Magnetic charachterization of surface sediments in the South Atlantic

Surface sediment samples representative for the tropical and subtropical South Atlantic (15°N to 40°S) were investigated by isothermal magnetic methods to delineate magnetic mineral distribution patterns and to identify their predominant Holocene climatic and oceanographic controls. Individual parameters reveal distinct, yet frequently overlapping, regional sedimentation characteristics. A probabilistic ('fuzzy c-means') cluster analysis was applied to five concentration independent magnetic properties assessing magnetite to hematite ratios and diagnostic of bulk and fine-particle magnetite grain size and coercivity spectra. The resultant 10 cluster structures establish an oceanwide magnetic sediment classification scheme tracing the major terrigenous eolian and fluvial fluxes, authigenic biogenic magnetite accumulation in high-productivity areas, transport by ocean current systems, and effects of bottom water velocity on depositional regimes. Distinct dissimilarities in magnetic mineral inventories between the eastern and western basins of the South Atlantic reflect prominent contrasts of both oceanic and continental influences.

Sedimentology and age determinations on core PS2813-1

Die Rekonstruktion des Einflusses von Strömungen und glazialmarinen Prozessen auf das Sedimentationsgeschehen am Kontinentalhang der Antarktischen Halbinsel im westlichen Weddellmeer basiert auf sedimentologischen und geophysikalischen Daten eines Kolbenlotkerns. Der Sedimentkern wurde während des Fahrtabschnitts ANT-XIV/3 mit dem FS "Polarstern" aus einer mächtigen Levee-Struktur eines Rinnen-Rückensystems gewonnen. Es wurden sedimentologische sowie sedimentphysikalische Untersuchungen an dem Kernmaterial durchgeführt. Die texturellen Änderungen im Kern und die Variationen der gemessenen Parameter ermöglichen eine lithofazielle Gliederung und stratigraphische Einstufung der Sedimentabfolge. Die untersuchten Sedimente umfassen den Zeitraum der vier letzten Klimazyklen bis heute und repräsentieren die Ablagerungsbedingungen von mehr als 340 000 Jahren. Vier Faziestypen wurden unterschieden, die sowohl glaziale als auch interglaziale Ablagerungsräume charakterisieren. (1) Die überwiegend groblaminierten Sedimentabfolgen wurden der Laminitfazies zugeordnet. Unter glazialen Umweltbedingungen kam es infolge schwacher Bodenströmungen zur Ablagerung feinkörniger, laminierter, strömungsbetonter Sedimente. (2) Strukturlose, sehr homogene Sedimentabfolgen des Kems beschreiben einen weiteren, den Kaltzeiten zugeordneten, Faziestyp, der durch geringe Variationen in den Sedimenteigenschaften charakterisiert ist. (3) Kernabschnitte, die weitgehend strukturlos sind bzw. leichte Bioturbationen und relativ viel eistransportiertes Material aufweisen, wurden als IRD-Fazies bezeichnet. Sie repräsentiert den Übergang vom Glazial zum Interglazial, in dem sich das Schelfeis und die Meereisbeckung zurückzogen. In den Sedimenten kam es infolge der gesteigerten Kalbungsrate zur Anreicherung der Eisfracht. (4) Die relativ biogenreichen, hellen Ablagerungen wurden der interglazialzeitlichen Karbonatfazies zugeteilt. Der signifikant erhöhte Anteil planktischer Foraminiferen weist auf eine gesteigerte Bioproduktivität im Oberflächenwasser hin, die aus verstärkten jahreszeitlichen Schwankungen der Meereisbedeckung resultiert. Die betrachteten Sedimentationsprozesse, wie biologische Produktivität, Umlagerungsprozesse durch Meeresströmungen, gravitativer Sedimenttransport und Eistransport, sind das Abbild komplexer Wechselwirkungen aus Meeresspiegelschwankungen, Änderungen ozeanographischer Bedingungen und der Vereisungsdynamik. Das Sedimentationsgeschehen im Untersuchungsgebiet wurde folglich durch die Variationen der vorherrschenden Umweltbedingungen bestimmt. Im Glazial kam es unter einer geschlossenen Meereisbedeckung zur Ablagerung feinkörniger, geschichteter Sedimente. Vorwiegend Turbiditströmungen kontrollierten das Sedimentationsgeschehen innerhalb des betrachteten Rinnen-Rückensystems. Unter dem Einfluß der Coriolis-Kraft und wahrscheinlich einer Konturströmung wurden die suspendierten, feinkörnigen Partikel aus dem zentralen Bereich der Rinne verdriftet und über dem nördlichen Uferwall abgelagert. Höherenergetische gravitative Prozesse beeinflußten das Sedimentationsgeschehen episodisch und sind durch gut sortierte Ablagerungen mit erhöhten Gehalten im Mittel- bis Grobsiltbereich dokumentiert. Höhere Sedimentationsraten in den Glazialen trugen verstärkt zur Bildung des Uferwalls bei. Die Ablagerungen der ebenfalls glazialzeitlichen homogenen Fazies belegen unterschiedliche Ablagerungsbedingungen und eine Verschiebung der dominierenden Prozesse. Während des Übergangs vom Glazial zum Interglazial nahm die Bodenwasserbildungsrate durch das Aufschwimmen des Schelfeises zu, wodurch die Strömungsintensität gesteigert wurde. Eine verstärkte Eisbergaktivität wird durch die Anreichung des IRD-Materials dokumentiert. Während interglazialer Zeiten ermöglichten offen-marine Bedingungen im Südsommer eine leicht erhöhte biologische Produktivität, so daß der Ablagerungsraum durch die Sedimentation biogener Komponenten verstärkt beeinflußt wurde.

