608 resultados para Barium.


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The petrography, mineralogy and geochemistry of volcanic and subvolcanic rocks in CRP-3 core have been examined in detail in order to characterise and to compare them with volcanic and subvolcanic rocks cropping out in the Victoria Land area, and to define the clast provenance or to establish possible volcanic activity coeval with deposition. Clasts with sizes ranging from granule to boulder show geochemical and mineralogical features comparable with those of Ferrar Supergroup rocks. They display a subalkaline affinity and compositions ranging from basalts to dacite. Three different petrographic groups with distinct textural and grain size features (subophitic, intergranular-intersertal, and glassy-hyalopilitic) are recognised and are related to the emplacement/cooling mechanism. In the sand to silt fraction, the few glass shards that have been recognised are strongly altered: however chemical analyses show they have subalkalic magmatic affinity. Mineral compositions of the abundant free clinopyroxene grains found in the core, are less affected by alteration processes, and indicate an origin from subalkaline magmas. This excludes the presence, during the deposition of CRP-3 rocks of alkaline volcanic activity comparable with the McMurdo Volcanic Group. Strong alteration of the magmatic body intruded the Beacon sandstones obliterates the original mineral assemblage. Geochemical investigations confirm that intrusion is part of the Ferar Large Igneous Province.

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Igneous rock units were encountered at four of the five sites drilled on Leg 30 of the Deep Sea Drilling Project. These units uncluded a diabase sill at Site 285, a basalt underlain by a gabbro at 286, two basalt flows at 287, and a basalt flow at 289. Site 285 is located approximately in the center of the South Fiji Basin, Site 286 is adjacent to a filled portion of the New Hebrides Trench, Site 287 is adjacent to a basement high in the Coral Sea Basin, and Sites 288 and 289 are located on the Ontong-Java Plateau north of the Solomon Islands (Figure 1). Figure 2 presents generalized lithologic columns for the igneous rock units found at these sites. When a unit number is given, e.g., Site 286, Unit 4 basalt, this number conforms with the unit number assigned to it in the overall stratigraphic sequence of that hole as defined in the individual Site Reports in this volume. Unless otherwise stated, depths are given as measured from the sediment-igneous rock contact rather than the mudline.

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Elemental concentrations were determined on 21 samples from Hole 1215A to evaluate the influence of hydrothermal sources on bulk sediment composition. Rare earth element (REE) concentrations were also determined on 10 of these samples. Concentration profiles and REE patterns are consistent with a strong hydrothermal influence on sediment composition at the base of Hole 1215A.

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Four samples of Nauru Basin basalts (Cores 94 to 109 of Hole 462A, sub-bottom depth 1077-1209 m) have 87Sr/86Sr ratios in the range 0.7037 to 0.7038, which is distinctly higher than the ratios of N-type MORB. The Rb contents of the samples are depleted in comparison with those of MORB and ocean-island basalts. These chemical and isotopic characteristics are identical to those of the basalts previously drilled during Leg 61 (Cores 75 to 90 of Hole 462A), and are explained in terms of inhomogeneity of the source region in the mantle or later alteration effects. Sr/Ca-Ba/Ca systematics of 15 samples from Cores 462A-94 to 462A-109 and 14 samples from Cores 462A-75 to 462A-90 suggest that the Nauru Basin basalts are derived from a mantle peridotite by 20 to 30% partial melting with subsequent Plagioclase crystallization.

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The basalts recovered during Legs 183 and 120 from the southern, central, and northernmost parts of the Kerguelen Plateau (Holes 1136A, 1138A, 1140A, and 747C, respectively), as well as those recovered from the eastern part of the crest of Elan Bank (Hole 1137A), represent derivates from tholeiitic melts. In the northern part of the Kerguelen Plateau (Hole 1140A), basalts may have formed from two sources located at different depths. This is reflected in the presence of both low- and high-titanium basalts. The basalts are variably altered by low-temperature hydrothermal processes (at temperatures up to 120°C), and some are affected by subaerial weathering. The hydrothermal alteration led mainly to the formation of smectites, chlorite minerals, mixed-layer hydromica-smectite and smectite-chlorite minerals, hydromica, serpentine(?), clinoptilolite, heulandite, stilbite, analcime, mordenite, thomsonite, natrolite(?), calcite, quartz, and dickite(?). Alteration of extrusive basalts is mainly related to horizontal fluid flow within permeable contact zones between lava flows. Under a nonoxidizing environment of alteration, the tendency to lose most of elements, including rare earth elements, from basalts dominates. Under on oxidizing environment, basalts accumulate many elements.