Site characteristics and ice speed at four sites on Kangiata Nunata Sermia glacier, southwest Greenland

We present subdaily ice flow measurements at four GPS sites between 36 and 72 km from the margin of a marine-terminating Greenland outlet glacier spanning the 2009 melt season. Our data show that >35 km from the margin, seasonal and shorter-time scale ice flow variations are controlled by surface melt-induced changes in subglacial hydrology. Following the onset of melting at each site, ice motion increased above background for up to 2 months with resultant up-glacier migration of both the onset and peak of acceleration. Later in our survey, ice flow at all sites decreased to below background. Multiple 1 to 15 day speedups increased ice motion by up to 40% above background. These events were typically accompanied by uplift and coincided with enhanced surface melt or lake drainage. Our results indicate that the subglacial drainage system evolved through the season with efficient drainage extending to at least 48 km inland during the melt season. While we can explain our observations with reference to evolution of the glacier drainage system, the net effect of the summer speed variations on annual motion is small (~1%). This, in part, is because the speedups are compensated for by slowdowns beneath background associated with the establishment of an efficient subglacial drainage system. In addition, the speedups are less pronounced in comparison to land-terminating systems. Our results reveal similarities between the inland ice flow response of Greenland marine- and land-terminating outlet glaciers.

Calcareous nannofossil abundance and datums of sediments from ODP Leg 170 sites

Three Pleistocene, five Pliocene, and thirteen late and middle Miocene calcareous nannofossil datums have been identified in the Leg 170 cored sequences collected from a transect across the Middle America Trench off the Nicoya Peninsula. Although some nannofossil zones could not be delineated, particularly in the Pliocene and upper Miocene, there appears to be a complete or very nearly complete Pleistocene through lower Miocene section at Sites 1039 and 1040. The oldest assemblages, observed at Site 1039 and 1040, are latest early Miocene in age (nannofossil Zone NN4). These assemblages are associated with gabbro intrusions into the basal sediments (one contact metamorphic hornfels sample contains relict nannofossils), indicating an age for the intrusion event of between 15.6 and 18.2 Ma at both Sites 1039 and 1040. Reference Site 1039, located on the Cocos plate, provides the best-preserved sequence of sediments of late Pleistocene to latest early Miocene age. The sediments cored in the prism sections at Sites 1040, 1041, 1042, and 1043 all indicate that the age of nannofossil assemblages in the prism sediments, including the toe, wedge, and apron, are all Pleistocene with a considerable amount of upper Miocene reworking. A period of low sediment accumulation rates (~5.3 m/m.y.) is recorded for Pliocene and upper Miocene sediments at Sites 1039, 1040, and 1043. Pliocene calcareous nannofossil assemblages characteristic of the ~2.5- to 3.75-m.y. time interval (nannofossil Zones NN16 and equivalent nannofossil Subzones CN12b and CN12a) were not resolved at any site. Nannofossil Zones NN15, NN14, NN13, and NN12 (early late Pliocene to early Pliocene) could not be resolved at any site either because of the absence of marker species. Within the Miocene at Sites 1039 and 1040, nannofossil Zones NN10-NN6 were difficult to differentiate because of the absence of several species that define the zonal boundaries. These intervals, where the nannofossil zones have not been resolved or are partially resolved, are primarily composed of carbonate ooze deposited during an ~8.5-m.y. (2.5-11 Ma) low sediment accumulation rate time interval. The absence of many of the marker species is attributed to warmer water conditions during those periods. Many of the same marker species are absent in the sediments recovered from nearby Deep Sea Drilling Project Site 155 in the Panama Basin.

Geochemistry of Early Cretaceous basaltic rocks from ODP Sites 123-765 and 123-766

The Early Cretaceous basaltic rocks obtained from Sites 765 and 766 in the eastern Indian Ocean floor were mostly iron-rich normal mid-ocean ridge basalts (N-MORB), which were derived from a depleted mantle source having strongly light rare earth element (LREE)-depleted rare-earth patterns and a high titanium/zirconium (Ti/Zr) ratio. Basaltic rocks in the upper part of the Site 765 basement section include megacrysts and gabbroic fragments of widely varying mineral chemistry. These megacrysts range from An90 plagioclase, including highly magnesian basaltic glass coexisting with augite of Mg# (= 100 Mg/[Fe+Mg]) at 85, to An50 plagioclase coexisting with hypersthene. This varying mineralogy of megacrysts and gabbroic fragments indicates that a considerable degree of fractional crystallization took place in the magma chamber. The unusual negative correlation between incompatible elements (e.g., TiO2) and FeO*/MgO observed among Site 765 basement basalts and fresh volcanic glasses suggest source-mantle heterogeneity in terms of FeO*/MgO. Strontium isotope ratios (87Sr/86Sr) of the basaltic rocks from both sites are between 0.7027 and 0.7033 and are comparable to those of mid-Indian Ocean ridge basalts (MIORB). The basalt pebbles encountered in the sedimentary section may have been transported from the basement highs nearer the Australian continent and include basaltic compositions ranging from primitive N-MORBs to evolved enriched (E)-MORBs. Their mantle source was not as depleted as that of the basement basalts. These rocks may be the products of earlier volcanism that took place during the rifting of the Australian continent.

