Organic geochemistry of two sediment cores from the Kara Sea

Within the Russian-German research project on "Siberian River Run-off (SIRRO)" devoted to the freshwater discharge and its influence on biological, geochemical, and geological processes in the Kara Sea, sedimentological and organic-geochemical investigations were carried-out on two well-dated sediment cores from the Yenisei Estuary area. The main goal of this study was to quantify the terrigenous organic carbon accumulation based on biomarker and bulk accumulation rate data, and its relationship to Yenisei river discharge and climate change through Holocene times. The biomarker data at both cores clearly indicate the predominance of terrigenous organic matter, reaching 70 to 100% and 50 to 80% of the total organic carbon within and directly north of the estuary, respectively. During the last about 9 Cal. kyrs. BP represented in the studied sediment section, siliciclastic sediment and (terrigenous) organic carbon input was strongly influenced by postglacial sea-level rise and climate-related changes in river discharge. The mid-Holocene Climatic Optimum is documented by maximum river discharge between 8.2 and 7.3 Cal. kyrs. BP. During the last 2000 years river discharge probably became reduced, and accumulation of both terrigenous and marine organic carbon increased due to increased coagulation of fine-grained material.

Calcareous nannofossil bioevents of early-middle Pleistocene sediments from the Mediterranean Sea and the Noth Atlantic

Quantitative distributions of calcareous nannofossils are analysed in the early-middle Pleistocene at the small Gephyrocapsa and Pseudoemiliania lacunosa zone transition in deep-sea cores from the Mediterranean Sea and North Atlantic Ocean (Ocean Drilling Program [ODP] Sites 977, 964 and 967, Deep Sea Drilling Project [DSDP] Site 607). The temporal and spatial mode of occurrence of medium-sized gephyrocapsids and reticulofenestrids has been examined to refine biostratigraphic constraints and evaluate possible relationships of stratigraphic patterns to environmental changes during a period of global climatic deterioration. The timing of bioevents has been calibrated using high-resolution sampling and correlation to the delta18O record in chronologically well-constrained sections. Newly identified events and ecostratigraphical signals enhance the stratigraphic resolution at the early-middle Pleistocene. The first occurrence (FO) of intermediate morphotypes between Pseudoemiliania and Reticulofenestra (Reticulofenestra sp.) is proposed as a reliable event within marine isotope stage (MIS) 35 or at the MIS 35/34 transition. The distribution of Reticulofenestra asanoi is characterized by rare and scattered occurrences in its lowest range, but the first common occurrence (FCO) is consistently identified at MIS 32 or 32/31; the last common occurrence (LCO) of the species is a distinctive event at MIS 23. In the studied interval, Gephyrocapsa omega dominates among medium-sized Gephyrocapsa. The FO of G. omega and contemporaneous re-entry of medium-sized gephyrocapsids at the lower-middle Pleistocene transition are diachronous between the Atlantic Ocean and Mediterranean Sea and from the western to eastern Mediterranean. In the Mediterranean, the LO of G. omega falls at MIS 15, insolation cycle 54 and is isochronous among the sites. Abundance fluctuations of G. omega show notable relations to early-middle Pleistocene climate changes; they considerably increase in abundance at the interglacial stages, suggesting warm water preferences. Gephyrocapsa omega temporarily disappears during the glacial MIS 22 and MIS 20. Above MIS 20, an impoverishment in G. omega and in the total abundance of medium-sized gephyrocapsids occurs. A decrease in abundance of G. omega is observed between the western Site 977 and the easternmost Site 967 in the Mediterranean Sea, as a possible response to high salinity and/or low nutrient content. Possible environmental influences on the distribution of R. asanoi and of Reticulofenestra sp. are discussed.

Concentrations of labile dissolved forms of Cu, Zn, Pb, and Cu in waters of the Kara Sea and Ob and Yenisey estuaries

Concentrations of labile dissolved forms of Cu, Zn, Pb, and Cu in waters of the Kara Sea and Ob and Yenisey estuaries measured on board during Cruise 49 of R/V Dmitry Mendeleev.

