(Table 1) Mineralogical composition of sediments from DSDP Sites 69-504 and 69-505

We discuss the provenance of minerals detected by X-ray-diffraction analyses of sediments of Sites 504 and 505 of Deep Sea Drilling Project Leg 69. These are X-ray-amorphous material, opal-CT, calcite, quartz, feldspar, apatite, smectite, illite, kaolinite, magnetite, maghemite, pyrite, marcasite, barite, sepiolite, and clinoptilolite. Authigenic marcasite and clinoptilolite together with opal-CT are restricted to Site 504, indicating the special diagenetic conditions related to relatively high sediment temperatures at this site. Marcasite formation is likely dependent on the relatively low pH values of <7.1 found in interstitial waters of Site 504 sediments below 50 meters sub-bottom. Clinoptilolite evidently was formed by diagenetic alteration of rhyolitic volcanic glass or smectite plus biogenic silica within the chalk-limestone-chert sequence of Site 504, where opal-CT also reflects a high degree of silica dissolution and reprecipitation. This was a consequence of high temperatures (50-55 °C) at the base of the sediment column.

Age determination and stable isotope ratios of sediment core RC11-83

The Southern Ocean is perhaps the only region where fluctuations in the global influence of North Atlantic Deep Water (NADW) can be monitored unambiguously in single deep-sea cores. A carbon isotope record from benthic foraminifera in a Southern Ocean core reveals large and rapid changes in the flux of NADW during the last deglaciation, and an abrupt increase in the NADW production rate which immediately preceded large-scale melting of the Northern Hemisphere ice sheets. This sudden strengthening of the NADW thermoha-line cell provides strong evidence for the importance of NADW in glacial-interglacial climate change.