Oligocene and Neogene radiolarians from the Labrador Sea

Two sites in the Labrador Sea and one site in Baffin Bay were drilled during Leg 105. Radiolarians were recovered at all three sites, although at Site 645 (Baffin Bay), radiolarians were present in useful numbers only in the mudline sample. Radiolarians of late Neogene age were recovered at Site 646 south of Greenland, while early Oligocene and early Miocene radiolarians were recovered from the Labrador Sea at Site 647. In Site 646, radiolarian and other coarse-fraction abundances vary dramatically from sample to sample and may reflect deep-water depositional processes as well as changes in surface-water conditions. Site 647 siliceous microfossils reach their peak abundance and preservation in Core 105-647A-25R and decline gradually upward into the lower Miocene (Cores 105-647A-13R and -14R). Siliceous microfossil abundances in counts of the > 38-µm Carbonate-free coarse fraction from the siliceous interval are correlated to each other, but not to the abundance of nonbiogenic coarse-fraction components. Radiolarian abundances in specimens per gram (but not diatom abundances) are correlated to bulk opal concentration and to the organic carbon content of the sediment. The abundance of radiolarians and other siliceous microfossils within the lower Oligocene to lower Miocene is interpreted as reflecting changes in surface-water productivity. With only a few exceptions, no stratigraphic indicator species were seen in samples from either Site 646 or Site 647. The absence of both tropical/subtropical and Norwegian-Greenland Sea stratigraphic forms is due to the dominance of subarctic North Atlantic taxa in Leg 105 assemblages. The early Oligocene and early Miocene assemblages recovered at Site 647 are of particular interest, as very little material of these ages has previously been recovered from the subarctic North Atlantic region, and virtually no descriptive work has been conducted on the more endemic components of the radiolarian assemblages from these time intervals. Thus, this report concentrates on providing, at least in part, the first comprehensive documentation of early Oligocene and early Miocene radiolarians from the subarctic North Atlantic, with emphasis on basic descriptions, measurements, and photographic documentation. However, synonymic work and formal designation of new species names has been deferred until additional material from other regions can be examined. The sole exception is the emendation of Theocalyptra tetracantha Bjorklund and Kellogg 1972 to Cycladophora tetracantha n. comb.

Palynology, source vegetation, environment and age of ODP Site 188-1166 sediments

Twenty-three core catcher samples from Site 1166 (Hole 1166A) in Prydz Bay were analyzed for their palynomorph content, with the aims of determining the ages of the sequence penetrated, providing information on the vegetation of the Antarctic continent at this time, and determining the environments under which deposition occurred. Dinocysts, pollen and spores, and foraminiferal test linings were recovered from most samples in the interval from 142.5 to 362.03 meters below seafloor (mbsf). The interval from 142.5 to 258.72 mbsf yielded palynomorphs indicative of a middle-late Eocene age, equivalent to the lower-middle Nothofagidites asperus Zone of the Gippsland Basin of southeastern Australia. The Prydz Bay sequence represents the first well-dated section of this age from East Antarctica. Dinocysts belonging to the widespread "Transantarctic Flora" give a more confident late Eocene age for the interval 142.5-220.5 mbsf. The uppermost two cores within this interval, namely, those from 142.5 and 148.36 mbsf, show significantly higher frequencies of dinocysts than the cores below and suggest that an open marine environment prevailed at the time of deposition. The spore and pollen component may reflect a vegetation akin to the modern rainforest scrubs of Tasmania and New Zealand. Below 267 mbsf, sparse microfloras, mainly of spores and pollen, are equated with the Phyllocladidites mawsonii Zone of southeastern Australia, which is of Turonian to possibly Santonian age. Fluvial to marginal marine environments of deposition are suggested. The parent vegetation from this interval is here described as "Austral Conifer Woodland." The same Late Cretaceous microflora occurs in two of the cores above the postulated unconformity at 267 mbsf. In the core at 249.42 mbsf, the Late Cretaceous spores and pollen are uncontaminated by any Tertiary forms, suggesting that a clast of this older material has been sampled; such a clast may reflect transport by ice during the Eocene. At 258.72 mbsf, Late Cretaceous spores and pollen appear to have been recycled into the Eocene sediments.

