Radiocarbon dates, grain size measurements and selected foraminifera analysis from sediment cores AvH248260-2 and AvH248260-1, Ameralik Fjord, SW Greenland

Sedimentological and geochemical (XRF) data together with information from diatom and benthic foraminiferal records of a 3.5 m long gravity core from Ameralik Fjord, southern West Greenland, is used for reconstructing late-Holocene environmental changes in this area. The changes are linked to large-scale North Atlantic ocean and climate variability. AMS 14C-dating of benthic foraminifera indicates that the sediment core records the last 4400 years and covers the termination of the Holocene Thermal Maximum (HTM). The late HTM (4.4 3.2 ka BP) is characterized by high accumulation rates of fine (silty) sediments related to strong meltwater discharge from the Inland Ice. The HTM benthic foraminiferal fauna demonstrates the presence of well-ventilated, saline bottom water originating from inflow of subsurface West Greenland Current water of Atlantic (Irminger Sea) origin. The hydrographic conditions were further characterized by limited sea ice probably related to a mild and relatively windy winter climate. After 3.2 ka BP lower fine-grained sedimentation rates, but a larger input from sea-ice rafted or aeolian coarse material prevailed. This can be related to colder atmospheric conditions with a decreased meltwater discharge and more widespread sea-ice cover in the fjord.

(Table 1) Grain size results, statistical parameters and magnetic susceptibility values of disturbed sediments from ODP holes 204-1249C and 204-1245B

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.

(Table 2) Facies and grain-size description for Mississippi Fan sediments of DSDP Leg 96

Eight lithologic facies recognized in the Mississippi Fan sediments drilled during DSDP Leg 96 are defined on the basis of lithology, sedimentary structures, composition, and texture. Of these, the calcareous biogenic sediments are of minor importance, volumetrically, as compared with the dominant resedimented terrigenous facies. Clay, mud, and silt are the most abundant sediments at all the sites drilled, with some sand and gravel in the midfan channel fill and an abundance of sand on the lower fan. Facies distribution and vertical sequences reflect the importance of sediment type and supply in controlling fan development. Sea-level changes and diapiric activity have also played an important role. Clay and sand fraction mineralogy closely mirror the dominant sediment source, namely, the Mississippi River system and adjacent continental shelf. Local and regional variation in composition on the fan mostly reflects facies differences.

(Table 1) Grain size, sedimentation rates and accumulation rates of ODP Hole 152-919A coarse-sand ice-rafted debris

At mid- to high-latitude marine sites, ice-rafted debris (IRD) is commonly recognized as anomalously coarse-grained terrigenous material contained within a fine-grained hemipelagic or pelagic matrix (e.g., Conolly and Ewing, 1970; Ruddiman, 1977, doi:10.1130/0016-7606(1977)88<1813:LQDOIS>2.0.CO;2; Krissek, 1989, doi:10.2973/odp.proc.sr.104.114.1989; Jansen et al., 1990; Bond et al., doi:10.1038/360245a0, 1992; Krissek, 1995, doi:10.2973/odp.proc.sr.145.118.1995). The presence of such ice-rafted material is a valuable indicator of the presence of glacial ice at sea level on an adjacent continent, whereas the composition of the IRD can often be used to identify the location of the source area (e.g., Goldschmidt, 1995, doi:10.1016/0025-3227(95)00098-J). Because the amount of core recovered during Leg 163 was very limited, this shore-based, postcruise study focuses on materials recovered at a nearby site during Leg 152. In particular, this study examines sediments recovered at Site 919; these sediments were described as containing a significant ice-rafted component in the Leg 152 Initial Reports volume (Larsen, Saunders, Clift, et al., 1994, doi:10.2973/odp.proc.ir.152.1994). In this study, the sedimentary section from Site 919 has been examined with the goal of providing a detailed history of glaciations on Greenland and other landmasses adjacent to the Norwegian-Greenland Sea; this history ultimately will be calibrated using an oxygen isotope stratigraphy (Flower, 1998, doi:10.2973/odp.proc.sr.152.219.1998), although that calibration has not been completed at this time. Because ice-core studies of the Greenland Ice Sheet (GIS) have shown that the GIS changed dramatically, and in some cases extremely rapidly, during at least the last interglacial stage (GRIP Members, 1993, doi:10.1038/364203a0), a detailed IRD record from the Southeast Greenland margin should provide insight into the longer term behavior of this sensitive component of the Northern Hemisphere climate system.

