Physical Oceanography in the tropical Atlantic oxygen minimum zone

The replenishment of consumed oxygen in the open ocean oxygen minimum zone (OMZ) off northwest Africa is accomplished by oxygen transport across and along density surfaces, i.e. diapycnal and isopycnal oxygen supply. Here the diapycnal oxygen supply is investigated using a large observational set of oxygen profiles and diapycnal mixing data from years 2008 to 2010. Diapycnal mixing is inferred from different sources: (i) a large-scale tracer release experiment, (ii) microstructure profiles, and (iii) shipboard?acoustic current measurements plus density profiles. From these measurements, the average diapycnal diffusivity in the studied depth interval from 150 to 500m is estimated to be 1×10**-5 m2 s**-1, with lower and upper 95% confidence limits of 0.8×10**-5 m2 s**-1 and 1.4×10**-5 m2 s**-1. Diapycnal diffusivity in this depth range is predominantly caused by turbulence, and shows no significant vertical gradient. Diapycnal mixing is found to contribute substantially to the oxygen supply of the OMZ. Within the OMZ core, 1.5 µmol kg**-1 yr**-1 of oxygen is supplied via diapycnal mixing, contributing about one-third of the total demand. This oxygen which is supplied via diapycnal mixing originates from oxygen that has been laterally supplied within the upper CentralWater layer above the OMZ, and within the Antarctic Intermediate Water layer below the OMZ. Due to the existence of a separate shallow oxygen minimum at about 100m depth throughout most of the study area, there is no net vertical oxygen flux from the surface layer into the Central Water layer. Thus all oxygen supply of the OMZ is associated with remote pathways.

On the role of circulation and mixing in the ventilation of oxygen minimum zones with a focus on the eastern tropical North Atlantic

Ocean observations carried out in the framework of the Collaborative Research Center 754 (SFB 754) "Climate-Biogeochemistry Interactions in the Tropical Ocean" are used to study (1) the structure of tropical oxygen minimum zones (OMZs), (2) the processes that contribute to the oxygen budget, and (3) long-term changes in the oxygen distribution. The OMZ of the eastern tropical North Atlantic (ETNA), located between the well-ventilated subtropical gyre and the equatorial oxygen maximum, is composed of a deep OMZ at about 400 m depth with its core region centred at about 20° W, 10° N and a shallow OMZ at about 100 m depth with lowest oxygen concentrations in proximity to the coastal upwelling region off Mauritania and Senegal. The oxygen budget of the deep OMZ is given by oxygen consumption mainly balanced by the oxygen supply due to meridional eddy fluxes (about 60%) and vertical mixing (about 20%, locally up to 30%). Advection by zonal jets is crucial for the establishment of the equatorial oxygen maximum. In the latitude range of the deep OMZ, it dominates the oxygen supply in the upper 300 to 400 m and generates the intermediate oxygen maximum between deep and shallow OMZs. Water mass ages from transient tracers indicate substantially older water masses in the core of the deep OMZ (about 120-180 years) compared to regions north and south of it. The deoxygenation of the ETNA OMZ during recent decades suggests a substantial imbalance in the oxygen budget: about 10% of the oxygen consumption during that period was not balanced by ventilation. Long-term oxygen observations show variability on interannual, decadal and multidecadal time scales that can partly be attributed to circulation changes. In comparison to the ETNA OMZ the eastern tropical South Pacific OMZ shows a similar structure including an equatorial oxygen maximum driven by zonal advection, but overall much lower oxygen concentrations approaching zero in extended regions. As the shape of the OMZs is set by ocean circulation, the widespread misrepresentation of the intermediate circulation in ocean circulation models substantially contributes to their oxygen bias, which might have significant impacts on predictions of future oxygen levels.