Primary mineralogy of ODP Leg 115 basalts

Basement rocks were recovered at four sites on Leg 115 along the Reunion hotspot track in the western Indian Ocean. Plate tectonic reconstructions indicate that the drilled structures formed in three different volcanic environments. Sites 706 and 713 from the eastern side of the Saya de Malha Bank and the northern end of the Chagos Bank, respectively, are on a large volcanic platform analogous to Iceland on the Mid-Atlantic Ridge. Lavas at Site 707 on the northwestern side of the Saya de Malha Bank erupted during the early stages of rifting of the Seychelles from India. Basalts from Site 715 were erupted onto an isolated oceanic island that was distant from ocean ridges and continents much as Reunion Island is today. Many of the rocks were examined in thin section and found to be primarily augite-plagioclase basalts with minor olivine and rare opaque oxides. Site 715 is unusual in that it contains a variety of basalts including olivine-rich and aphyric Fe-Ti basalts. At each of the four sites the rocks were grouped into chemical types (units) on the basis of ship- board bulk-rock analyses and at least one thin section from each chemical unit was analyzed by electron microprobe. The plagioclase and augite chemistry reflects the bulk-rock chemistry and, in general, these minerals were in equilibrium with their host magmas at the time the basalts were quenched. Olivine was rarely preserved, but where it is still present it also appears to have crystallized in equilibrium with the host magma. At three of the drill sites plagioclase phenocrysts or megacrysts that crystallized from a primitive magma are also present. The one site (715) that does not contain these primitive plagioclase phenocrysts is also the site that appears to have been influenced the least by ocean- ridge or Deccan-type magmas. Site 715, furthermore, has a mineralogy that is dominated by olivine as compared with the plagioclase-rich lavas of the other sites.

Holocene sedimentation in the Strait of Otranto, Mediterranean Sea

An extensive radiograph study of 24 undisturbed, up to 206-cm long box and gravity cores from the western part of the Strait of Otranto revealed a great variety of primary bedding structures and secondary burrowing features. The regional distribution of the sediments according to their structural, textural, and compositional properties reflects the major morphologic subdivisions of the strait into shelf, slope, and trough bottom (e.g., the bottom of the northern end of the Corfu-Kephallinia Trough, which extends from the northeastern Ionian Sea into the Strait of Otranto): (1) The Apulian shelf (0 to -170m) is only partly covered by very poorly sorted, muddy sands without layering. These relict(?) sands are rich in organic carbonate debris and contain glauconite and reworked (?Pleistocene) ooids. (2) The slope sediments (-170 to -1,000 m) are poorly sorted, sandy muds with a high degree of burrowing. One core (OT 5) is laminated and shows slump structures. An origin of these slumped sediment masses from older deposits higher on the slope was inferred from their abnormal compaction, color, texture, organic content, and mineral composition. (3) Cores from the northern end of the Corfu-Kephallinia Trough (-980 to -1,060 m) display a few graded sand layers, 2-5 cm (maximum 30 cm) thick with parallel and ripple-cross-laminations, deposited by oceanic bottom or small-scale turbidity currents. They are intercalated with homogeneous lutite. (4) Hemipelagic sediments prevail in the more southerly part of the Corfu-Kephallinia Trough and on the "Apulian-Ionian Ridge", the southern submarine extension of the Apulian Peninsula. Below a core depth of 160 cm, these cores have a laminated ("varved") zone, representing an Early Holocene (Boreal-Atlanticum) "stagnation layer" (14C age approximately 9,000 years). The terrigenous components of the surface sediments as well as those of the deeper sand layers can be derived from the Apulian shelf and the Italian mainland (Cretaceous Apulian Plateau and Gargano Mountains, southern Apennines, volcanic province of the Monte Vulture). Indicated by the heavy mineral glaucophane, a minor proportion of the sedimentary material is probably of Alpine origin. If this portion is considered to be first-cycle clastic material it reaches the Strait of Otranto after a longitudinal transport of 700 km via the Adriatic Sea. The lack of phyllosilicates in the coarse- to medium-grained shelf samples might be explained by the activity of the "Apulian Current" (surface velocities up to 4 knots) which in the past possibly has affected the bottom almost down to depths of the shelf edge. The percentage of planktonic organisms, and also the plankton: benthos ratio in the sediments is a useful indicator for bathymetry (depth zonation).

