Iodine ages of pore water at Hydrate Ridge, Cascadian continental margin

Hydrate Ridge off the coast of Oregon, USA, is a prime example for gas hydrate occurrences in active margin settings. It is part of the Cascadia Margin and was the focus of Ocean Drilling Program (ODP) Leg 204, which successfully recovered fluids from nine sites from the southern part of the ridge. Iodide concentrations in pore fluids associated with gas hydrates are strongly enhanced, by factors up to 5000 compared to seawater, which allows the use of this biophilic element as tracer for organic source regions. We applied the cosmogenic isotope 129I (T1/2=15.7 Ma) system to determine the age of the organic source formation responsible for the iodide enrichment. In all sites at ODP Leg 204, 129I/I ratios were found to decrease with depth to values around 250x10**-15, corresponding to minimum ages of 40 Ma, but in several sites, maxima in the 129I/I ratios point to the local addition of young iodide. The results indicate that a large amount of iodide was derived from deep accreted sediments of Eocene age, and that additional source regions provide iodide of Late Miocene age. The presence of old iodide in the pore waters suggests that fluid pathways are open to allow transport over large distances into the gas hydrate fields. The strong correlation between iodide and methane in hydrate fields coupled with the similarity in transport parameters in aqueous solutions suggests that a large fraction of methane in gas hydrates also has old sources and is transported into the present locations from source regions of Eocene age.

(Table 1) Age determination of sediment core PS51/092-12

Diatom assemblages were employed to study temporal changes of Siberian river runoff on the Laptev Sea shelf. Using a correlation between freshwater diatoms (%) in core-top sediments and summer surface water salinities from the inner Kara Sea, salinity conditions were reconstructed for a site northeast of the Lena River Delta (present water depth 32 m) since 9 calendar years (cal) ka. The reconstruction indicate a strong, near-coastal, and river-influenced environment at the site until about 8.6 cal ka. Corroborated by comparison with other proxy records from further to the east, surface salinities increased from 9 to 14 until about 7.4 cal ka, owing to ongoing global sea level rise and synchronous southward shift of the coastline. Although riverine water became less influential at the site since then, salinities still varied between 12.5 and 15, particularly during the last 3.5 kyr. These more recent salinity fluctuations agree well with reconstructions from just north of the Lena Delta, emphasizing the strong linkage between shelf hydrography and riverine discharge patterns in Arctic Siberia.