The early Eocene global warming events: Implications from ODP Leg 208 Walvis Ridge depth transect

Five sections drilled in multiple holes over a depth transect of more than 2200 m at the Walvis Ridge (SE Atlantic) during Ocean Drilling Program (ODP) Leg 208 resulted in the first complete early Paleogene deep-sea record. Here we present high-resolution stratigraphic records spanning a ~4.3 million yearlong interval of the late Paleocene to early Eocene. This interval includes the Paleocene-Eocene thermal maximum (PETM) as well as the Eocene thermal maximum (ETM) 2 event. A detailed chronology was developed with nondestructive X-ray fluorescence (XRF) core scanning records and shipboard color data. These records were used to refine the shipboard-derived spliced composite depth for each site and with a record from ODP Site 1051 were then used to establish a continuous time series over this interval. Extensive spectral analysis reveals that the early Paleogene sedimentary cyclicity is dominated by precession modulated by the short (100 kyr) and long (405 kyr) eccentricity cycles. Counting of precession-related cycles at multiple sites results in revised estimates for the duration of magnetochrons C24r and C25n. Direct comparison between the amplitude modulation of the precession component derived from XRF data and recent models of Earth's orbital eccentricity suggests that the onset of the PETM and ETM2 are related to a 100-kyr eccentricity maximum. Both events are approximately a quarter of a period offset from a maximum in the 405-kyr eccentricity cycle, with the major difference that the PETM is lagging and ETM2 is leading a 405-kyr eccentricity maximum. Absolute age estimates for the PETM, ETM2, and the magnetochron boundaries that are consistent with recalibrated radiometric ages and recent models of Earth's orbital eccentricity cannot be precisely determined at present because of too large uncertainties in these methods. Nevertheless, we provide two possible tuning options, which demonstrate the potential for the development of a cyclostratigraphic framework based on the stable 405-kyr eccentricity cycle for the entire Paleogene.

Barium intensities and tie points between holes of Leg 208

The Paleocene - Eocene thermal maximum (PETM) is one of the best known examples of a transient climate perturbation, associated with a brief, but intense, interval of global warming and a massive perturbation of the global carbon cycle from injection of isotopically light carbon into the ocean-atmosphere system. One key to quantifying the mass of carbon released, identifying the source(s), and understanding the ultimate fate of this carbon is to develop high-resolution age models. Two independent strategies have been employed, cycle stratigraphy and analysis of extraterrestrial Helium (HeET), both of which were first tested on Ocean Drilling Program (ODP) Site 690. Both methods are in agreement for the onset of the PETM and initial recovery, or the clay layer ("main body"), but seem to differ in the final recovery phase of the event above the clay layer, where the carbonate contents rise and carbon isotope values return toward background values. Here we present a state-of-the-art age model for the PETM derived from a new orbital chronology developed with cycle stratigraphic records from sites drilled during ODP Leg 208 (Walvis Ridge, Southeastern Atlantic) integrated with published records from Site 690 (Weddell Sea, Southern Ocean, ODP Leg 113). During Leg 208, five Paleocene - Eocene (P-E) boundary sections (Sites 1262 to 1267) were recovered in multiple holes over a depth transect of more than 2200 m at the Walvis Ridge yielding the first stratigraphically complete P-E deep-sea sequence with moderate to relatively high sedimentation rates (1 to 3 cm/kyr). A detailed chronology was developed with non-destructive X-ray fluorescence (XRF) core scanning records on the scale of precession cycles, with a total duration of the PETM now estimated to be ~ 170 kyr. The revised cycle stratigraphic record confirms original estimates for the duration of the onset and initial recovery, but suggests a new duration for the final recovery that is intermediate to the previous estimates by cycle stratigraphy and HeET.