Water, bottom deposits, and macrobenthos in the south part of the East Siberian Sea in September 2003

Macrobenthos biomass and bottom biocoenoses were studied in the sublittoral zone of the southern East Siberian Sea. The macrobenthos is characterized by relatively high abundance (from 30 to 2680 #/m**2), biomass (from 0.25 to 578.8 g/m**2), and diversity (83 species in total). Lateral distribution of macrobenthos biomass correlates with a substrate type and salinity and is substantially higher in areas washed by the Arctic water mass than in estuaries with mixed fresh and Arctic waters and shows a tendency to decreasing in the convergence zone of different water masses. The highest macrobenthos biomass is observed in cores of water masses in the Long Strait area and in the eastern part of the sea.

Opal concentration of ODP Leg 178 holes

Neogene to Quaternary records of biogenic opal contents and opal accumulation rates are presented for Sites 1095, 1096, and 1101, which were drilled during Ocean Drilling Program Leg 178 in the Bellingshausen Sea, a marginal sea in the eastern Pacific sector of the Southern Ocean. The opal records in the drift sediments on the continental rise west of the Antarctic Peninsula provide signals of paleoproductivity, although they are influenced by dissolution in the water column and the sediment column. Opal contents at Sites 1095, 1096, and 1101 show similar long-term trends through the Neogene and Quaternary, whereas the opal accumulation rates exhibit marked discrepancies, which are caused by local differences in opal preservation linked to local variations of bottom current-induced supply of lithogenic detritus. We used a regression describing the relationship between opal preservation and sedimentation rate to extract the signal of primary opal deposition on the seafloor in the Bellingshausen Sea from the opal accumulation in the drift deposits. On long-term timescales, the reconstructed opal depositional rates show patterns similar to those of the opal contents and a much better coherency between the different locations on the Antarctic Peninsula continental rise. Therefore, the estimated opal depositional rates are suggested to represent a suitable proxy for paleoproductivity in the drift setting of the Bellingshausen Sea. Supposing that the sea-ice coverage within the Antarctic Zone was the main factor controlling biological productivity in the Bellingshausen Sea, and thus the estimated opal depositional rates on the continental rise, we reconstructed paleoceanographic long-term changes during the Neogene and Quaternary considering the climatic control on regional and global scales. Slightly enhanced opal depositional rates during the late Miocene are interpreted to indicate warmer climatic conditions in the vicinity of the Antarctic Peninsula than at present. The contribution of heat from the Northern Component Water (NCW) into the Southern Ocean seems only to have played a subordinate role during that time. High opal depositional rates during the early Pliocene document a strong reduction of sea-ice coverage and relatively warm climatic conditions in the Bellingshausen Sea. The early onset of the Pliocene warmth points to a positive feedback of regional Antarctic climate on the global thermohaline circulation. A decrease of opal deposition between 3.1 and 1.8 Ma likely reflects sea-ice expansion in response to reduced NCW flow, caused by the onset and intensification of Northern Hemisphere glaciation. Throughout the Quaternary, a relatively constant level of opal depositional rates in the Bellingshausen Sea indicates stable climatic conditions in the Antarctic Peninsula area.

