(Table 1) Minerals of bulk sediment at DSDP Holes 64-480 and 64-481

This paper provides a brief, descriptive, sedimentological background for the chapters on hydraulic piston core Site 480 in this symposium, and supplements data given in the site chapter for Sites 479-480 (this volume, Pt. 1). Sediments are composed primarily of planktonic diatoms, with minor numbers of silicoflagellates, radiolarians, and varying amounts of both benthic and planktonic foraminifers, along with a large terrigenous component of olive brown, silty clay. The section contains meter-thick intervals of finely laminated facies alternating with nonlaminated zones. A few paleoenvironmental events are documented within the generally uniform sequence by sporadic occurrences of thin turbidites, phosphatic concretions, fish debris concentrations, an ash layer, and a thin layer of diagenetic dolomite. The distribution of nonlaminated and laminated zones is attributed to fluctuations of bottom-water oxygen content caused by variations in circulation, fertility, and productivity. Homogeneous sections are interpreted as coinciding with cooler climatic periods, whereas laminated sections seem to correspond to upwelling conditions during drier periods.

Petrographic and chemical characteristics of abyssal tholeiites at DSDP Leg 63 Holes

Tholeiitic basalts were obtained from basaltic basement ranging in age from 6 to 17 m.y. on IPOD/DSDP Leg 63. The main rock types encountered at all sites but 473 are basaltic pillow lavas. Although many of these pillow basalts are highly or moderately altered, fresh glass is usually present. At Site 473, we recovered coarse-grained, massive basalts; no clearly defined pillowed forms were observed. Phenocrysts or microphenocrysts present in the Leg 63 basalts are Plagioclase and clinopyroxene at Site 469; olivine, Plagioclase, and spinel at Site 470; and olivine, Plagioclase, and clinopyroxene at Sites 472 and 473. Olivines of the basalts from Holes 470A and 472 (Fo85-88) are generally more magnesian than those of the Hole 473 basalts (Fo77-81). Also, plagioclases of Holes 470A and 472 basalts (An70-85) are generally more calcic than those of Holes 469 and 473 basalts (An66-72). Geochemical study of the Leg 63 basalts indicates that in all cases they are large-ion-lithophile (LIL) element depleted tholeiites like typical abyssal tholeiites. In particular, they are very similar in composition to those described from the eastern Pacific, although the degree of iron enrichment found in the Leg 63 basalts is not as extensive as in basalts from the Galapagos spreading center. Hence, the geochemical evidence of the Leg 63 basalts is compatible with their formation at a spreading center. Compositional variations in Leg 63 basalts from any single drill hole is small. Major and trace element data indicate that the samples from Holes 469 and 473 are more fractionated in chemical composition than are the samples from Holes 470A and 472; this compositional variation may be largely ascribed to differences in the extent of shallow-level fractional crystallization of similar parental magma. The Hole 472 samples, however, show a LIL element character distinct from the other Leg 63 samples.

Composition of bottom sediments from the Mediterranean Sea off Syria

An investigation of recent bottom sediments between the Cyprus Island and the Syrian seacoast during Cruise 27 of R/V Vityaz-2 (1993) gave comprehensive field data significantly complementing our understanding of the sedimentation process in this part of the Mediterranean Sea. Mineralogical and geochemical indicators testify to different input into sedimentation of the Syrian and Nile River sources. The Nile River plays a leading role in terrigenous sedimentation in the southeastern Mediterranean Sea, especially in deep-sea areas. In contrast, contribution of weathering products of basalts and ophiolites from the Syrian drainage area (hornblende, monoclinic and rhombic pyroxenes, olivine, spinel, palagonite, and epidote) are particularly detectable in sediments of the near-coast zone. During Late Quaternary contribution of terrigenous material both from the Syrian and Nile sources was irregular in time.

