Phosphorus components, trace metals and Ba excess of ODP Site 202-1237 sediments

We determined the sedimentary concentrations of phosphorus (P), barium (Ba), manganese (Mn), titanium (Ti), aluminum (Al), and uranium (U) for sediment samples from the southeast Pacific Nazca Ridge, Ocean Drilling Program Site 1237. This unique record extends to 31 Ma over 360 meters composite depth (mcd), recording depositional history as the site progressed eastward over its paleohistory. We sampled with a temporal resolution of ~0.2 m.y. throughout the sequence, equivalent to an average spacing of 1.63 m/sample. Concentrations of sequentially extracted components of P (oxide-associated, authigenic, organic, and detrital) increase toward the modern. Al/Ti ratios indicate that the background detrital source material is consistent with upper continental crust. U enrichment factors (U EFs) generally exceed crustal values and indicate slightly reducing environments. However, authigenic U precipitation can also be influenced by the organic carbon rain rate and may not be solely an indicator of redox conditions. Dramatic changes in Mn EFs at ~162 mcd, from values between 12 and 93 to values <12 after this depth, and a sharp color contact boundary lead us to believe that a paleoredox boundary from an oxygenated to a more reducing depositional environment occurred near this depth. Estimates of biogenic barite concentrations from a total sediment digestion technique (Ba excess) are greater than those from a barite extraction (Ba barite) for selected samples across the entire depth range. Applying a range of Ba/Ti ratios from different source materials to correct for detrital inputs does not change the lack of agreement with Ba barite concentrations. Reactive P (P reactive) concentrations (the sum of oxide-associated, authigenic, and organic P concentrations) increase toward the modern with values typically <12 µmol P/g from the base of our record through ~100 mcd, with a gradual increase to concentrations >15 µmol P/g. Ba excess follows the same general trends as Preactive, with concentrations <14 µmol Ba/g in the lower portion of the record to values >15 µmol Ba/g. Accumulation rate records of these proxies will be needed to infer paleoproductivity. P reactive/Ba excess ratios, an indicator of the relative burial of the nutrient P to organic carbon export, exhibit higher values, similar to modern, from the base of our record through ~180 mcd. The remainder of the record exhibits values lower than modern, indicating that organic carbon export to the sediments was higher relative to nutrient burial.

(Table 3) Pollen analytical and carpological record of the outcrop Hölle below Dwadieden Park, Rügen Island

Pollen analyses and 14C-datings were carried out on two late glacial profiles from Ruegen Island, Mecklenburg-Vorpommern at the southwestern Baltic coast. The palaeoclimatic and palaeoecologic interpretations were supported by carpological investigations. The organogenic deposits of the 'Hoelle' outcrop near Dwasieden Park were chosen because of their unique stratigraphic position, which according to PANZIG (1989), lay under a m3m-Glacial Till of the Mecklenburg Advance (W3). The results indicated that the initial phase of the late glacial sedimentation in a relatively small and asymmetrical lake basin (in comparison with the larger Nieder- and Credner lake to the southwest), probably had its origin in the older Alleroed (II a) after FIRBAS (1949). The basal clastic sediments were rapidly followed by peat deposits and later, due to a rising water table, by muds rich in organic matter. The area was covered with sparse Betula-(Pinus) forests having heliophilous late-glacial elements typical of the surrounding areas during the younger Alleroed (II b). With the climatic change to colder and drier conditions at the beginning of the Younger Dryas (III), the vegetation decreased and enhanced erosional processes led to the fill up of the depression with fine clastic sediments. The intense relief differences of the surroundings coupled with high water saturation in the sediments led to solifluction in the m3m-Glacial Till and its placement discordantly over the organogenic sequence.

Morphology and surface texture of quartz grains from ODP Site 105-645

The shapes and surface textures of sand-sized quartz grains from the sediments cored at Site 645 in southern Baffin Bay during ODP Leg 105 were studied to characterize the terrigenous materials and the settling processes involved in the deposition of these sediments. Here, we show a homogeneous sand fraction that results from mixing grains from various provenances. The characteristics inherited from terrestrial processes (varying degrees of wear; fluviatile, aeolian, and diagenetic features) dominate the characteristics that result from evolution in a high-energy marine environment. Thus, the influence of the last stage of sedimentation in a deep-marine environment was difficult to distinguish. However, fluctuations in the relative proportions of particular features reveal that the terrigenous material derived from sedimentary formations of Baffin Island and East Greenland or from direct abrasion of the crystalline shield, which changed through time as the dominant settling processes evolved. In particular, this study confirms the onset of major ice rafting as old as late Miocene.