Temporal evolution of organic carbon and lipid content and derived SST of sediment core GIK23258-2, Norwegian Sea

Lipids are used for the evaluation of the different organic matter contributions in the north eastern Norwegian sea (M23258 site; 75ºN, 14ºE) over the last 15,000 years. Development of a mass balance model based on the down core quantification of the C37 alkenones, the odd carbon numbered n-alkanes (Aodd) and the unresolved complex mixture of hydrocarbons (UCM) has allowed three main organic matter inputs involving marine, continental and ancient reworked organic matter to be recognized. The model shows a good agreement between measured and reconstructed TOC values. Similarly, a strong parallelism is observed between predicted components such as marine TOC and carbonate content (CaCO3), which was determined independently. Representation of the model results within a time-scale based on 15 AMS-14C measurements shows that the main changes in organic matter constituents are coincident with the major climatic events of the last 15,000 a. Thus, the predominance of reworked organic matter is characteristic of Termination Ia (up to 70%), continental organic matter was dominant during the Bølling-Allerød (B-A) and Younger Dryas (YD) periods (about 85%) and a strong increase of marine organic matter occurred in the Holocene (between 50 and 75%). This agreement reflects the main hydrographic changes that determined the deposition of sedimentary materials during the period studied: ice-rafted detritus from the Barents continental platform, ice-melting waters from the Arctic fluvial system discharging into the Barents sea and dominance of north Atlantic currents, respectively. In this respect, the high-resolution down core record resulting from the mass balance and lipid measurements allows the identification of millennial-scale events such as the increase of reworked organic matter at the final retreat of the Barents ice sheet at the end of the deglaciation period (Termination Ib).

Bitumoids and methane in bottom sediments of the northeast Black Sea

Complex investigations of recent and ancient Black Sea sediments from the outer shelf, continental slope, and deep-water basin of the Russian Black Sea sector have been carried out. Samples were collected during Cruise 100 of R/V Professor Shtokman organized by the P.P. Shirshov Institute of Oceanology (March 2009) and expedition of UZHMORGEO (summer 2006). Rates of the main anaerobic processes during diagenesis (sulfate reduction, dark CO2 assimilation, methanogenesis, and methane oxidation) were studied for the first time in sediment cores of the studied area. Two peaks in the rate of microbial processes and two sources of these processes were identified: the upper peak near the water-sediment contact is related to solar energy (OM substrate of the water column) and the lower peak at the base of ancient Black Sea sediments with high(>1 mmol) methane concentration related to energy of anaerobic methane oxidation. New labile OM formed during this process is utilized by other groups of microorganisms. According to experimental data, daily rate of anaerobic methane oxidation is many times higher than that of methanogenesis, which unambiguously indicates migration nature of the main part of methane.

Age model and stable isotope record of eastern equatorial Pacific sediment cores

Six deep sea cores from the eastern equatorial Pacific (EEP) were analyzed for planktonic foraminifera and stable isotopes in order to reconstruct sea surface temperatures (SST) for the last 40 ka. South of the Equatorial Front the abundance of Globorotalia inflata increased, and SST decreased by >5°C (core ODP846B), creating a stronger SST meridional gradient and advection of the Peru Current than present for the ~16-35 ka interval. A sharper SST meridional gradient forced stronger Choco jet events and a moisture increase in western Colombia, which supplied, through the San Juan River and the south-flowing equatorial and the Peru-Chile countercurrents, abundant hemipelagic quartz over the northern Peru basin (core TR163-31B). The Choco jet, and its associated mesoscale convective cells, provoked an increase in snow precipitation over the Central Cordillera of Colombia and the advance of the Murillo glacier. In synchrony with the intensified Choco jet events, the "dry island" effect over the Eastern Cordillera of Colombia intensified, and the level of Fuquene Lake dropped.