Sedimentology, geochemistry and paleomagnetic of ODP Hole 151-913B

The Eocene and Oligocene epochs (55 to 23 million years ago) comprise a critical phase in Earth history. An array of geological records (Zachos et al., 2001, doi:10.1126/science.1059412; Lear et al., 2000, doi:10.1126/science.287.5451.269; Coxall et al., 2005, doi:10.1038/nature03135; Pekar et al., 2005; doi:10.1130/B25486.1; Strand et al., 2003, doi:10.1016/S0031-0182(03)00396-1) supported by climate modelling (DeConto and Pollard, 2003, doi:10.1038/nature01290) indicates a profound shift in global climate during this interval, from a state that was largely free of polar ice caps to one in which ice sheets on Antarctica approached their modern size. However, the early glaciation history of the Northern Hemisphere is a subject of controversy (Coxall et al., 2005, doi:10.1038/nature03135; Tripati et al., 2005, doi:10.1038/nature03874; Wolf-Welling et al., 1996, doi:10.2973/odp.proc.sr.151.139.1996; Moran et al., 2006, doi:10.1038/nature04800). Here we report stratigraphically extensive ice-rafted debris, including macroscopic dropstones, in late Eocene to early Oligocene sediments from the Norwegian-Greenland Sea that were deposited between about 38 and 30 million years ago. Our data indicate sediment rafting by glacial ice, rather than sea ice, and point to East Greenland as the likely source. Records of this type from one site alone cannot be used to determine the extent of ice involved. However, our data suggest the existence of (at least) isolated glaciers on Greenland about 20 million years earlier than previously documented (Winkler et al., 2002, doi:10.1007/s005310100199), at a time when temperatures and atmospheric carbon dioxide concentrations were substantially higher.