Miocene calcareous nannofossil abundance and events in sediments of ODP Leg 189 sites

During Ocean Drilling Program (ODP) Leg 189, five sites were drilled in the Tasmanian Seaway with the objective to constrain the paleoceanographic implications of the separation of Australia from Antarctica and to elucidate the paleoceanographic developments throughout the Neogene (Shipboard Scientific Party, 2001a, doi:10.2973/odp.proc.ir.189.101.2001). Sediments ranged from Cretaceous to Quaternary in age and provided the opportunity to describe the paleoenvironments in the Tasman Seaway prior to, during, and after the separation of Australia and Antarctica. This study will focus on postseparation distribution of calcareous nannofossils through the Miocene. Miocene sediments were recovered at all five Leg 189 sites, and four of these sites were studied in detail to determine the calcareous nannofossil biostratigraphy. Hole 1168A, located on the western Tasmanian margin, contains a fairly continuous Miocene record and could be easily zoned using the Okada and Bukry (1980, doi:10.1016/0377-8398(80)90016-X) zonation. Analysis of sediments from Hole 1169A, located on the western South Tasman Rise, was not included in this study, as the recovered sediments were highly disturbed and unsuitable for further analysis (Shipboard Scientific Party, 2001c, doi:10.2973/odp.proc.ir.189.104.2001). Holes 1170A, 1171A, and 1171C are located on the South Tasman Rise south of the modern Subtropical Front (STF). They revealed incomplete Miocene sequences intersected by an early Miocene and late Miocene hiatus and could only be roughly zoned using the Okada and Bukry zonation. Similarly, Hole 1172A, located on the East Tasman Plateau, contains a Miocene sequence with a hiatus in the early Miocene and in the late Miocene and could only be roughly zoned using the Okada and Bukry (1980, doi:10.1016/0377-8398(80)90016-X) zonation. This study aims to improve calcareous nannofossil biostratigraphic resolution in this sector of the mid to high southern latitudes. This paper will present abundance, preservation, and stratigraphic distribution of calcareous nannofossils through the Miocene and focus mainly on biozonal assignment.

Strontium isotope ratios of fish teeth from ODP sites in the central North Pacific

Strontium isotopic compositions of ichthyoliths (microscopic fish remains) in deep-sea clays recovered from the North Pacific Ocean (ODP holes 885A, 886B, and 886C) are used to provide stratigraphic age control within these otherwise undatable sediments. Age control within the deep-sea clays is crucial for determining changes in sedimentation rates, and for calculating fluxes of chemical and mineral components to the sediments. The Sr isotopic ages are in excellent agreement with independent age datums from above (diatom ooze), below (basalt basement) and within (Cretaceous-Tertiary boundary) the clay deposit. The 87Sr/86Sr ratios of fish teeth from the top of the pelagic clay unit (0.7089891), indicate an Late Miocene age (5.8 Ma), as do radiolarian and diatom biostratigraphic ages in the overlying diatom ooze. The 87Sr/86Sr ratio (0.707887) is consistent with a Cretaceous-Tertiary boundary age, as identified by anomalously high iridium, shocked quartz, and sperules in Hole 886C. The 87Sr/86Sr ratios of pretreated fish teeth from the base of the clay unit are similar to Late Cretaceous seawater (0.707779-0.7075191), consistent with radiometric ages from the underlying basalt of 81 Ma. Calculation of sedimentation rates based on Sr isotopic ages from Hole 886C indicate an average sedimentation rate of 17.7 m/Myr in Unit II (diatom ooze), 0.55 m/Myr in Unit IIIa (pelagic clay), and 0.68 m/Myr in Unit IIIb (distal hydrothermal precipitates). The Sr isotopic ages indicate a period of greatly reduced sedimentation (or possible hiatus) between about 35 and 65 Ma (Eocene-Paleocene), with a linear sedimentation rate of only 0.04 m/Myr The calculated sedimentation rates are generally inversely proportional to cobalt accumulation rates and ichthyolith abundances. However, discrepancies between Sr isotope ages and cobalt accumulation ages of l0-15 Myr are evident, particularly in the middle of the clay unit IIIa (Oligocene-Paleocene).