Neogene planktonic foraminifera of DSDP Leg 41 holes

During Leg 41 Neogene sediments were recovered from five sites off northwest Africa. On the Sierra Leone Rise (Site 366), Neogene sediments consist of nanno oozes, nanno chalk, and calcareous clays 230 meters thick, resting conformably on the late Oligocene sediments. The common succession of zones occurs with two hiatuses. The lower gap corresponds to an interval around the lower/middle Miocene boundary (the Praeorbulina glomerosa and Orbulina suturalis-Globorotalia peri-pheroronda zones are absent) and the upper gap coincides with an interval around the middle/upper Miocene boundary (the Sphaeroidinellopsis sub-dehiscens-GIobigerina druryi, Globigerina nepenthes-Globorotalia siakensis and Globorotalia conlinuosa zones are missing). In the Cape Verde Basin (Site 367) deep-water Neogene turbidites (about 200-250 m thick) contain poor fauna of redeposited and sorted Cretaceous, Eocene, Oligocene, and Neogene species. On the Cape Verde Rise (Site 368) the Neogene section starts with slightly calcareous and non-calcareous clays with poor planktonic foraminifers of the lower Miocene. Later on this area was uplifted and clayey sediments have been replaced upsection in order by more shallow-water clayey nanno and nanno-foraminifer oozes and marls and pure calcareous oozes. In the middle Miocene, planktonic foraminifers are still not diverse, but since the level of the Globigerina nepenthes-Globorotalia siakensis Zone, almost all Neogene zones have been traced. The minimum thickness of the Neogene sediments is about 230 meters. On the continental slope off Spanish Sahara (Site 369) monotonous calcareous pelagic sediments of Neogene age (164 m thick) overlie the late Oligocene comformably, or with a small time gap. A set of zones beginning from the Globigerinoides primordis-Globorotaiia kugleri Zone up to the Globorotalia fohsi fohsi Zone has been revealed with a gap corresponding to the Globigerinita stainforthi and the Globigerinatella insueta-Globigerinoides irilobus zones. Above that follow sediments with heterogeneous microfauna which result from redeposition or mixing of sediments during drilling. The section ends with sediments of the late Miocene and lower Pliocene with abundant planktonic foraminifers. The latter are unconformably overlain by the Quaternary ooze. In the Morocco basin (Site 370) deep-water marls and calcareous clays of the lower Miocene contain poor assemblages of planktonic foraminifers. The middle and upper Miocene are represented by turbidites (alternation of nanno oozes, clays, siltstones, and sands) with heterogeneous microfauna. Total thickness of Neogene is up to 200 meters. In general the Neogene foraminifer microfauna of the area studied includes the majority of species which developed within the tropical-subtropical belt. The entire succession of the Miocene and Pliocene foraminifer zones occurs. The only exclusion is the Sphaeroidinellopsis subdehiscens-Globigerina druryi Zone of the middle Miocene. The distribution of species is shown on three tables. Comments are given for 47 species and subspecies of foraminifers (stratigraphic ranges, peculiarities of morphology, and ultrastructure of the shell wall).

Geochemistry of minerals at DSDP Holes 68-501 and 69-504B

The interaction of seawater with basalts in DSDP Hole 501 and the upper part of Hole 504B (Costa Rica Rift) produced oxidative alteration and a zonation of clay minerals along cracks. From rock edges to interiors in many cracks the following succession occurs, based on microscopic observations and microprobe analysis: iron hydroxides (red), "protoceladonite" (green), iddingsite (orange), and saponite (yellow). Clay minerals replace olivines and fill vesicles and cracks. Other secondary minerals are phillipsite, aragonite, and unidentified carbonates. Some glass is transformed to Mg-rich palagonite. Bulk rock chemistry is related to the composition of the secondary minerals. The zonation can be interpreted as a succession of postburial nonoxidative and oxidative diagenesis similar to that described in the Leg 34 basalts.

(Table 2) Geochemistry of glasses at DSDP Leg 54 Holes

The compositions of 45 natural basalt glasses from nine dredge stations and six Deep Sea Drilling Project Leg 54 sites near 9°N on the East Pacific Rise have been determined by electron microprobe. These comprise 19 distinct chemical groups. Seventeen of these fall in the range of the eastern Pacific tholeiite suite, which is characterized by marked enrichment in FeO*, TiO2, K2O, and P2O5 as CaO, MgO, and Al2O3 all decrease. Based on trace elements, an estimated 50-75 per cent fractionation of plagioclase, clinopyroxene, and olivine is required to produce ferrobasalts from parental olivine tholeiites. Additional chemical variations occur which require source heterogeneities, differences in the degree of melting, different courses of shallow fractionation, or magma mixing to explain. Glass compositions from within the Siqueiros fracture zone are mostly less fractionated than those from the flanks of the Rise, and show chemical differences which require variations in the depth of melting or highpressure fractionation to explain. Some of them could not be parental to East Pacific Rise flank ferrobasalts. Two remaining glass groups, from dredge hauls atop a ridge and a seamount, respectively, have distinctly higher K2O, P2O5, and TiO2 as well as lower CaO/Al2O3 and SiO2 at corresponding values of MgO than the tholeiite suite. These abundances, and whole-rock Y/Zr, Ce/Y, Nb/Zr, and isotopic abundances indicate that these basalts had a deeper, less depleted mantle source than the Rise tholeiite suite. Trace element abundances preclude the "ridge" basalt type from being a hybrid between the "seamount" basalt type and any East Pacific Rise tholeiite so far analyzed. The East Pacific Rise glasses from 9°N compare very closely to glasses dredged and drilled elsewhere on the East Pacific Rise. However, glass compositions from Site 424 on the Galapagos Rift drilled during Leg 54, as well as glasses and basalts dredged from the Galapagos and Costa Rica rifts, indicate that a greater degree of melting prevailed along much of the Galapagos Spreading Center than anywhere along the East Pacific Rise.