Beryllium-10, mineralogy and grain size distribution of DSDP Hole 68-502B (Table 1)

We present a high-resolution 10Be profile from deep sea sediments (sampled from Hole 502B in the Caribbean sea) that strongly resembles the 10Be record in ice core profiles, particularly the Vostok core from Antarctica. This high-resolution profile revealed occurrences of enhanced 10Be concentrations at about 23-24, 37-39 and 60-65 ka. The excellent match between these peaks appearing in a georeservoir profile other than in polar ice, strengthens the implications that can be inferred from 10Be and provide global markers for chronological correlation of climatic events. The position at low latitude of the studied sediment section is, unlike the case with the high latitude polar regions, excellent for exposing causes of modulation in 10Be production. We interpret the source of the pattern and enhancements, particularly the 37-39 ka peak, of 10Be to be global and do not strictly relate to climatic conditions and/or production rates specific to the polar regions.

(Appendix) Grain-size distribution, calcium carbonate content and proportion of cemented aggregates in ODP Site 133-820

The textural and compositional characteristics of the 400 m sequence of Pleistocene wackestones and packstones intersected at Ocean Drilling Program (ODP) Site 820 reflect deposition controlled by fluctuations in sea-level, and by variations in the rate of sediment supply. The development of an effective reefal barrier adjacent to Site 820, between 760 k.y. and 1.01 Ma, resulted in a marked reduction in sediment accumulation rates on the central Great Barrier Reef outermost shelf and upper slope. This marked change corresponds with the transition from sigmoidal prograding seismic geometry in the lower 254 m of the sequence, to aggradational geometry in the top 146 m. The reduction in the rate of sediment accumulation that followed development of the reefal barrier also caused a fundamental change in the way in which fluctuations in sea-level controlled sediment deposition. In the lower, progradational portion of the sequence, sea-level cyclicity is represented by superimposed coarsening-upward cycles. Although moderately calcareous throughout (mostly 35%-75% CaCO3), the depositional system acted in a similar manner to siliciclastic shelf depositional systems. Relative sea-level rises resulted in deposition of more condensed, less calcareous, fine, muddy wackestones at the base of each cycle. Sea-level highstands resulted in increased sedimentation rates and greater influx of coarse bioclastic material. Continued high rates of sedimentation of both coarse bioclastic material and mixed carbonate and terrigenous mud marked falling and low sea-levels. This lower part of the sequence therefore is dominated by coarse packstones, with only thin wackestone intervals representing transgressions. In contrast, sea-level fluctuations following formation of an effective reefal barrier produced a markedly different sedimentary record. The more slowly deposited aggradational sequence is characterized by discrete thin interbeds of relatively coarse packstone within a predominantly fine wackestone sequence. These thin packstone beds resulted from relatively low sedimentation rates during falling and low sea-levels, with much higher rates of muddy sediment accumulation during rising and high sea-levels. The transition from progradational to aggradational sequence geometry therefore corresponds to a transition from a "siliciclastic-type" to a "carbonate-type" depositional system.

Age models, accumulation rates, and grain size distributions of sediment cores from the northern subtropical Atlantic