(Fig. 9) Pollen analysis of sediment core GIK16017-2

The improved understanding of the pollen signal in the marine sediments offshore of northwest Africa is applied to deep-sea core M 16017-2 at 21°N. Downcore fluctuations in the percentage, concentration and influx diagrams record latitudinal shifts of the main northwest African vegetation zones and characteristics of the trade winds and the African Easterly Jet. Time control is provided by 14C ages and 180 records. During the period 19,000-14,000 yr B.P. a compressed savanna belt extended between about 12 ° and 14-15°N. The Sahara had maximally expanded northward and southward under hyperarid climatic conditions. The belt with trade winds and dominant African Easterly Jet transport had not shifted latitudinally. The trade winds were strong as compared to the modern situation but around 13,000 yr B.P. the trade winds weakened. After 14,000 yr B.P. the climate became less arid south of the Sahara and a first spike of fluvial runoff is registered around 13,000 yr B.P. Fluvial runoff increased strongly around 11,000 yr B.P. and maximum runoff is recorded from about 9000-7800 yr B.P. Around 12,500 yr B.P. the savanna belt started to shift northward and became richer in woody species: it shifted about 6° of latitude, reached its northernmost position during the period of 9200-7800 yr B.P. and extended between about 16° and 24°N at that time. Tropical forest had reached its maximum expansion and the Guinea zone reached as far north as about 15°N, reflecting very humid climatic conditions south of the Sahara. North of the Sahara the climate also became more humid and Mediterranean vegetation developed rapidly. The Sahara had maximally contracted and the trade winds were weak and comparable with the present day intensity. After about 7800 yr B.P. the southern fringe of the Sahara and accordingly the savanna belt, shifted rapidly southward again.

Rock magnetic properties of ODP Leg 134 sites

During Leg 134, the influence of ridge collision and subduction on the structural evolution of island arcs was investigated by drilling at a series of sites in the collision zone between the d'Entrecasteaux Zone (DEZ) and the central New Hebrides Island Arc. The DEZ is an arcuate Eocene-Oligocene submarine volcanic chain that extends from the northern New Caledonia Ridge to the New Hebrides Trench. High magnetic susceptibilities and intensities of magnetic remanence were measured in volcanic silts, sands, siltstones, and sandstones from collision zone sites. This chapter presents the preliminary results of studies of magnetic mineralogy, magnetic properties, and magnetic fabric of sediments and rocks from Sites 827 through 830 in the collision zone. The dominant carrier of remanence in the highly magnetic sediments and sedimentary rocks in the DEZ is low-titanium titanomagnetite of variable particle size. Changes in rock magnetic properties reflect variations in the abundance and size of titanomagnetite particles, which result from differences in volcanogenic contribution and the presence or absence of graded beds. Although the anisotropy of magnetic susceptibility results are difficult to interpret in terms of regional stresses because the cores were azimuthally unoriented, the shapes of the susceptibility ellipsoids provide information about deformation style. The magnetic fabric of most samples is oblate, dominated by foliation, as is the structural fabric. The variability of degree of anisotropy (P) and a factor that measures the shape of the ellipsoid (q) reflect the patchy nature of deformation, at a micrometer scale, that is elucidated by scanning electron microscope analysis. The nature of this patchiness implies that deformation in the shear zones is accomplished primarily by motion along bedding planes, whereas the material within the beds themselves remains relatively undeformed.

Magnetic extracts of three gravity cores located at the Ceará Rise, the Mid-Atlantic Ridge and the Sierra Leone Rise