Mineral and organic geochemistry from Lake Anterne sediments (North French Alps)

A high-resolution sedimentological and geochemical study was performed on a 20 m long core from the alpine Lake Anterne (2063 m a.s.l., NW French Alps) spanning the last 10 ka. Sedimentation is mainly of minerogenic origin. The organic matter quantity (TOC%) as well as its quality (hydrogen (HI) and oxygen (OI) indices) both indicate the progressive onset and subsequent stabilization of vegetation cover in the catchment from 9950 to 5550 cal. BP. During this phase, the pedogenic process of carbonate dissolution is marked by a decrease in the calcium content in the sediment record. Between 7850 and 5550 cal. BP, very low manganese concentrations suggest anoxic conditions in the bottom-water of Lake Anterne. These are caused by a relatively high organic matter (terrestrial and lacustrine) content, a low flood frequency and longer summer stratification triggered by warmer conditions. From 5550 cal. BP, a decrease in TOC, stabilization of HI and higher sedimentation rates together reflect increased erosion rates of leptosols and developed soils, probably due to a colder and wetter climate. Then, three periods of important soil destabilization are marked by an increased frequency and thickness of flood deposits during the Bronze Age and by increases in topsoil erosion relative to leptosols (HI increases) during the late Iron Age/Roman period and the Medieval periods. These periods are also characterized by higher sedimentation rates. According to palynological data, human impact (deforestation and/or pasturing activity) probably triggered these periods of increased soil erosion.

Distribution of planktonic foraminifera and other biogenic components in ODP Hole 113-693A (Figure 2)

A planktonic foraminiferal fauna of probable late Aptian age is recorded in Cores 113-693A-47R and -48R, located on the Antarctic continental margin. Moderate to highly productive surface waters and upper bathyal paleodepths are inferred from benthic and planktonic foraminifers, and other biotic and mineral components in the >63 µm size fraction.

Pedogeomorphology, geochronology and paleobotany of soil profiles obtained in the Nagqu area, central Tibet

Vast areas on the Tibetan Plateau are covered by alpine sedge mats consisting of different species of the genus Kobresia. These mats have topsoil horizons rich in rhizogenic organic matter which creates turfs. As the turfs have recently been affected by a complex destruction process, knowledge concerning their soil properties, age and pedogenesis are needed. In the core area of Kobresia pygmaea mats around Nagqu (central Tibetan Plateau, ca. 4500 m a.s.l.), four profiles were subjected to pedological, paleobotanical and geochronological analyses concentrating on soil properties, phytogenic composition and dating of the turf. The turf of both dry K. pygmaea sites and wet Kobresia schoenoides sites is characterised by an enrichment of living (dominant portion) and dead root biomass. In terms of humus forms, K. pygmaea turfs can be classified as Rhizomulls mainly developed from Cambisols. Wet-site K. schoenoides turfs, however, can be classified as Rhizo-Hydromors developed from Histic Gleysols. At the dry sites studied, the turnover of soil organic matter is controlled by a non-permafrost cold thermal regime. Below-ground remains from sedges are the most frequent macroremains in the turf. Only a few pollen types of vascular plants occur, predominantly originating from sedges and grasses. Large amounts of microscopic charcoal (indeterminate) are present. Macroremains and pollen extracted from the turfs predominantly have negative AMS 14C ages, giving evidence of a modern turf genesis. Bulk-soil datings from the lowermost part of the turfs have a Late Holocene age comprising the last ca. 2000 years. The development of K. pygmaea turfs was most probably caused by an anthropo(zoo)-genetically initiated growth of sedge mats replacing former grass-dominated vegetation ('steppe'). Thus the turfs result from the transformation of pre-existing topsoils comprising a secondary penetration and accumulation of roots. K. schoenoides turfs, however, are characterised by a combined process of peat formation and penetration/accumulation of roots probably representing a (quasi) natural wetland vegetation.

