Major-oxides and trace-elements at DSDP Hole 78-543A

Four chemically distinct basalts were cored in 44 m of basement penetration at Deep Sea Drilling Project Site 543, in Upper Cretaceous crust just seaward of the deformation front of the Barbados Ridge and north of the Tiburon Rise. All four types are moderately fractionated abyssal tholeiites. The four types have different magnetic inclinations, all of reversed polarity, suggesting eruption at different times which recorded secular variation of the earth's magnetic field. Extensive replacement of Plagioclase by K-feldspar has occurred at the top of the basalts, giving analyses with K2O contents up to 5 %. The earliest stages of alteration were dominantly oxidative, resulting in fractures lined with celadonite and dioctahedral smectite, and pervasive replacement of olivine and most intersertal glass with iron hydroxides and green clay minerals. Latef, non-oxidative alteration resulted in formation of olive-green clays and pyrite veins in a portion of the rocks. Basalts affected by this alteration actually lost K2O (to abundances lower than in adjacent fresh basalt glasses), and gained MgO (to abundances higher than in the glasses). Finally, fractures and interpillow voids were lined with calcite, sealing in much fresh glass. Oxygen-isotope measurements on the calcite indicate that this occurred at 12 to 25C. Either altering fluids were warm or the basalts had become buried with a considerable thickness of sediments, such that temperatures increased until a conductive thermal gradient was established, when the veining occurred.

(Table 1) Major and trace elements of basalts at DSDP Hole 72-516F

The geochemistry of basalts recovered during Leg 72 is described with emphasis on trace elements. Only Hole 516F penetrated basement; the basalts recovered are plagioclase-phyric and olivine-phyric and pervasively altered. Chemically, the basalts from Hole 516F are rather uniform in composition. However, four distinct geochemical units can be recognized, although the chemistry of two of the units appears to be controlled by chemical mobility associated with alteration. The two less-altered units cannot be related by fractional crystallization processes. Hole 516F basalts have a trace element chemistry characteristic of T-type mid-ocean ridge basalt; rare-earth element patterns (as indicated by Ce/Y ratios) are mildly fractionated flight rare-earth element enriched), and a number of incompatible element ratios are close to chondritic.

Geochemistry of ODP Site 131-808 muds and mudstones

The principal aims of undertaking a shore-based bulk inorganic geochemical analysis of muds and mudstones from Site 808 were as follows: 1. Characterize the geochemical signature of the muds and mudstones at regular intervals downhole to sample and identify any changes in sediment type and provenance. 2. Integrate the inorganic geochemistry with the shipboard and more detailed land-based laboratory studies of the clay minerals. 3. Investigate any possible inorganic geochemical anomalies associated with the décollement.