Geochemistry of gas hydrates of DSDP Hole 84-570

During Deep Sea Drilling Project (DSDP) Leg 84 a core 1 m long and 6 cm in diameter of massive gas hydrate was unexpectedly recovered at Site 570 in upper slope sediment of the Middle America Trench offshore of Guatemala. This core contained only 5-7% sediment, the remainder being the solid hydrate composed of gas and water. Samples of the gas hydrate were decomposed under controlled conditions in a closed container maintained at 4°C. Gas pressure increased and asymptotically approached the equilibrium decomposition pressure for an ideal methane hydrate, CH4.5-3/4H2O, of 3930 kPa and approached to this pressure after each time gas was released, until the gas hydrate was completely decomposed. The gas evolved during hydrate decomposition was 99.4% methane, ~0.2% ethane, and ~0.4% CO2. Hydrocarbons from propane to heptane were also present, but in concentrations of less than 100 p.p.m. The carbon-isotopic composition of methane was -41 to -44 per mil, relative to PDB standard. The observed volumetric methane/water ratio was 64 or 67, which indicates that before it was stored and analyzed, the gas hydrate probably had lost methane. The sample material used in the experiments was likely a mixture of methane hydrate and water ice. Formation of this massive gas hydrate probably involved the following processes: (i) upward migration of gas and its accumulation in a zone where conditions favored the growth of gas hydrates, (ii) continued, unusually rapid biological generation of methane, and (iii) release of gas from water solution as pressure decreased due to sea level lowering and tectonic uplift.

Hydro-sedimentary parameters measurements within the proglacial area of the Bossons glacier (Mont-Blanc massif, France)

This dataset presents hydro-sedimentary data within the Bossons glacier proglacial area. Bossons glacier is rapidly retreating and its proglacial area is deglaciated for ~ 30 years. It is an intriguing location to study periglacial, proglacial and subglacial erosion processes which requires estimating Total Dissolved Solid (TDS) and Total Suspended Solid (TSS) concentrations, and discharge. Measurements were performed at three distinct locations within Bosson glacier watershed : Bossons downstream (BDS), Bossons upstream (BUS) and Crosette (CRO). The latter is located at the glacier termini whereas BDS and BUS stations are farther downstream from the glacier, at 1.5 and 1.15 km, respectively .