Polonium-210 and Lead-210 activities measured on 9 water bottle profiles during POLARSTERN cruise ANT-XXIV/3

As part of the GEOTRACES Polarstern expedition ANT XXIV/3 (ZERO and DRAKE), Polonium-210 and Lead-210 have been measured in the water column and on suspended particulate matter in February to April 2008. Our goal was to resolve the affinities of 210Po and 210Pb to transparent exopolymer particles (TEP) and particulate organic carbon (POC). Polonium-210 and Lead-210 in the ocean can be used to identify the sources and sinks of suspended matter. In seawater, Polonium-210 (210Po) and Lead-210 (210Pb) are produced by stepwise radioactive decay of Uranium-238. 210Po (138 days half life) and 210Pb (22.3 years half life) have high affinities for suspended particles. Those radionuclides are present in dissolved form and adsorbed onto particles. Following adsorption onto particle surfaces, 210Po especially is transported into the interior of cells where it bonds to proteins. In this way, 210Po also accumulates in the food chain. 210Po is therefore considered to be a good tracer for POC, and traces particle export over a timescale of months. 210Pb (22.3 years half life) adsorbs preferably onto structural components of cells, biogenic silica and lithogenic particles, and is therefore a better tracer more rapidly sinking matter. Water samples were taken with Niskin bottles. Dissolved Polonium-210 and Lead-210 activities refer to the fraction < 1µm. Particulate Polonium-210 and Lead-210 refer to the activity on particles >1µm retained on nucleopore filters. Zooplankton retained on the filters was systematically removed as this study focused on phytoplankton and exudates. The data have been submitted to Pangaea following a Polonium-Lead intercalibration exercise organized by GEOTRACES, where the AWI lab results range within the data standard deviation from 10 participating labs.

Dinoflagellate cyst counts of ODP Site 1081, Benguela Upwelling, Miocene-Pliocene

Using the Late Miocene to Pliocene organic-walled dinoflagellate cyst record of ODP Site 1081 we reconstruct and discuss the early upwelling history over the Walvis Ridge with a special focus on the movement of the Angola-Benguela Front (ABF). We suggest that during the Late Miocene the Angola Current flowed southwards over the Walvis Ridge more frequently than today because the ABF was probably located further south as a result of a weaker meridional temperature gradient. A possible strengthening of the meridional gradient during the latest Miocene to early Pliocene in combination with uplift of south-western Africa intensified the upwelling along the coast and increased the upwelling's filaments over the Walvis Ridge. An intermediate period from 6.2 to 5.5 Ma is shown by the dominance of Habibacysta tectata, cysts of a cool-tolerant dinoflagellate known from the northern Atlantic, indicating changing oceanic conditions contemporaneous with the Messinian Salinity Crisis. From 4.3 Ma on, the upwelling signal got stronger again and waters were well-mixed and nutrient-rich. Our results indicate a northward migration of the ABF as early as 7 Ma and the initial stepwise intensification of the BUS.

Planktonic foraminiferal preservation in Plio/Pleistocene sediments from the western equatorial Atlantic and Caribbean

Records of mean sortable silt and planktonic foraminiferal preservation from the Ceará Rise (western equatorial Atlantic) and from the Caribbean are presented to analyze the Pliocene (3.5-2.2 Ma) to Pleistocene (1.6-0.3 Ma) evolution of near-bottom current strength and the carbonate corrosiveness of deep water. During the mid-Pleistocene climate transition (~1 Ma) a drastic decrease in glacial bottom current strength and an increase in carbonate corrosiveness is registered, demonstrating a substantial decrease in the glacial contribution of the Lower North Atlantic Deep Water (LNADW) to the Atlantic Ocean. Also, an increased sensitivity to eccentricity orbital forcing is registered after the MPT. By contrast, carbonate preservation increases considerably in the deep Caribbean in response to a strong and persistent stable contribution of Upper North Atlantic Deep Water (UNADW). We found evidence for the strongest and most stable circulation within the LNADW cell during the Northern Hemisphere cooling period between ~3.2 and 2.75 Ma. This is in agreement with the 'superconveyor model' which postulates that the highest NADW production took place prior to ~2.7 Ma. A considerable decrease in bottom current strength and planktonic foraminiferal preservation is observed synchronous with the first occurrence of large-scale continental ice sheets in the Northern Hemisphere. This documents the final termination of the 'superconveyor' at ca. 2.75 Ma. However, our data do not support a 'superconveyor' in the interval between 3.5 and 3.2 Ma when high-amplitude fluctuations in bottom current flow and preservation in planktonic foraminifera are observed. Because of the great sensitivity of NADW production to changes in surface water salinity, we assume that the high-amplitude fluctuations of LNADW circulation prior to ~3.2 Ma are linked to changes in the Atlantic salinity budget. After 2.75 Ma they are primarily controlled by ice-sheet forcing. In contrast to the stepwise deterioration of planktonic foraminiferal preservation in the western deep Atlantic, a trend toward better preservation from the Pliocene to Pleistocene is observed in the deep Caribbean. This indicates a long-term increase in the contribution of UNADW to the Atlantic Ocean.

