Chemical composition of manganese nodules and crusts from the Pacific and Indian Ocean and Loch Fyne, Scotland

The first part of this thesis includes some topics of a non-geochemical nature but which are of importance in interpreting the geochemistry of nodules. The points covered include their distribution, petrography, structure, mineralogy and internal compositional variations. Part Two includes the geochemistry of both nodules and that of their surrounding sediments, This geochemical study has been divided into firstly, a general geochemical study of both nodules and sediments using a statistical approach to the interpretation of the data, secondly, the regional geochemistry of Pacific and Indian Ocean nodules and sediments, the latter entirely uninvestigated in the past, and thirdly, local variations in the composition of nodules. Throughout, emphasis has been placed on the geochemistry of nodules in terms of their environment of formation.

Annotated record of the detailed examination of Mn deposits from DODO Expedition stations

The cores and dredges described in this report were taken on the DODO Expedition in May 1964 until December 1964 by the Scripps Institution of Oceanography from the R/V Argo. A total of 290 cores and dredges were recovered and are available at Scripps for sampling and study.

Sedimentological and geophysical investigation of sediment cores from the Amundsen Sea

Ice loss from the marine-based, potentially unstable West Antarctic Ice Sheet (WAIS) contributes to current sea-level rise and may raise sea level by up to 3.3 to 5 meters in the future. Over the past few decades, glaciers draining the WAIS into the Amundsen Sea Embayment (ASE) have shown accelerated ice flow, rapid thinning and grounding-line retreat. However, the long-term context of this ice-sheet retreat is poorly constrained, limiting our ability to accurately predict future WAIS behaviour. Here we present a new chronology for WAIS retreat from the inner continental shelf of the eastern ASE based on radiocarbon dates from three marine sediment cores. The ages document a retreat of the grounding line to within ~93 km of its modern position before 11.7±0.7 kyr BP (thousand years before present). This early deglaciation is consistent with ages for grounding-line retreat from the western ASE. Our new data demonstrate that, other than in the Ross Sea, WAIS retreat in the ASE has not continued progressively since the Last Glacial Maximum. Furthermore, our results suggest that the grounding-line position in the ASE was predominantly stable throughout the Holocene, and that any episodes of fast retreat similar to that observed today must have been short-lived. Alternatively, today's rapid retreat was unprecedented during the Holocene. Therefore, the current ice loss must originate in recent changes in regional climate, ocean circulation or ice-sheet dynamics. Incorporation of these results into models is essential to produce robust predictions of future ice-sheet change and its contribution to sea-level rise.

Annotated record of the detailed examination of Mn deposits from the FANFARE Expedition stations

The cores described in this report were taken on the FANFARE Expedition in July 1959 by Scripps Institution of Oceanography from the R/V H. M. Smith and the R/V Spencer F. Baird. A total of 49 cores and dredges were recovered and are available at Scripps for sampling and study. The coring sites, all in the eastern tropical central Pacific.

Physical, Geochemical, Geomechanical, Geophysical and Hydrodynamic Characterization and Anisotropy Assessment of Corvio Sandstone

Corvio sandstone is a ~20 m thick unit (Corvio Formation) that appears in the top section of the Frontada Formation (Campoó Group; Lower Cretaceous) located in Northern Spain in the southern margin of the Basque-Cantabrian Basin. Up to 228 plugs were cored from four 0.3 x 0.2 x 0.5 m blocks of Corvio sandstone, to perform a comprehensive characterization of the physical, mineralogical, geomechanical, geophysical and hydrodynamic properties of this geological formation, and the anisotropic assessment of the most relevant parameters. Here we present the first data set obtained on 53 plugs which covers (i) basic physical and chemical properties including density, porosity, specific surface area and elementary analysis (XRF - CHNS); (ii) the curves obtained during unconfined and confined strengths tests, the tensile strengths, the calculated static elastic moduli and the characteristic stress levels describing the brittle behaviour of the rock; (iii) P- and S-wave velocities (and dynamic elastic moduli) and their respective attenuation factors Qp and Qs, electrical resistivity for a wide range of confining stress; and (iv) permeability and transport tracer tests. Furthermore, the geophysical, permeability and transport tests were additionally performed along the three main orthogonal directions of the original blocks, in order to complete a preliminary anisotropic assessment of the Corvio sandstone.

Data compilation on the biological response to ocean acidification: environmental and experimental context of data sets and related literature

The exponential growth of studies on the biological response to ocean acidification over the last few decades has generated a large amount of data. To facilitate data comparison, a data compilation hosted at the data publisher PANGAEA was initiated in 2008 and is updated on a regular basis (doi:10.1594/PANGAEA.149999). By January 2015, a total of 581 data sets (over 4 000 000 data points) from 539 papers had been archived. Here we present the developments of this data compilation five years since its first description by Nisumaa et al. (2010). Most of study sites from which data archived are still in the Northern Hemisphere and the number of archived data from studies from the Southern Hemisphere and polar oceans are still relatively low. Data from 60 studies that investigated the response of a mix of organisms or natural communities were all added after 2010, indicating a welcomed shift from the study of individual organisms to communities and ecosystems. The initial imbalance of considerably more data archived on calcification and primary production than on other processes has improved. There is also a clear tendency towards more data archived from multifactorial studies after 2010. For easier and more effective access to ocean acidification data, the ocean acidification community is strongly encouraged to contribute to the data archiving effort, and help develop standard vocabularies describing the variables and define best practices for archiving ocean acidification data.

Lithostratigraphy determined from downhole logs in the AND-2A borehole

During the 2007-2008 austral spring season, the ANDRILL (Antarctic Drilling project) Southern McMurdo Sound Project recovered an 1138-m-long core, representing the last 20 m.y. of glacial history. An extensive downhole logging program was successfully carried out. Due to drill hole conditions, logs were collected in several passes from the total depth at 1138.54 m below seafloor (mbsf) to 230 mbsf. After data correction, several statistical methods, such as factor analysis, cluster analysis, box-and-whisker diagrams, and cross-plots, were applied. The aim of these analyses was to use detailed interpretation of the downhole logs to obtain a description of the lithologies and their specific physical properties that is independent of the core descriptions. The sediments were grouped into the three main facies, diamictite, mudstone and/or siltstone, and sandstone, and the physical properties of each were determined. Notable findings include the high natural radioactivity values in sandstone and the high and low magnetic susceptibility values in mudstone and/or siltstone and in sandstone. A modified lithology cluster column was produced on the basis of the downhole logs and statistical analyses. It was possible to use the uranium content in the downhole logs to determine hiatuses and thus more accurately place the estimated hiatuses. Using analyses from current literature (geochemistry, clasts, and clay minerals) in combination with the downhole logs (cluster analysis), the depths 225 mbsf, 650 mbsf, 775 mbsf, and 900 mbsf were identified as boundaries of change in sediment composition, provenance, and/or environmental conditions. The main use of log interpretation is the exact definition of lithological boundaries and the modification of the paleoenvironmental interpretation.