Phytoplankton in the surface desalted lens of the Kara Sea

Phytoplankton of a surface strongly desalinated water lens was investigated on the basis of materials collected during Cruise 57 of R/V Akademik Mstislav Keldysh in September 2007. The lens with salinity <18 psu had area of ca. 19000 sq. km and was located in the northwestern part of the Kara Sea near the eastern coast of Novaya Zemlya. It was a specific biotope that had been isolated from surrounding waters for more than three months. In the investigated area 66 algae species were identified. The maximal species diversity was found in the upper layers of the desalinated lens, where species number was 1.5 to 3 times higher than in other parts of the water column. Phytoplankton abundance in the upper layers of the lens was 1.5 to 4.5 times higher than in its lower part and generally higher than below the picnocline. Diatoms were the most abundant group in the upper layers of the lens, while flagellates dominated in the subpicnocline part of the water column. Maximal values of phytoplankton biomass were observed everywhere in the upper layers of the lens, where they were 1.2 to 3.7 times higher than in the lower part of the lens and 1.3 to 7.2 times higher than in the layer below the picnocline. Dinoflagellates generally gave the most contribution to total phytoplankton biomass. Phytoplankton of the desalinated surface lens in the northwestern part of the Kara Sea by its composition and quantitative parameters had the nearest resemblance to a phytocenosis that we observed two weeks later at a shallow desalinated shelf closely adjacent to the Ob estuary.

Abundance of benthic Foraminifera in the Kara Sea

Taxonomic composition and structure of assemblages of the present-day benthic Foraminifera in the Kara Sea has been studied on the base of 37 samples of surface sediments. Three assemblages have been distinguished by composition of dominant species. The assemblage Cribrostomoides subglobosus-Tritaxis nana with prevalence of agglutinating forms, typical for abyssal areas of the World Ocean, occurs in brown oozes in the deep western part of the sea at depths 70-375 m under conditions of considerable bottom stratification. The assemblage Elphidium clavatum-Cassidulina reniforme consists predominantly of species with calcareous shells and is characterized by a wide range of species; this assemblage occurs in the eastern part of the sea at depths 30-90 m in a well-aerated area. Species typical for sublittoral areas of polar regions are dominant. The assemblage Elphidium clavatum-Haynesina orbiculare occupies the littoral estuarine part of the sea. This assemblage is poor in species and not abundant, and it occurs under influence of freshened water masses undersaturated with dissolved carbonaceous matter.

Benthic foraminiferal assemblages of the Barents Sea

Foraminiferal assemblages were studied in northern Barents Sea core ASV 880 along with oxygen and carbon isotope measurements in planktonic (N. pachyderma sin.) and benthic (E. clavatum) species. AMS C-14 measurements performed on molluscs Yoldiella spp. show that this core provides a detailed and undisturbed record of Holocene climatic changes over the last 10000 calendar years. Surface and deep waters were very cold (<0°C) at the beginning of the Holocene. C. reniforme dominated the highly diverse benthic foraminiferal assemblage. From 10 to 7.8 cal. ka BP, a warming trend culminated in a temperature optimum, which developed between 7.8 and 6.8 cal. ka BP. During this optimum, the input of Atlantic water to the Barents Sea reached its maximum. The Atlantic water mass invaded the whole Franz Victoria Trough and was present from subsurface to the bottom. No bottom water, which would form through rejection of brine during winter, was present at the core depth (388 m). The water stratification was therefore greatly reduced as compared to the present. An increase in percentage of I. helenae/norcrossi points to long seasonal ice-free conditions. The temperature optimum ended rather abruptly, with the return of cold polar waters into the trough within a few centuries. This was accompanied by a dramatic reduction of the abundance of C. reniforme. During the upper Holocene, the more opportunistic species E. clavatum became progressively dominant and the water column was more stratified. Deep water in Franz Victoria Trough contained a significant amount of cold Barents Sea bottom water as it does today, while subsurface water warmed progressively until about 3.7 cal. ka BP and reached temperatures similar to those of today. These long-term climatic changes were cut by several cold events of short duration, in particular one in the middle of the temperature optimum and another, which coincides most probably with the 8.2 ka BP cold event. Both long- and short-term climatic changes in the Barents Sea are associated with changes in the flow of Atlantic waters and the oceanic conveyor belt.