(Table 1) Argon dating of ash layers from DSDP Hole 18-178

Ash layers from Deep Sea Drilling Project site 178 in the northeast Pacific Ocean have been dated by the 40Ar-39Ar stepwise heating technique to resolve published discrepancies concerning the length of time explosive volcanism has affected the eastern Aleutian arc and Alaskan Peninsula. The results of the investigation indicate that the record of ash-fall deposition at site 178 extends back at least 6.5 m.y. Assuming that 6.5 m.y. ago marks the onset of renewed calc-alkalic volcanism of the volcanic arc, proposed models of continuous and discontinuous motion between the Pacific and North American lithospheric plates can be evaluated. If appreciable time elapsed between the onset of subduction and the onset of arc volcanism, the 6.5-m.y. record of ash-fall deposition in the north-east Pacific is most compatible with models of continuous plate motion throughout late Cenozoic time.

Planktonic foraminiferal assemblages of the Paleocene-Eocene Thermal Maximum of ODP Hole 113-690B

High-resolution study of Antarctic planktonic foraminiferal assemblages (Ocean Drilling Program Site 690, Weddell Sea) shows that these microplankton underwent a stepwise series of changes during the Paleocene-Eocene thermal maximum (PETM). Initiation of this response coincides with the onset of the carbon isotope excursion (CIE) but precedes the benthic foraminiferal mass extinction. The "top-to-bottom" succession in the biotic response indicates that the surface ocean/atmosphere was affected before the deep sea. The earliest stage of the faunal response entailed a conspicuous turnover within the shallow-dwelling genus Acarinina and a succession of stratigraphic first appearances. The genus Morozovella, large (>180 µm) biserial planktonics, and A. wilcoxensis are all restricted to the lower CIE within this PETM section. Acarininid populations crashed as the ocean/climate system ameliorated during the CIE recovery, reflecting atypical surface water conditions. This transient decline in acarininids is paralleled by a marked increase in carbonate content of sediments. It is postulated that this interval of carbonate enrichment, and its unusual microfauna, reflects enhanced carbon storage within reservoirs of the global carbon cycle other than the marine carbonate system (sensu Broecker et al., 1993, doi:10.1029/93PA00423; Ravizza et al., 2001, doi:10.1029/2000PA000541).

(Table 2) Concentrations of dissolved aluminum in interstitial water from sediments of the Indian Ocean

Results are presented of application of laser stepwise photoionization of atoms in combination with thermal atomization of matter in vacuum for direct determination of aluminum dissolved in sea and interstitial waters. Dry residue from evaporation of 40 ?l sea water was atomized in a crucible at 1800°C, and aluminum atoms in the beam thus formed were energized into Rydberg state in two steps by two tunable dye laser beams; the atoms were then ionized by an electric pulse and resulting ions were recorded by secondary emission electron multiplier (ion detector). Ionic signal dependence on sample vaporization time was studied. The procedure is suggested for separating out a selective signal in a single measurement. Dissolved aluminum concentrations in interstitial waters of the Indian Ocean and in waters of the river-sea zone were determined using preliminarily plotted calibration characteristics for aluminum solutions in deionized and sea waters. The minimum detectable Al concentration in seawater was 1 ?g/l that corresponds to 40 pg of Al in a sample.

Paleoceanography on sediment core MD01-2416

IMAGES core MD01-2416 (51°N, 168°E) provides the first centennial-scale multiproxy record of Holocene variation in North Pacific sea-surface temperature (SST), salinity, and biogenic productivity. Our results reveal a gradual decrease in subarctic SST by 3-5 °C from 11.1 to 4.2 ka and a stepwise long-term decrease in sea surface salinity (SSS) by 2-3 p.s.u. Early Holocene SSS were as high as in the modern subtropical Pacific. The steep halocline and stratification that is characteristic of the present-day subarctic North Pacific surface ocean is a fairly recent feature, developed as a product of mid-Holocene environmental change. High SSS matched a salient productivity maximum of biogenic opal during Bølling-to-Early Holocene times, reaching levels similar to those observed during preglacial times in the warm mid-Pliocene prior to 2.73 Ma. Similar productivity spikes marked every preceding glacial termination of the last 800 ka, indicating recurrent short-term events of mid-Pliocene-style intense upwelling of nutrient-rich Pacific Deepwater in the Pleistocene. Such events led to a repeated exposure of CO2-rich deepwater at the ocean surface facilitating a transient CO2 release to the atmosphere, but the timing and duration of these events repudiate a long-term influence of the subarctic North Pacific on global atmospheric CO2 concentration.