Benthic foraminifera of surface sediments from the continental slope off Sierra Leone, North-West Africa

On "Meteor" cruise 30 (1973) 22 piston-cores were collected off Sierra Leone from water-depths between about 5000 m (Sierra Leone Basin) and 500 m (upper continental slope) with the objective to study the sediment composition and age as well as processes of sedimentation on the continental slope in a tropical humid region. Granulometric analysis and determinations of the carbonate contents of the sediment samples were carried out, as well as qualitative and quantitative analysis of the components of the grain size fractions > 63 µm and of the planktonic and benthonic foraminifera > 160 µm. Presently, the cold Canary Current influences the composition of the planktonic foraminifera within the northwestern area of investigation (profile A), whereas the planktonic fauna of the eastern area (profile C) seems to be truly tropical. In all Quaternary sediments from the continental slope off Sierra Leone, species of Globorotalia are less abundant than in truly pelagic sediments. For that reason, the zonation of the Pleistocene sediments based on the presence or absence of Globorotalia cultrata does not always agree with the climatic changes reflected in the sediments. Concerning past climates better results can be obtained by using the changes in percentage abundances of Globigerina sp. sp. and Globigerinoides sp. sp. as indicators for cool and warm temperatures. The Tertiary sediments contain a pelagic foraminiferal assemblage. In the Holocene sediments the benthonic foraminifera do not only serve as good paleodepth indicators, but their communities are also restricted to defined water masses, which change their positions in accordance with climatic changes. Thus, Cassidulina carinata in the area of investigation is an excellent indicator for sediments deposited during times, which were cooler than today; this is true for all cores from the continental slope off Sierra Leone independent of water-depth although this species presently abounds at water-depths around 600 m. The cores from the continental rise and from the Sierra Leone Basin (M30-261, M30-146, M30-147) were deposited below the calcium carbonate compensation depth. Only small sections of the cores consist of the original carbonate-free sediments, whereas the main part of the sediment column is redeposited material, rich in foraminifera, which normally live on the upper continental slope, or even on the shelf. From these cores only M30-261 can be subdivided into biostratigraphic zones ranging from zone V to zone Y. In all cores from the middle and upper continental slope of the eastern area of investigation (profile C; KL 230, 209-204) and in cores KL 183 and KL 184 from the northwestern area (profile A) we observed an undisturbed succession of sediments from the biostratigraphic zones X (partly), Y and Z. All cores from the central area (M30-181, M30-182, M30-262 to 264) and M30-187 from the upper slope of profile A show variable hiatuses in the sedimentary record. Locally, high velocity bottom currents were probably responsible for erosion, nondeposition or minimal sedimentation rates. These currents might have been initiated partly by the somewhat exposed position of this part of the continental slope, where the shelf edge bends from a northwest towards an eastern direction, and partly by very young tectonic movements. Fracture zones with vertically displaced fault blocs are frequent at Sierra Leone continental margin. According to seismic measurements by McMaster et al. (1975) the sites of the central area are located on an uplifted fault bloc explaining the reduced sediment rates or erosion. Unlike the central area, the eastern area (profile C) is situated on a downfaulted bloc with high sediment rates. The sediments from the cores of profile B as well as the turbiditic deep-sea sediments were deposited under a higher flow regime; therefore they are coarser than the extremely fine-grained sediments of the cores from profile C. Since the sand fraction (> 63 µm) is mainly composed of foraminifera, besides pteropods and light-colored fecal pellets, the carbonate content increases with the increasing percentage of the coarse grain fraction. Higher concentrations of quartz were only observed in core sections with considerable carbonate dissolution (mainly in the X-Zone), and, in general, in all sediments from the eastern area with higher terrigenous input including larger concentration of mica. Especially during times transitional between glacials and interglacials (or interstadials) the bottom currents were intensified. The percentages of coarse fraction and carbonate increase with increasing current velocities. Calcium carbonate dissolution becomes important in water depths > 3500 m. During cooler times the lysokline is depressed. Light-colored fecal pellets were redeposited from Late Neogene sediments (M30-187, M30-181). In the area of investigation they occur in the Holocene and mainly the Pleistocene sediments of the cores from the northwestern and central area because only here Tertiary sediments have been eroded at the uppermost continental slope. In the central area there are at least two periods of non-sedimentation and/or erosion which can be confined as being (1) not older than middle Pliocene and not younger than zone V and (2) younger than zone W. The local character of the erosion is documented by the fact that a complete Late Quaternary section is present in the cores of the northwestern and eastern area, each within less than 100 km from incomplete cores from the central area.

General descriptions, organic contents and ratios of geolipid components at DSDP Holes 75-530B and 75-532

Distributions of free and bound n-alkanes, n-alkanoic acids, and n-alkanols were determined in order to compare the character of organic matter contained in organic-carbon-rich sediments from two sites sampled by the hydraulic piston corer. Two diatomaceous debris-flow samples of Pleistocene age were obtained from Hole 530B in the Angola Basin. A sample of bioturbated Pleistocene diatomaceous clay and another of bioturbated late Miocene nannofossil clay were collected from Hole 532 on the Walvis Ridge. Geolipid distributions of all samples contain large terrigenous contributions and lesser amounts of marine components. Similarities in organic matter contents of Hole 530B and Hole 532 sediments suggest that a common depositional setting, probably on the Walvis Ridge, was the original source of these sediments through Quaternary, and possibly late Neogene, times and that downslope relocation of these biogenic deposits has frequently occurred.