Distribution of deep-sea foraminifera in surface sediments east of New Zealand

Paleobathymetric assessments of fossil foraminiferal faunas play a significant role in the analysis of the paleogeographic, sedimentary, and tectonic histories of New Zealand's Neogene marine sedimentary basins. At depths >100 m, these assessments often have large uncertainties. This study, aimed at improving the precision of paleodepth assessments, documents the present-day distribution of deep-sea foraminifera (>63 µm) in 66 samples of seafloor sediment at 90-700 m water depth (outer shelf to mid-abyssal), east of New Zealand. One hundred and thirty-nine of the 465 recorded species of benthic foraminifera are new records for the New Zealand region. Characters of the foraminiferal faunas which appear to provide the most useful information for estimating paleobathymetry are, in decreasing order of reliability: relative abundance of common benthic species; benthic species associations; upper depth limits of key benthic species; and relative abundance of planktic foraminifera. R mode cluster analysis on the quantitative census data of the 58 most abundant species of benthic foraminifera produced six species associations within three higher level clusters: (1) calcareous species most abundant at mid-bathyal to outer shelf depths (<1000 m); (2) calcareous species most abundant at mid-bathyal and greater depths (>600 m); (3) agglutinated species mostly occurring at deep abyssal depths (>3000 m). A detrended correspondence analysis ordination plot exhibits a strong relationship between these species associations and bathymetry. This is manifest in the bathymetric ranges of the relative abundance peaks of many of the common benthic species (e.g., Abditodentrix pseudothalmanni 500-2800 m, Bolivina robusta 200-650 m, Bulimina marginata f. marginata 20-600 m, B. marginata f. aculeata 400-3000 m, Cassidulina norvangi 1000-4500 m, Epistominella exigua 1000-4700 m, and Trifarina angulosa 10-650 m), which should prove useful in paleobathymetric estimates. The upper depth limits of 28 benthic foraminiferal species (e.g., Fursenkoina complanata 200 m, Bulimina truncana 450 m, Melonis affinis 550 m, Eggerella bradyi 750 m, and Cassidulina norvangi 1000 m) have potential to improve the precision of paleobathymetric estimates based initially on the total faunal composition. The planktic percentage of foraminiferal tests increases from outer shelf to upper abyssal depths followed by a rapid decline within the foraminiferal lysocline (below c. 3600 m). A planktic percentage <50% is suggestive of shelf depths, and >50% is suggestive of bathyal or abyssal depths above the CCD. In the abyssal zone there is dramatic taphonomic loss of most agglutinated tests (except some textulariids) at burial depths of 0.1-0.2 m, which negates the potential usefulness of these taxa in paleobathymetric assessments.

Seasonal changes in labile organic matter composition on the continental shelf and bathyal sediments of the Cretan Sea

Bacterial abundance, biomass and cell size were studied in the oligotrophic sediments of the Cretan Sea (Eastern Mediterranean), in order to investigate their response to the seasonal varying organic matter (OM) inputs. Sediment samples were collected on a seasonal basis along a transect of seven stations (ranging from 40 to 1570 m depth) using a multiple-corer. Bacterial parameters were related to changes in chloroplastic pigment equivalents (CPE), the biochemical composition (proteins, lipids, carbohydrates) of the sedimentary organic matter and the OM flux measured at a fixed station over the deep basin (1570 m depth). The sediments of the Cretan Sea represent a nutrient depleted ecosystem characterised by a poor quality organic matter. All sedimentary organic compounds were found to vary seasonally, and changes were more evident on the continental shelf than in deeper sediments. Bacterial abundance and biomass in the sediments of the Cretan Sea (ranging from 1.02 to 4.59 * 10**8 cells/g equivalent to 8.7 and 38.7 µgC/g) were quite high and their distribution appeared to be closely related to the input of fresh organic material. Bacterial abundance and biomass were sensitive to changes in nutrient availability, which also controls the average cell size and the frequency of dividing cells. Bacterial abundance increased up to 3-fold between August '94 and February '95 in response to the increased amount of sedimentary proteins and CPE, indicating that benthic bacteria were constrained more by changes in quality rather than the quantity of the sedimentary organic material. Bacterial responses to the food inputs were clearly detectable down to 10 cm depth. The distribution of labile organic compounds in the sediments appeared to influence the vertical patterns of bacterial abundance and biomass. Cell size decreased significantly with water depth. Bacterial abundance and biomass were characterised by clear seasonal changes in response to seasonal OM pulses. The strong coupling between protein flux and bacterial biomass together with the strong bacterial dominance over the total biomass suggest that the major part of the carbon flow was channelled through the bacteria and the benthic microbial loop.