The terrigenous sediment proportion of the deep sea sediments from off Northwest Africa has been studied in order to distinguish between the aeolian and the fluvial sediment supply. The present and fossil Saharan dust trajectories were recognized from the distribution patterns of the aeolian sediment. The following timeslices have been investigated: Present, 6,000, 12,000 and 18,000 y. B. P. Furthermore, the quantity of dust deposited off the Saharan coast has been estimated. For this purpose, 80 surface sediment samples and 34 sediment cores have been analysed. The stratigraphy of the cores has been achieved from oxygen isotopic curves, 14C-dating, foraminiferal transfer temperatures, and carbonate contents. Silt sized biogenic opal generally accounts for less than 2 % of the total insoluble sediment proportion. Only under productive upwelling waters and off river mouths, the opal proportion exceeds 2 % significantly. The modern terrigenous sediment from off the Saharan coast is generally characterized by intensely stained quartz grains. They indicate an origin from southern Saharan and Sahelian laterites, and a zonal aeolian transport in midtropospheric levels, between 1.5 an 5.5 km, by 'Harmattan' Winds. The dust particles follow large outbreaks of Saharan air across the African coast between 15° and 21° N. Their trajectories are centered at about 18° N and continue further into a clockwise gyre situated south of the Canary Islands. This course is indicated by a sickle-shaped tongue of coarser grain sizes in the deep-sea sediment. Such loess-sized terrigenous particles only settle within a zone extending to 700 km offshore. Fine silt and clay sized particles, with grain sizes smaller than 10- 15 µm, drift still further west and can be traced up to more than 4,000 km distance from their source areas. Additional terrigenous silt which is poor in stained quartz occurs within a narrow zone off the western Sahara between 20° and 27° N only. It depicts the present dust supply by the trade winds close to the surface. The dust load originates from the northwestern Sahara, the Atlas Mountains and coastal areas, which contain a particularly low amount of stained quartz. The distribution pattern of these pale quartz sediments reveals a SSW-dispersal of dust being consistent with the present trade wind direction from the NNE. In comparison to the sediments from off the Sahara and the deeper subtropical Atlantic, the sediments off river mouths, in particular off the Senegal river, are characterized by an additional input of fine grained terrigenous particles (< 6 µm). This is due to fluvial suspension load. The fluvial discharge leads to a relative excess of fine grained particles and is observed in a correlation diagram of the modal grain sizes of terrigenous silt with the proportion of fine fraction (< 6 µm). The aeolian sediment contribution by the Harmattan Winds strongly decreased during the Climatic Optimum at 6,000 y. B. P. The dust discharge of the trade winds is hardly detectable in the deep-sea sediments. This probably indicates a weakened atmospheric circulation. In contrast, the fluvial sediment supply reached a maximum, and can be traced to beyond Cape Blanc. Thus, the Saharan climate was more humid at 6,000 y B. P. A latitudinal shift of the Harmattan driven dust outbreaks cannot be observed. Also during the Glacial, 18,000 y. B. P., Harmattan dust transport crossed the African coast at latitudes of 15°-20° N. Its sediment load increased intensively, and markedly coarser grains spread further into the Atlantic Ocean. An expanded zone of pale-quart sediments indicates an enhanced dust supply by the trade winds blowing from the NE. No synglacial fluvial sediment contribution can be recognized between 12° and 30° N. This indicates a dry glacial climate and a strengthened stmospheric circulation over the Sahelian and Saharan region. The climatic transition pahes, at 12, 000 y. B. P., between the last Glacial and the Intergalcial, which is compareable to the Alerod in Europe, is characterized by an intermediate supply of terrigenous particles. The Harmattan dust transport wa weaker than during the Glacial. The northeasterly trade winds were still intensive. River supply reached a first postglacial maximum seaward of the Senegal river mouth. This indicates increasing humidity over the southern Sahara and a weaker atmospheric circulation as compared to the glacial. The accumulation rates of the terrigenous silt proportion (> 6 µm) decrcase exponentially with increasing distance from the Saharan coast. Those of the terrigenous fine fraction (< 6 µm) follow the same trend and show almost similar gradients. Accordingly, also the terrigenous fine fraction is believed to result predominantly from aeolian transport. In the Atlantic deep-sea sediments, the annual terrigenous sediment accumulation has fluctuated, from about 60 million tons p. a. during the Late Glacial (13,500-18,000 y. B. P, aeolian supply only) to about 33 million tons p. a. during the Holocene Climatic Optimum (6,000-9,000 y. B. P, mainly fluvial supply), when the river supply has reached a maximum, and to about 45 million tons p. a. during the last 4,000 years B. P. (fluvial supply only south of 18° N).