Sea surface temperture reconstruction for ODP Site 189-1172

Relative to the present day, meridional temperature gradients in the Early Eocene age (~56-53 Myr ago) were unusually low, with slightly warmer equatorial regions (Pearson et al., 2007, doi:10.1130/G23175A.1 ) but with much warmer subtropical Arctic (Sluijs et al., 2008, doi:10.1029/2007PA001495) and mid-latitude (Sluijs et al., 2007, doi:10.1038/nature06400) climates. By the end of the Eocene epoch (~34 Myr ago), the first major Antarctic ice sheets had appeared (Zachos et al., 1992, doi:10.1130/0091-7613(1992)020<0569:EOISEO>2.3.CO;2; Barker et al., 2007, doi:10.1016/j.dsr2.2007.07.027), suggesting that major cooling had taken place. Yet the global transition into this icehouse climate remains poorly constrained, as only a few temperature records are available portraying the Cenozoic climatic evolution of the high southern latitudes. Here we present a uniquely continuous and chronostratigraphically well-calibrated TEX86 record of sea surface temperature (SST) from an ocean sediment core in the East Tasman Plateau (palaeolatitude ~65° S). We show that southwest Pacific SSTs rose above present-day tropical values (to ~34° C) during the Early Eocene age (~53 Myr ago) and had gradually decreased to about 21° C by the early Late Eocene age (~36 Myr ago). Our results imply that there was almost no latitudinal SST gradient between subequatorial and subpolar regions during the Early Eocene age (55-50 Myr ago). Thereafter, the latitudinal gradient markedly increased. In theory, if Eocene cooling was largely driven by a decrease in atmospheric greenhouse gas concentration Zachos et al. (2008, doi:10.1038/nature06588), additional processes are required to explain the relative stability of tropical SSTs given that there was more significant cooling at higher latitudes.

Lithology, stratigraphy, organic carbon content, extract and liquid chromatography yields, and Rock-Eval pyrolysis at DSDP Holes 75-530A and 75-532

Seventeen sediment samples of Albian-Cenomanian to early Pliocene age from DSDP Hole 530A in the Angola Basin and six sediment samples of early Pliocene to late Pleistocene age from the Walvis Ridge were investigated by organic geochemical methods, including organic carbon determination, Rock-Eval pyrolysis, gas chromatography and combined gas chromatography/mass spectrometry of extractable hydrocarbons, and kerogen microscopy. The organic matter in all samples is strongly influenced by a terrigenous component from the nearby continent. The amount of marine organic matter present usually increases with the total organic carbon content, which reaches an extreme value of more than 10% in a Cenomanian black shale from Hole 530A. At Site 530 the extent of preservation of organic matter in the deep sea sediments is related to mass transport down the continental slope, whereas the high organic carbon contents in the sediments from Site 532 reflect both high bioproductivity in the Benguela upwelling regime and considerable supply of terrigenous organic matter. The maturation level of the organic matter is low in all samples.

Mineral composition, major element oxides and trace element concentration of sediments from ODP Leg 180 sites

Middle Miocene to Holocene fine-grained argillaceous sediments (clays, claystones/muds, and mudstones), which volumetrically dominated the sediment recovery in the Woodlark Basin during Leg 180, were chemically analyzed for major elements, trace elements, and some rare earth elements by X-ray fluorescence. Selected samples also underwent X-ray diffraction (XRD) analysis for mineral determination. The results shed light on sediment provenance when combined with shipboard sediment descriptions, smear slide study, and XRD. The oldest sediments recovered (Site 1108) of middle-late Miocene age include volcanogenic muds with distinctive high MgO and K2O, indicative of a relatively basic calc-alkaline source related to an inferred Miocene forearc succession. The forearc basement, composed of diabase and basalt, was locally exposed (Site 1109) and eroded in the late Miocene (<5.4-9.93 Ma), giving rise to fluvial conglomerates (Sites 1109, 1115, and 1118). Chemically distinctive fine-grained claystones and siltstones (with relatively high Ti, low K) are compatible with derivation from tropically weathered basic igneous rocks, correlated with the Paleogene Papuan ophiolite. Overlying latest Miocene-Pleistocene fine-grained sediments throughout the Woodlark Basin were partly derived from calc-alkaline volcanic sources. However, relatively high abundances of Al2O3 and related element oxides (K2O and Na2O) and trace elements (e.g., Rb and Y) reflect an additional terrigenous input throughout the basin, correlated with pelitic metamorphic rocks exposed on Papua New Guinea and adjacent areas. In addition, sporadic high abundances of Cr and Ni, some other trace metals, and related minerals (talc, crysotile, and chlorite) reflect input from an ophiolitic terrain dominated by ultramafic rocks, correlated with the Paleogene Papuan ophiolite. The source areas possibly included serpentinized ultramafic ophiolitic rocks exposed in the Papua New Guinea interior highlands. Chemical evidence further indicates that fine-grained terrigenous sediment reached the Woodlark Basin throughout its entire late Miocene-Holocene history. Distinctive high-K volcanogenic muds rich in tephra and volcanic ash layers that appear at <2.3 Ma (Sites 1109 and 1115) are indicative of high-K calc-alkaline volcanic centers, possibly located in the Dawson Strait, Moresby Strait, or Dobu Seamount area. Chemical diagenesis of fine-grained sediments within the Woodlark Basin is reflected in clay neomorphism and localized formation of minerals including dolomite, ankerite, and zeolite but has had little effect on the bulk chemical composition of most samples.