Phytoplankton of the southwest Kara Sea on August 9-12, 2007

A research was carried out along a transect from the Yamal Peninsula coast towards the outer shelf of the southwestern the Kara Sea in September 2007. 130 phytoplankton species were identified, among which 63 were found in the area for the first time. Total phytoplankton abundance varied from of 0.2 x10**9 to 11.3x10**9 cells/m**2, while biomass from 43 to 1057 mgC/m**2. A well pronounced cross-shelf zoning in phytoplankton communities was ascertained. The inner shelf zone about 30 km wide with depths down to 30 meters was characterized by predominance of diatoms (up to 80% of total algal abundance and biomass). The second group by value was dinoflagellates. Seaward in the area of depth increase from 30 to 140 m, the zone of the Yamal Current was located, which was 40 km wide and notable for its active water dynamics. Total abundance in the zone was maximal for the entire investigated area: up to 11.3x10**9 cells/m**2. Autotrophic flagellates were the leading group in phytoplankton, their share in total abundance reached 56-82%. Further than 70 km from the shore, the outer shelf zone was found with the water column rigidly stratified. The highest for the whole area phytoplankton biomass was identified here (up to 1.06 gC/m**2), 80% of which concentrated above the halocline. Diatoms dominated in phytoplankton abundance (up to 92%) and biomass (up to 90%) that resulted from mass development of two species: Chaetoceros diadema and Leptocylindrus danicus.

Geochemistry of evaporite in the Red Sea

One of the major shipboard findings during Leg 23 drilling in the Red Sea was the presence of late Miocene evaporites at Sites 225, 227, and 228. The top of the evaporite sequence correlates with a strong reflector (Reflector S) which has been mapped over much of the Red Sea (Ross et al., 1969, Phillips and Ross, 1970). This indicates that the Red Sea appears to be extent. Miocene sediments, including evaporites, are known from a few outcrops along the coastal plains of the Gulf of Suez to lat 14°N (Sadek, 1959, cited in Friedman, 1972; Heybroek, 1965; Friedman, 1972). Along the length of the Red Sea, the presence of Miocene salt is indicated by seismic reflection studies (Lowell and Genik, 1972) and confirmed by drilling. The recently published data from deep exploratory wells (Ahmed, 1972) demonstrate the great thickness of elastics and evaporites which were deposited in the Red Sea depression during Miocene time. The Red Sea evaporites are of the same age as the evaporites found by deep sea drilling (DSDP Leg 13) in the Mediterranean Sea. Therefore, Reflector S in the Red Sea is comparable to Reflector M in the Mediterranean. It is assumed that during Miocene time a connection between these two basins was established (Coleman, this volume) resulting in a similar origin for the evaporites deposited in the Red Sea and in the Mediterranean Sea. The origin of the Mediterranean evaporites has been discussed in great detail (Hsü et al., 1973; Nesteroff, 1973; Friedman, 1973). The formation of evaporites may be interpreted by three different hypotheses. 1) Evaporation of a shallow restricted shelf sea or lagoon which receives inflows from the open ocean. 2) Evaporation of a deep-water basin which is separated from the open ocean by a shallow sill (Schmalz, 1969). 3) Evaporation of playas or salt lakes which are situated in desiccated deep basins isolated from the open ocean (Hsü et al., 1973). The purpose of this study is to show whether one of these models might apply to the formation and deposition of the Red Sea evaporites. Therefore, a detailed petrographic and geochemical investigation was carried out.