Porosity and sound velocity measured in sediment core CIROS-1

The CIROS-1 drillhole, which in 1986 reached a depth of 700 m below the seafloor, is still the only deep hole that can provide information on the velocity structure of the upper crust in McMurdo Sound and the Ross Sea, Antarctica. A careful review and quality control of the downhole logging data of CIROS-1 resulted in a new porosity depth function that is consistent with porosity data from the MSSTS-1 and CRP-1 drillholes. Using existing porosity-velocity equations, it was possible for the first time to obtain reliable velocity information for the upper 700 m of strata off the Victoria Land coast. The calculated synthetic seismograms, based on downhole velocity and density data, fit very well with the existing seismic lines IT90A-71, PD90-12, and NBP9601-89. The quality of the correlation confirms that the average velocity of the top 700 m of strata is about 2 000-2 300 m/s, and not 2 800-3 000 m/s, as was previously assumed. In consequence, these distinctly lower velocities result in shallower depths for the seismic unconformities V3/V4 andV4/V5 and thus may have important implications for further drilling off Cape Roberts.

Molecular hydrogen (H2) mixing ratio and stable isotopic composition (dD) at the Cabauw tall tower in the Netherlands (2008-2012)

Measurements of the stable isotopic composition (dD(H2) or dD) of atmospheric molecular hydrogen (H2) are a useful addition to mixing ratio (X(H2)) measurements for understanding the atmospheric H2 cycle. dD datasets published so far consist mostly of observations at background locations. We complement these with observations from the Cabauw tall tower at the CESAR site, situated in a densely populated region of the Netherlands. Our measurements show a large anthropogenic influence on the local H2 cycle, with frequently occurring pollution events that are characterized by X(H2) values that reach up to 1 ppm and low dD values. An isotopic source signature analysis yields an apparent source signature below -400 per mil, which is much more D-depleted than the fossil fuel combustion source signature commonly used in H2 budget studies. Two diurnal cycles that were sampled at a suburban site near London also show a more D-depleted source signature (-340 per mil), though not as extremely depleted as at Cabauw. The source signature of the Northwest European vehicle fleet may have shifted to somewhat lower values due to changes in vehicle technology and driving conditions. Even so, the surprisingly depleted apparent source signature at Cabauw requires additional explanation; microbial H2 production seems the most likely cause. The Cabauw tower site also allowed us to sample vertical profiles. We found no decrease in (H2) at lower sampling levels (20 and 60m) with respect to higher sampling levels (120 and 200m). There was a significant shift to lower median dD values at the lower levels. This confirms the limited role of soil uptake around Cabauw, and again points to microbial H2 production during an extended growing season, as well as to possible differences in average fossil fuel combustion source signature between the different footprint areas of the sampling levels. So, although knowledge of the background cycle of H2 has improved over the last decade, surprising features come to light when a non-background location is studied, revealing remaining gaps in our understanding.