Carbon geochemistry in serpentinites from and beneath the Lost City Hydrothermal Field

The carbon geochemistry of serpentinized peridotites and gabbroic rocks recovered at the Lost City Hydrothermal Field (LCHF) and drilled at IODP Hole 1309D at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) was examined to characterize carbon sources and speciation in oceanic basement rocks affected by long-lived hydrothermal alteration. Our study presents new data on the geochemistry of organic carbon in the oceanic lithosphere and provides constraints on the fate of dissolved organic carbon in seawater during serpentinization. The basement rocks of the Atlantis Massif are characterized by total carbon (TC) contents of 59 ppm to 1.6 wt% and 17863_TC values ranging from -28.7? to +2.3?. In contrast, total organic carbon (TOC) concentrations and isotopic compositions are relatively constant (d13C_TOC: -28.9? to -21.5?) and variations in d13CTC reflect mixing of organic carbon with carbonates of marine origin. Saturated hydrocarbons extracted from serpentinites beneath the LCHF consist of n-alkanes ranging from C15 to C30. Longer-chain hydrocarbons (up to C40) are observed in olivine-rich samples from the central dome (IODP Hole 1309D). Occurrences of isoprenoids (pristane, phytane and squalane), polycyclic compounds (hopanes and steranes) and higher relative abundances of n-C16 to n-C20 alkanes in the serpentinites of the southern wall suggest a marine organic input. The vent fluids are characterized by high concentrations of methane and hydrogen, with a putative abiotic origin of hydrocarbons; however, evidence for an inorganic source of n-alkanes in the basement rocks remains equivocal. We propose that high seawater fluxes in the southern part of the Atlantis Massif likely favor the transport and incorporation of marine dissolved organic carbon and overprints possible abiotic geochemical signatures. The presence of pristane, phytane and squalane biomarkers in olivine-rich samples associated with local faults at the central dome implies fracture-controlled seawater circulation deep into the gabbroic core of the massif. Thus, our study indicates that hydrocarbons account for an important proportion of the total carbon stored in the Atlantis Massif basement and suggests that serpentinites may represent an important (as yet unidentified) reservoir for dissolved organic carbon (DOC) from seawater.

(Table 2) Paleoclimate reconstruction for palynology samples of Turkey

Palynofloras of the Kocaçay and Cumaovasi basins in western Turkey that belong to a time-span from the late Early to late Middle Miocene (the late Burdigalian-Serravallian) are studied and compared with published palynofloras of Europe and Turkey. Palynological data and numerical climatic results obtained by the coexistence approach indicate palaeoclimate changed from warm subtropical to temperate during the late Burdigalian-Serravallian. Moreover, the palaeoclimates of the Kocacay and Cumaovasi basins are compared with continental palaeoclimatic records of coal-bearing sediments in western Turkey and current temperatures in the Izmir region. According to this comparison, palaeoclimatic results of these basins and other localities in western Turkey show a distinct difference as a result of orographic change. The palaeovegetation in the Kocaçay and Cumaovasi basins during the studied time-span was affected by palaeotopography and palaeoclimate. In these basins mixed mesophytic, coniferous forests, and swamp palaeovegetation generally predominated during the late Early-early Middle Miocene. The role of the herbaceous taxa increased at the end of the late Middle Miocene (the Serravallian) in the Kocaçay and Cumaovasi basins. It is obvious from the palynomorph data of these basins that grassland palaeovegetation started to expand in the late Middle Miocene. Unlike in Central Europe, where late Burdigalian and Langhian represent a period of outstanding warmth, the so-called Mid-Miocene Climatic Optimum, cold month mean temperatures reconstructed in this study point to an ongoing cooling trend, already from the late Burdigalian onwards, possibly related to increasing terrestrial conditions in the study area.

Grain size composition of 275 sediment profiles from the Arctic seas

This data set contains grain size analyses of bottom sediments collected by scientists from the V.P. Zenkovich Laboratory of Shelf and Sea Coasts (P.P. Shirshov Institute of Oceanology, Russian Academy of Sciences) during the Project ''Arctic Shelf of the Eurasia in the Late Quaternary'' in a number of expeditions to the Barents, Kara, East Siberian and Chukchi Seas on board the research vessels R/V Professor Shtokman, H/V Dmitry Laptev, H/V Malygin, and icebreaker Georgy Sedov since 1978. The analyses have been carried out according to the methods published by Petelin (1967) in the Analytical Laboratory of the P.P. Shirshov Institute of Oceanology. Archiving and electronic publication was performed through a data rescue by Evgeny Gurvich in 2003.