Biostratigraphic datums and magnetic properties of ODP Leg 178 sites

During Ocean Drilling Program (ODP) Leg 178, eight holes were drilled at three sites (1095, 1096, and 1101) on the continental rise along the western Antarctic Peninsula. The rise sediments proved to be good paleomagnetic recorders and provided continuous magnetostratigraphic records at all three sites. Biosiliceous microfossils, particularly diatoms and radiolarians, were present in the upper Miocene through lower Pliocene sections. In the upper Pliocene to Pleistocene sections, biosiliceous microfossils were rare but calcareous nannofossils and foraminifers were present. This paper summarizes the biostratigraphy and magnetostratigraphy of Leg 178 continental rise sites and is the first attempt at direct calibration of Antarctic biostratigraphic events to the geomagnetic polarity timescale in the Pacific sector of the Southern Ocean.

Cation exchange capacity and water content of ODP sites from Nankai

Pore fluid chlorinity lower than seawater is often observed in accretionary wedges and one of the possible causes of pore water freshening is the smectite to illite reaction. This reaction occurs during diagenesis in the 80-150°C temperature range. Low chlorinity anomalies observed at the toe of accretionary wedges have thus been interpreted as evidence for lateral fluid migration from inner parts of the wedge and the seismogenic zone. However, temperature conditions in Nankai Trough are locally high enough for the smectite to illite transition to occur in situ. Cation exchange capacity is here used as a proxy for smectite content in the sediment and the amount of interlayer water released during the smectite to illite reaction represents in average 12 water molecules per cation charge. Water and chloride budget calculations show that there is enough smectite to explain the chlorinity anomalies by in situ reactions. The shape of the pore fluid chlorinity profiles can be explained if compaction is also taken into account in the model. Lateral flow is not needed. This argument, based solely on chloride concentration, does not imply that lateral flow is absent. However, previous estimations of lateral fluid fluxes, and of the duration of transient flow events along the de.collement, should be reconsidered.

Geochemistry of sands and sandstones in ODP Leg 126 sites

During Ocean Drilling Program Leg 126, six sites were cored in a young backarc rift basin and its flanks (rift onset 1.1-3.56 Ma) and in the forearc basin of the Izu-Bonin Arc. In the backarc area, strata are younger than about 4.5 Ma, whereas in the forearc, ages are about 0-31 Ma in sections punctuated by important Miocene unconformities. Bulk chemical analyses of volcaniclastic turbidite sands and sandstones, derived directly from the arc, were obtained from 271 atomic absorption analyses (major elements), 253 XRF analyses (trace elements) and 16 ICP-MS analyses (trace and rare-earth elements). Of the 271 samples, 78 come from the backarc area and the remainder from the forearc. The sands and sandstones reflect the igneous compositions of their sources. Most are formed of materials derived from subalkaline, low-K andesites, and dacites, although compositions range from basalt to rhyolite. Basic and acid andesites are predominant in Oligocene rocks; in contrast, Pliocene-Pleistocene sediments were derived from acid andesitic to rhyolitic sources. The oldest sandstones, estimated to have an age of about 31 Ma, were derived from an arc tholeiitic, not boninitic, source. The 26-31 Ma sandstones furthest to the north, at Sites 787 and 792, have higher relative concentrations of Ti, Zr, and Y than do those at southern Site 793. Data from younger samples indicate that, for more than 30 m.y., the average composition of volcaniclastic sediments and volcanism near Aoga Shima was more basic than to the south, near Sumisu Jima. Using the sandstones as igneous proxies, we conclude that magmas erupted along the arc have become more depleted in light-rare-earth elements (LREE) with time. There was a major change in rare-earth-element (REE) concentrations in the late Oligocene, from essentially flat patterns (normalized La/Yb about 1-1.5) to LREE-depleted patterns (normalized La/Yb about 0.5). At the same time, Zr/Y ratios decreased from about 2-4 to about 1.5-2.5. These changes may reflect a shift in provenance, or changes in the composition of the mantle wedge beneath the arc. In the backarc area, lithic clasts and glass shards of rift-facies basalt are present in sediments as old as 2.35-3.15 Ma. Two samples of mafic sand from the backarc basin have flat REE patterns (normalized La/Yb about 1.0), like some of the <1-Ma rift lavas and unlike pre-rift sand and sandstone samples. These possibly represent the local effects of sedimentary mixing of detritus from arc and backarc eruptions because no evidence from the arc itself exists to suggest a recent change in the REE content of magmas.

