Stable carbon isotopic analyses of n-alkanes and the calculated C4 plant-derived fractions in the dust samples

Atmospheric dust samples collected along a transect off the West African coast have been investigated for their lipid content and compound-specific stable carbon isotope compositions. The saturated hydrocarbon fractions of the organic solvent extracts consist mainly of long-chain n-alkanes derived from epicuticular wax coatings of terrestrial plants. Backward trajectories for each sampling day and location were calculated using a global atmospheric circulation model. The main atmospheric transport took place in the low-level trade-wind layer, except in the southern region, where long-range transport in the mid-troposphere occurred. Changes in the chain length distributions of the n-alkane homologous series are probably related to aridity, rather than temperature or vegetation type. The carbon preference of the leaf-wax n-alkanes shows significant variation, attributed to a variable contribution of fossil fuel- or marine-derived lipids. The effect of this nonwax contribution on the d13C values of the two dominant n-alkanes in the aerosols, n-C29 and n-C31 alkane, is, however, insignificant. Their d13C values were translated into a percentage of C4 vs. C3 plant type contribution, using a two-component mixing equation with isotopic end-member values from the literature. The data indicate that only regions with a predominant C4 type vegetation, i.e. the Sahara, the Sahel, and Gabon, supply C4 plant-derived lipids to dust organic matter. The stable carbon isotopic compositions of leaf-wax lipids in aerosols mainly reflect the modern vegetation type along their transport pathway. Wind abrasion of wax particles from leaf surfaces, enhanced by a sandblasting effect, is most probably the dominant process of terrigenous lipid contribution to aerosols.

Distribution of coarse and fine sediment fractions at Site 178-1095

Fine-fraction (<63 µm) grain-size analyses of 530 samples from Holes 1095A, 1095B, and 1095D allow assessment of the downhole grain-size distribution at Drift 7. A variety of data processing methods, statistical treatment, and display techniques were used to describe this data set. The downhole fine-fraction grain-size distribution documents significant variations in the average grain-size composition and its cyclic pattern, revealed in five prominent intervals: (1) between 0 and 40 meters composite depth (mcd) (0 and 1.3 Ma), (2) between 40 and 80 mcd (1.3 and 2.4 Ma), (3) between 80 and 220 mcd (2.4 and 6 Ma), (4) between 220 and 360 mcd, and (5) below 360 mcd (prior to 8.1 Ma). In an approach designed to characterize depositional processes at Drift 7, we used statistical parameters determined by the method of moments for the sortable silt fraction to distinguish groups in the grainsize data set. We found three distinct grain-size populations and used these for a tentative environmental interpretation. Population 1 is related to a process in which glacially eroded shelf material was redeposited by turbidites with an ice-rafted debris influence. Population 2 is composed of interglacial turbidites. Population 3 is connected to depositional sequence tops linked to bioturbated sections that, in turn, are influenced by contourite currents and pelagic background sedimentation.