The magnetic microparticle and nanoparticle inventories of marine sediments from equatorial Atlantic sites were investigated by scanning and transmission electron microscopy to classify all present detrital and authigenic magnetic mineral species and to investigate their regional distribution, origin, transport, and preservation. This information is used to establish source-to-sink relations and to constrain environmental magnetic proxy interpretations for this area. Magnetic extracts were prepared from sediments of three supralysoclinal open ocean gravity cores located at the Ceará Rise (GeoB 1523-1; 3°49.9'N/41°37.3'W), the Mid-Atlantic Ridge (GeoB 4313-2; 4°02.8'N/33°26.3'W), and the Sierra Leone Rise (GeoB 2910-1; 4°50.7'N/21°03.2'W). Sediments from two depths corresponding to marine isotope stages 4 and 5.5 were processed. This selection represents glacial and interglacial conditions of sedimentation for the western, central, and eastern equatorial Atlantic and avoids interferences from subsurface and anoxic processes. Crystallographic, elemental, morphological, and granulometric data of more than 2000 magnetic particles were collected by scanning and transmission electron microscopy. On basis of these properties, nine particle classes could be defined: detrital magnetite, titanomagnetite (fragmental and euhedral), titanomagnetite-hemoilmentite intergrowths, silicates with magnetic inclusions, microcrystalline hematite, magnetite spherules, bacterial magnetite, goethite needles, and nanoparticle clusters. Each class can be associated with fluvial, eolian, subaeric, and submarine volcanic, biogenic, or chemogenic sources. Large-scale sedimentation patterns are delineated as well: detrital magnetite is typical of Amazon discharge, fragmental titanomagnetite is a submarine weathering product of mid-ocean ridge basalts, and titanomagnetite-hemoilmenite intergrowths are common magnetic particles in West African dust. This clear regionalization underlines that magnetic petrology is an excellent indicator of source-to-sink relations. Hematite encrustations, magnetic spherules, and nanoparticle clusters were found at all investigated sites, while bacterial magnetite and authigenic hematite were only detected at the more oxic western site. At the eastern site, surface pits and crevices were seen on the crystal faces indicating subtle early diagenetic reductive dissolution. It was observed that paleoclimatic signatures of magnetogranulometric parameters such as the ratio of anhysteretic and isothermal remanent magnetizations can be formed either by mixing of multiple sources with separate, relatively narrow grain size ranges (western site) or by variable sorting of a single source with a broad grain size distribution (eastern site). Hematite, goethite, and possibly ferrihydrite nanoparticles occur in all sediment cores studied and have either high-coercive or superparamagnetic properties depending on their partly ultrafine grain sizes. These two magnetic fractions are generally discussed as separate fractions, but we suggest that they could actually be genetically linked.

Enviromagnetic, major element, and grain-size analyses of surface sediment samples along the continental margin between East Brazil and Patagonia

Continental margin sediments of SE South America originate from various terrestrial sources, each conveying specific magnetic and element signatures. Here, we aim to identify the sources and transport characteristics of shelf and slope sediments deposited between East Brazil and Patagonia (20°-48°S) using enviromagnetic, major element, and grain-size data. A set of five source-indicative parameters (i.e., chi-fd%, ARM/IRM, S0.3T, SIRM/Fe and Fe/K) of 25 surface samples (16-1805 m water depth) was analyzed by fuzzy c-means clustering and non-linear mapping to depict and unmix sediment-province characteristics. This multivariate approach yields three regionally coherent sediment provinces with petrologically and climatically distinct source regions. The southernmost province is entirely restricted to the slope off the Argentinean Pampas and has been identified as relict Andean-sourced sands with coarse unaltered magnetite. The direct transport to the slope was enabled by Rio Colorado and Rio Negro meltwaters during glacial and deglacial phases of low sea level. The adjacent shelf province consists of coastal loessoidal sands (highest hematite and goethite proportions) delivered from the Argentinean Pampas by wave erosion and westerly winds. The northernmost province includes the Plata mudbelt and Rio Grande Cone. It contains tropically weathered clayey silts from the La Plata Drainage Basin with pronounced proportions of fine magnetite, which were distributed up to ~24° S by the Brazilian Coastal Current and admixed to coarser relict sediments of Pampean loessoidal origin. Grain-size analyses of all samples showed that sediment fractionation during transport and deposition had little impact on magnetic and element source characteristics. This study corroborates the high potential of the chosen approach to access sediment origin in regions with contrasting sediment sources, complex transport dynamics, and large grain-size variability.