Soil characteristics of cryosols from two sites on King George Island, maritime Antarctica

This study presents soil temperature and moisture regimes from March 2008 to January 2009 for two active layer monitoring (CALM-S) sites at King George Island, Maritime Antarctica. The monitoring sites were installed during the summer of 2008 and consist of thermistors (accuracy of ±0.2 °C), arranged vertically with probes at different depths and one soil moisture probe placed at the bottommost layer at each site (accuracy of ± 2.5%), recording data at hourly intervals in a high capacity datalogger. The active layer thermal regime in the studied period for both soils was typical of periglacial environments, with extreme variation in surface temperature during summer resulting in frequent freeze and thaw cycles. The great majority of the soil temperature readings during the eleven month period was close to 0 °C, resulting in low values of freezing and thawing degree days. Both soils have poor thermal apparent diffusivity but values were higher for the soil from Fildes Peninsula. The different moisture regimes for the studied soils were attributed to soil texture, with the coarser soil presenting much lower water content during all seasons. Differences in water and ice contents may explain the contrasting patterns of freezing of the studied soils, being two-sided for the coarser soil and one-sided for the loamy soil. The temperature profile of the studied soils during the eleven month period indicates that the active layer reached a maximum depth of approximately 92 cm at Potter and 89 cm at Fildes. Longer data sets are needed for more conclusive analysis on active layer behaviour in this part of Antarctica.

The Paleocene-Eocene boundary in ODP Leg 208 sites

The Paleocene-Eocene thermal maximum (PETM) has been attributed to the rapid release of ~2000 * 10**9 metric tons of carbon in the form of methane. In theory, oxidation and ocean absorption of this carbon should have lowerd deep-sea pH, thereby triggering a rapid (<10,000-year) shoaling of the calcite compensation depth (CCD), followed by gradual recovery. Here we present geochemical data from five new South Atlantic deep-sea sections that constrain the timing and extent of massive sea-floor carbonate dissolution coincident with the PETM. The sections, from between 2.7 and 4.8 kilometers water depth, are marked by a prominent clay layer, the character of which indicates that the CCD shoaled rapidly (<10,000 years) by more than 2 kilometers and recovered gradually (>100,000 years). These findings indicate that a large mass of carbon (>>2000 * 10**9 metric tons of carbon) dissolved in the ocean at the Paleocene-Eocene boundary and that permanent sequestration of this carbon occurred through silicate weathering feedback.

Depth and ages of calcareous nannofossil events from ODP Leg 184 sites, South China Sea

Sites 1146 and 1148 of Ocean Drilling Program Leg 184, in the South China Sea (SCS), comprise long sediment sections with a time span from the early Oligocene to the Pleistocene. Calcareous nannofossils from these two sites were biostratigraphically studied. We recognized 53 early Oligocene to Pleistocene events that are commonly found in open sea areas and can therefore be correlated within a large geographic range. This study also revealed that a few conventionally used nannofossil events are not suitable for the SCS, and further evaluation is needed. The lower Oligocene to Pleistocene sequences recovered at Sites 1146 and 1148 were subdivided into the 4 Paleogene zones and 21 Neogene to Quaternary zones of Martini, in correlation with the Paleogene to Quaternary zones of Okada and Bukry. This provided a lower Oligocene through Pleistocene nannofossil biostratigraphic framework. A significant unconformity was recognized in the Oligocene-Miocene transition, in which the upper part of Oligocene Zone NP25 and lower part of Miocene Zone NN1 were missing. The time span of the unconformity was estimated to be ~1 m.y. Very high sedimentation rates were seen in the Oligocene, relative low values were seen in the Miocene, and the highest values were seen in the Pleistocene, which was believed to be the result of tectonic and sedimentation history of the SCS.

Paleogene and early Neogene planktonic foraminifera of ODP sites 119-738 and 119-744

