted throughmultiple vents constructing a volcanic ridge identified as the PACManus neovolcanic zone. The transition between these stages may be gradual and related to progressive heating of a silicic magma following a recharge event of hot, mantle-derived melts.

Age of samples from the sedimentary cover of the Primorye continental slope and from the submarine Bogorov Rise

Results of a complex study of the sedimentary cover (continuous seismic profiling and diatom analysis) in the northeastern Sea of Japan including the Bogorov Rise an adjacent part of the Japan Basin and the continental slope, are presented. Two varied-age complexes were distinguished in the sedimentary cover of the continental slope of Primorye: Middle Miocene and Late Miocene - Pleistocene. These complexes formed in a stable tectonic setting with no significant vertical movements. A depression in the acoustic basement is located along the continental slope and it is divided from the Japan Basin by a group of volcanic structures, the most uplifted part of which forms the Bogorov Rise. The depression probably formed before Middle Miocene. In Middle Miocene the Bogorov Rise was already at depths close to modern ones. In the sedimentary cover near the Bogorov Rise buried zones were found. Probably they were channels for gas transportation in pre-Pleistocene. Deformations of sediments that occurred in the beginning of Pleistocene are established in the basin.

Age model and elemental data of DSDP Holes 48-401 and 80-549

A growing body of geologic evidence suggests that emplacement of the North Atlantic Igneous Province (NAIP) played a major role in global warming during the early Paleogene as well as in the transient Paleocene-Eocene thermal maximum (PETM) event. A ~5 million year record of major and trace element abundances spanning 56 to 51 Ma at Deep Sea Drilling Project Sites 401 and 549 confirms that the majority of NAIP volcanism occurred as subaerial flows. Thus the trace element records provide constraints on the nature and scope of the environmental impact of the NAIP during the late Paleocene-early Eocene interval. Subaerial volcanism would have injected mantle CO2 directly into the atmosphere, resulting in a more immediate increase in atmospheric greenhouse gas abundances than CO2 input through submarine volcanism. The lack of significant hydrothermalism contradicts recently proposed mechanisms for thermally destabilizing methane hydrate reservoirs during the PETM. Any connection between NAIP volcanism and PETM warming had to occur through the atmosphere.

K-Ar dating of altered deep-sea igneous rocks from DSDP Legs 2, 34, and 35

In an attempt to establish criteria for obtaining reliable K-Ar dates, conventional K-Ar studies of several Deep Sea Drilling Project sites were undertaken. K-Ar dates of these rocks may be subject to inaccuracies as the result of sea-water alteration. Inaccuracies may also result from the presence of excess radiogenic 40Ar trapped in rapidly cooled rocks at the time of their formation. The results obtained for DSDP Leg 34 basalts indicate that lowering of K-Ar dates, which is related to potassium addition by weathering, is a major cause of uncertainty in obtaining reliable K-Ar dates for deep-sea rocks. It could not be determined if the potassium addition to the basalts occurred at the time of formation, t_o, or continuously from t_o to the present. Calculations show that sediment cover is not a significant barrier to the diffusion of potassium into the basalt. 40Ar loss contributes, at least in part, to the lowering of the K-Ar date in rocks that have added potassium. The meaning of the K-Ar results obtained for DSDP Legs 35 and 2 basalts could not be unambiguously established. Because of the problems involved, caution must be used in interpreting the meaning of conventional K-Ar dates for deep-sea rocks.