Stable isotope ratios measured on molluscan from the CRP sediment cores in the Ross Sea, Antarctica

Stable isotope analyses of marine bivalve growth increment samples have been used to estimate early Oligocene (29.4 - 31.2) Ma and early Miocene (24.0 Ma) seafloor palaeotemperature from the southwestern continental margin of the Ross Sea. Measured d18O values average +2.5 ? in the early Miocene and range between +1.26 to +3.24 ? in the early Oligocene. The results show that palaeoceanographic conditions in McMurdo Sound during the mid-Cenozoic were significantly different from those of today. The minimum estimated spring through late summer seasonal temperature range was 3°C during the early Miocene and between 1 and 5°C during the early Oligocene. This compares to the equivalent modern day range of <0.5°C within the sound. Absolute seawater temperatures at <100 m depth were of the order of 5 to 7°C during both time slices, compared to modern day values of -1.4 to - 1.9°C in the same area. The results are in broad agreement with early Oligocene Mg/Ca temperature estimates from deep Atlantic foraminifera as well as estimates from local terrestrial palynology and palaeobotany.

Investigations on volcanic rocks in sediment core CRP-3 from the Ross Sea, Antarctica

The petrography, mineralogy and geochemistry of volcanic and subvolcanic rocks in CRP-3 core have been examined in detail in order to characterise and to compare them with volcanic and subvolcanic rocks cropping out in the Victoria Land area, and to define the clast provenance or to establish possible volcanic activity coeval with deposition. Clasts with sizes ranging from granule to boulder show geochemical and mineralogical features comparable with those of Ferrar Supergroup rocks. They display a subalkaline affinity and compositions ranging from basalts to dacite. Three different petrographic groups with distinct textural and grain size features (subophitic, intergranular-intersertal, and glassy-hyalopilitic) are recognised and are related to the emplacement/cooling mechanism. In the sand to silt fraction, the few glass shards that have been recognised are strongly altered: however chemical analyses show they have subalkalic magmatic affinity. Mineral compositions of the abundant free clinopyroxene grains found in the core, are less affected by alteration processes, and indicate an origin from subalkaline magmas. This excludes the presence, during the deposition of CRP-3 rocks of alkaline volcanic activity comparable with the McMurdo Volcanic Group. Strong alteration of the magmatic body intruded the Beacon sandstones obliterates the original mineral assemblage. Geochemical investigations confirm that intrusion is part of the Ferar Large Igneous Province.

Environmental analysis on sediment core CRP-2 from the Ross Sea, Antarctica

Cape Roberts Project drill core 2/2A was obtained from Roberts Ridge, a sea-floor high located at 77° S, 16 km offshore from Cape Roberts in western McMurdo Sound, Antarctica. The recovered core is about 624 m long and includes strata dated as being Quaternary, Pliocene, Miocene and Oligocene in age. The core includes twelve facies commonly occurring in associations that are repeated in particular sequences throughout the core and which are interpreted as representing different depositional environments through time. Depositional systems inferred to be represented in the succession include: outer shelf with minor iceberg influence, outer shelf-inner shelf-nearshore to shoreface under iceberg influence, deltaic and/or grounding-line fan, and ice proximal-ice marginal-subglacial (mass flow/rainout diamictite/subglacial till) singly or in combination. Changes in palaeoenvironmental interpretations up the core are used to estimate relative glacial proximity to the site through time. These inferred glacial fluctuations are then compared with the global eustatic sea level and d18O curves to evaluate the potential of glacial fluctuations on Antarctica influencing these records of global change. Although the comparisons are tentative at present, the records do have similarities, but there are also some differences especially in possible number (and perhaps magnitude) of glacial fluctuations that require further evaluation.

Planktonic foraminifera and stable isotopic record of sediments from the east Sea of Korea

Foraminiferal assemblage and stable isotopic data are presented for three Quaternary piston cores from Ulleung Basin, East Sea of Korea ((ESK) Japan Sea) near the Korean Peninsula. Major changes in both temperature and salinity strongly affected surface and deep waters of the ESK during the transition from the Last Glacial Maximum (LGM) to the middle Holocene. Local environmental effects dominated during the LGM and the Bølling/Allerød (B/A) when the ESK became semi-isolated from the Pacific Ocean. Regional/global influences dominated following the B/A, after sufficient reconnection with the Pacific. This is reflected in the foraminiferal d18O record which was largely salinity-controlled before the Younger Dryas (YD) and temperature-controlled after the YD. Paleoceanographic changes in the ESK during the last deglaciation reflect sequential reconnection with the Pacific Ocean, through gateways, first (B/A) in the north (Tsugaru Strait) and later (Holocene) in the south (Korea Strait).