Bolboforma of Eocene and lower Oligocene sediments of Maud Rise, Weddell Sea

Five species of Bolboforma have been found in middle Eocene to lower Oligocene sediments from Maud Rise, Weddel Sea, Antarctica (Leg 113, Holes 689B and 690B), the first reported Bolboforma from the Antarctic Paleogene. The previous oldest known occurrences of Bolboforma in the world's oceans were of late Eocene age and this study extends the known range to the middle middle Eocene (~ 44 Ma). Highest species diversity of Bolboforma in the Weddell Sea region of Antarctica occurred during the late Eocene, after which all but one important species disappeared before the Eocene/Oligocene boundary (36.5 Ma). The remaining species, B. irregularis, disappeared soon after, during the earliest Oligocene. The disappearance of Bolboforma in this region of Antarctica coincided with significant climatic cooling that occurred at the end of the Eocene and during the earliest Oligocene, when subpolar replaced temperate conditions. Bolboforma is not known from younger sediments in the Antarctic except for a brief interval during the late early Miocene, an interval of Neogene climatic warmth. The presence of Bolboforma in Eocene to lower Oligocene sequences in the Weddell Sea region of Antarctica is therefore consistent with this taxon's previously recognized association with temperate water masses. Bolboforma is of limited biostratigraphic value at present, because of relatively long stratigraphic ranges and diachronous extinctions. Previous suggestions that Bolboforma represents an encystment stage of phytoplankton require further critical study because the deposition, in large numbers, at paleodepths up to 2250 m in the open ocean, is an unlikely strategy for an encystment phase of a phytoplanktonic organism. A new species, Bolboforma antarctica, is described, exhibiting a stratigraphic range from middle middle Eocene to the upper Eocene (~ 44 to 39 Ma).

Miocene to Quaternary paleoenvironments and uplift history on the mid Norwegian shelf

Based on benthic and planktic foraminifera, Bolboforma, oxygen isotope measurements and seismic data, major changes in Miocene, Pliocene and Pleistocene paleoenvironments on the mid Norwegian shelf are discussed and a possible scenario of the late Cenozoic uplift history is given. The dating of the Neogene sequence has been done using foraminifera and Bolboforma. Four main assemblage zones have been identified with nine distinct subzones. Most of the Miocene sequence is preserved. The lower Miocene sediments contain only siliceous microfossils. A period of high fertility and upwelling in the study area prevailed. The early Miocene-early mid Miocene (15 Ma?) change from a siliceous to a calcareous rich microfauna, dominated by Nonion barleeanum, can be related to increased surface-water circulation due to overflow across the Iceland-Faeroe ridge. During the Miocene the temperature decreased in the study area. Evidence of increased amounts of coarser sediments may suggest that an uplift of the mainland areas occurred during the mid-late Miocene. Lower Pliocene sediments contain a foraminiferal fauna that seems to occur in slightly colder conditions than the late Miocene fauna suggesting a further cooling. Possibly, Arctic waters entered the study area in the early Pliocene. A very marked change in lithology (from compacted claystone to unconsolidated diamicton), fauna (from deep dwelling to shallow dwelling species) and seismic signature (from flat lying reflectors to prograding clinoforms) occurs during the mid?-late Pliocene. A two step cooling trend is indicated by the microfauna of these prograding wedges. (1) The first wedge buildups might have been associated with an uplift of the mainland during the early late Pliocene (mid Pliocene, ca. 4 Ma). However, the age determination is somewhat uncertain and may very well be of late Pliocene age. (2) The second step of wedge buildup is associated with a glacial phase where the dominating microfauna exists of arctic species. Large continental ice sheets might have occurred at this time reaching coastal areas and that possibly many of the geomorphological features such as the strandflat were made during this episode. The Pleistocene epoch is represented by an increased percentage of boreal foraminifera intermingled with high arctic species which indicates that interglacial-glacial cycles prevailed and the dynamics of the glacier system changed.