A virtually complete composite history of Cenozoic pelagic sedimentation was recovered from ODP Sites 738 (62°43' S) and 744 (61°35' S), drilled during Leg 119 on the Kerguelen Plateau. An excellent magnetobiochronologic record was obtained from upper Eocene through Holocene sediments at Site 744, and an expanded lower Paleocene through lower Oligocene sequence was cored at Hole 738. Analysis of the stratigraphic distribution of over 125 planktonic foraminifer taxa from these sites reveals changes in species composition that were strongly influenced by the climatic evolution of Antarctic water masses. Early Paleocene planktonic foraminifer assemblages are nearly identical in species composition to coeval assemblages from low and middle latitude sites, showing the same patterns of post-extinction recovery and taxonomic radiation. Biogeographic isolation, revealed by the absence of tropical keeled species, became apparent by late early Paleocene time. Diversity increased near the Paleocene/Eocene boundary when keeled morozovellids immigrated to the Kerguelen Plateau. Greatest diversity (23 species) was achieved by early Eocene time, corresponding to a Cenozoic warming maximum that has been recognized in lower Eocene deep sea and terrestrial sediments worldwide. A gradual decline in diversity from the late early through middle Eocene, primarily due to the disappearance of acarininids, parallels the record of cooling paleotemperatures in Southern Ocean surface waters. Chiloguembelina-dominated assemblages appeared in the late middle Eocene and persisted through the early Oligocene as Antarctic surface waters became thermally isolated. Late Eocene and early Oligocene assemblages exhibit considerably lower diversity than the older Eocene faunas, and were dominated by chiloguembelinids, subbotinids, and catapsydracids during a time of pronounced climatic cooling and development of continental glaciation on East Antarctica. The small foraminifer Globigerinit? juvenilis replaced chiloguembelinids as the dominant taxon during the late Oligocene. Diversity increased slightly toward the end of the late Oligocene with new appearances of several tenuitellid, globoturborotalitid, and globigerinid species. The trend toward diminishing planktonic foraminifer diversity was renewed during the late early Miocene as siliceous productivity increased in the Antarctic surface waters, culminating with the reduction to nearly monospecific assemblages of Neogloboqu?drin? p?chyderm? that occur in Pliocene-Holocene biosiliceous sediments. An Antarctic Paleogene zonal scheme previously devised for ODP Sites 689 and 690 in the Weddell Sea is used to biostratigraphically subdivide the Kerguelen Plateau sequence. The definition of one Antarctic Paleogene biozone is modified in the present study to facilitate correlation within the southern high latitudes. The ages of 13 late Eoceneearly Miocene datum events are calibrated based on a magnetobiochronologic age model developed for Site 744.

Lead and strontium isotope composition, mass accumulation rates and rare earth elements of selected samples from DSDP Sites 92-597 to 92-601

Most of the Pb isotope data for the Leg 92 metalliferous sediments (carbonate-free fraction) form approximately linear arrays in the conventional isotopic plots, extending from the middle of the field for mid-ocean ridge basalts (MORB) toward the field for Mn nodules. These arrays are directed closely to the average values of Mn nodules, the composition of which reflects the Pb isotope composition of seawater (Reynolds and Dasch, 1971). Since the Leg 92 samples are almost devoid of continentally derived detritus, it can be inferred that the more radiogenic end-member is seawater. The less radiogenic end-member lies in the very middle of the MORB field, and hence can be considered to reflect the Pb isotope composition of typical ocean-ridge basalt. The array of data lying between these two end-members is most readily interpreted in terms of simple linear mixing of Pb from the two different end-member sources. According to this model, eight samples from Sites 599 to 601 contain 50 to 100% basaltic Pb. Five of these samples have compositions that are identical within the uncertainty of the analyses. We use the average of these five values to define our unradiogenic end-member in the linear mixing model. The ratios used for this average are 206Pb/204Pb = 18.425 ± 0.010; 207Pb/204Pb = 15.495 ± 0.018; 208Pb/204Pb = 37.879 ± 0.068. These values should approximate the average Pb isotope composition of discharging hydrothermal solutions, and therefore also that of the basaltic crust, over the period of time represented by these samples ( 4 m.y., from 4 to 8 Ma). Sr isotope ratios show a significant range of values, from 0.7082 to 0.7091. The lower ratios are well outside the value of 0.70910 ± 6 for modern-day seawater (Burke et al., 1982). However, most values correspond very closely to the curve of 87Sr/86Sr versus age for seawater, with older samples having progressively lower 87Sr/86Sr ratios. The simplest explanation for this progressive reduction is that recrystallization of the abundant biogenic carbonate in the sediments released older seawater Sr which was incorporated into ferromanganiferous phases during diagenesis. Leg 92 metalliferous sediments have total rare earth element (REE) contents that range on a carbonate-free basis from 131 to 301 ppm, with a clustering between 167 and 222 ppm. The patterns have strong negative Ce anomalies. Samples from Sites 599 to 601 display a slight but distinct enrichment in the heavy REE relative to the light REE, whereas those from Sites 597 to 598 show almost no heavy REE enrichment. The former patterns (those for Sites 599 to 601) are interpreted as indicating moderate diagenetic alteration of metalliferous sediments originating at the EPR axis; the latter reflect more complete diagenetic modification.