(Table 3) Age-related trends of desert pavement properties in the Transantarctic Mountains

Compared to mid-latitude deserts, the properties, formation and evolution of desert pavements and the underlying vesicular layer in Antarctica are poorly understood. This study examines the desert pavements and the vesicular layer from seven soil chronosequences in the Transantarctic Mountains that have developed on two contrasting parent materials: sandstone-dolerite and granite-gneiss. The pavement density commonly ranges from 63 to 92% with a median value of 80% and does not vary significantly with time of exposure or parent material composition. The dominant size range of clasts decreases with time of exposure, ranging from 16-64 mm on Holocene and late Quaternary surfaces to 8-16 mm on surfaces of middle Quaternary and older age. The proportion of clasts with ventifaction increases progressively through time from 20% on drifts of Holocene and late Quaternary age to 35% on Miocene-aged drifts. Desert varnish forms rapidly, especially on dolerite clasts, with nearly 100% cover on surfaces of early Quaternary and older age. Macropitting occurs only on clasts that have been exposed since the Miocene. A pavement development index, based on predominant clast-size class, pavement density, and the proportion of clasts with ventifaction, varnish, and pits, readily differentiated pavements according to relative age. From these findings we judge that desert pavements initially form from a surficial concentration of boulders during till deposition followed by a short period of deflation and a longer period of progressive chemical and physical weathering of surface clasts. The vesicular layer that underlies the desert pavement averages 4 cm in thickness and is enriched in silt, which is contributed primarily by weathering rather than eolian deposition. A comparison is made between desert pavement properties in mid-latitude deserts and Antarctic deserts.

Paleomagnetic of ODP Leg 133 holes

Paleomagnetic and rock-magnetic analyses from discrete samples of carbonate sites on the Queensland Plateau were used to determine magnetic polarity reversal stratigraphy and the nature of magnetization in these sediments. Magnetic polarity zones were correlated with the geomagnetic polarity time scale in the upper portions of cores at Sites 812 through 814, usually back to a late Pliocene age. Loss of reliable directional data was coincidental with a major decrease in magnetic intensity, below which, no stable polarity zones could be identified. The intensity reduction is either an in-situ alteration of magnetic grains, or an input signal representing progressive increase in the magnetic component of Queensland Plateau sediments. Although not conclusive at this point, the geochemical conditions and differing age of intensity reduction support the former hypothesis. Rock-magnetic analysis of carbonate sediments suggests that ultrafine-grained magnetite or maghemite crystals is an important carrier of remanence and may be biogenic in origin. Application of a recently calibrated anhysteretic remanent magnetization test to assess configuration of single-domain crystal within a natural matrix indicates that cementation (ooze-chalk-limestone) may be important in post-depositional changes affecting magnetostatic grain interaction.

Chemical composition of phosphorite nodules off Peru

Phosphorite nodules collected during Cruise 8 of R/V Dmitry Mendeleev off the Peruvian coast are represented by three lithologic types: friable, compacted, and solid. As the nodules are progressively compacted, contents of phosphate components increase and of non-phosphate components decrease. Isotope composition of uranium in the friable nodules is the same as in ocean water, and diatoms contained in the nodules are represented by recent species indicating Late Quaternary age of the nodules.