(Table 2) Ba/Ca ratios of Cibicides wuellerstorfi and Orbulina universa from Bahaman sediment cores

This geochemical investigation utilizes Ba/Ca in the benthic foraminifer Cibicides wuellerstorfi from cores taken from the Bahama Banks and the Caribbean Sea to reconstruct changes in basal thermocline ventilation (800-1000 m) and middepth thermohaline circulation (1000-2000 m) in the western North Atlantic during the last glacial period, focusing on the deglacial transition. Previous studies show that an increase in ventilation of the North Atlantic subtropical gyre during the Last Glacial Maximum (LGM) caused a 30-60% decrease in labile nutrients within the thermocline layer. Using foraminiferal Ba/Ca as a proxy of refractory nutrients, increased ventilation during the LGM produced a depletion of less than 20% compared to Holocene values. Following glaciation, the production of Glacial North Atlantic Intermediate Water (GNAIW) shut down owing to the presence of meltwater in the surface ocean, which resulted in a decrease in ventilation, as seen by an enrichment of barium in the basal thermocline. GNAIW was subsequently replaced by barium-rich southern component water in the middepth western North Atlantic. Foraminiferal Ba/Ca data suggest a 38% contribution from southern component water to a depth as shallow as 1475 m and a 14% contribution at 1123 m during deglaciation.

Benthic foraminiferal stable isotope record from ODP Site 138-849 on the East Pacific Rise

Benthic foraminifer and delta13C data from Site 849, on the west flank of the East Pacific Rise (0°11 'N, 110°31'W; 3851 m), give relatively continuous records of deep Pacific Ocean stable isotope variations between 0 and 5 Ma. The mean sample spacing is 4 k.y. Most analyses are from Cibicides wuellerstorfi, but isotopic offsets relative to Uvigerina peregrina appear roughly constant. Because of its location west of the East Pacific Rise, Site 849 yields a suitable record of mean Pacific Ocean delta13C, which approximates a global oceanic signal. The ~100-k.y.-period climate cycle, which is prevalent in delta18O does not dominate the long-term delta13C record. For delta13C, variations in the ~400- and 41-k.y. periods are more important. Phase lags of delta13C relative to ice volume in the 41- and 23-k.y. bands are consistent with delta13C as a measure of organic biomass. A model-calculated exponential response time of 1-2 k.y. is appropriate for carbon stored in soils and shallow sediments responding to glacial-interglacial climate change. Oceanic delta13C leads ice volume slightly in the 100-k.y. band, and this suggests another process such as changes in continental weathering to modulate mean river delta13C at long periods. The delta13C record from Site 849 diverges from that of Site 677 in the Panama Basin mostly because of decay of 13C-depleted organic carbon in the relatively isolated Panama Basin. North Atlantic to Pacific delta13C differences calculated using published data from Sites 607 and 849 reveal variations in Pliocene deep water within the range of those of the late Quaternary. Maximum delta13C contrast between these sites, which presumably reflects maximum influx of high-delta13C northern source water into the deep North Atlantic Ocean, occurred between 1.3 and 2.1 Ma, well after the initiation of Northern Hemisphere glaciation. Export of high-delta13C North Atlantic Deep Water from the Atlantic to the circumpolar Antarctic, as recorded by published delta13C data from Subantarctic Site 704, appears unrelated to the North Atlantic-Pacific delta13C contrast. To account for this observation, we suggest that deep-water formation in the North Atlantic reflects northern source characteristics, whereas export of this water into the circumpolar Antarctic reflects Southern Hemisphere wind forcing. Neither process appears directly linked to ice-volume variations.

Age models and stabile isotope ratios from SO35 cores

Stable isotope measurements on the planktonic foraminifer Globigerinoides ruber (white) have been carried out on a number of selected deep-seas sediment cores from the South Lau and Norlh Fiji Basins. The d18O-curves show good correlation with the inter-ocean oraphic correlation composite d18O-record of the standard reference section (Prell et al. 1986), which, in combination with the chronostratigraphic classifications of Herterich & Sarnthein (1984, modified) and Imbrie et al. 1984), allows a detailed dating of the sedimentary sequences. The deepest layers in core no. 119 (southern Lau Basin) could be assigned to Isotope Stage 24. Measurements made on bulk carbonate in two cores show a much higher glacial-interglacial amplitude, allowing the general identification of the conventional oxygen isotope stages. The d13C-values of the benthic foraminifer Cibicidoides wuellerstorfi show progressively lighter values northwards reflecting an increasing contribution of the isotopically lighter CO2 from the remineralisation of organic matter during the general northward movement of the deep water masses. Cyclicities in the sedimentation rates were observed in core nos. 117 and 119 (both southern Lau Basin) where the interglacials exhibit higher levels than the glacials. Calculated new or export paleoproductivity show that the glacials had higher productivity in the euphotic zone. From the oxygen isotope stratigraphy, the five ash layers in core nos. 117 and 119 could be dated as about 530 ka B.P. in Stage 14, 695 ka B.P. in Stage 18, 775 ka B.P. in Stage 21, 790 ka B.P. and 825 ka B.P. in Stage 22. Carbonate dissolution occurred during stages 5, 8 and 10 to 12.

Stable isotope record of benthic and planktonic foraminifera from ODP Site 175-1087 in the southern Cape Basin, Atlantic Ocean

High-resolution planktonic and benthic stable isotope records from Ocean Drilling Program Site 1087 off southeast Africa provide the basis for a detailed study of glacial-interglacial (G-IG) cycles during the last 500 k.y. This site is located in the Southern Cape Basin at the boundary of the coastal upwelling of Benguela and close to the gateway between the South Atlantic and the Indian Oceans. It therefore monitors variations of the hydrological fronts associated with the upwelling system and the Atlantic-Indian Ocean interconnections, in relation to global climate change. The coldest period of the last 500 k.y. corresponds to marine isotope Stage (MIS) 12, when surface water temperature was 4°C lower than during the last glacial maximum (LGM) as recorded by the surface-dwelling foraminifer Globigerinoides ruber. The warmest periods occurred during MISs 5 and 11, a situation slightly different to that observed at Site 704, which is close to the Polar Front Zone, where there is no significant difference between the interglacial stages for the past 450 k.y., except the long period of warmth during MIS 11. The planktonic and benthic carbon isotope records do not follow the G-IG cycles but show large oscillations related to major changes in the productivity regime. The largest positive 13C excursion between 260 and 425 ka coincides with the global mid-Brunhes event of carbonate productivity. The oxygen and carbon isotopic gradients between surface and deep waters display long-term changes superimposed on rapid and high-frequency fluctuations that do not follow the regular G-IG pattern; these gradients indicate modifications of the temperature, salinity, and productivity gradients due to changes in the thermocline depth, the position of the hydrological fronts, and the strength of the Benguela Current.

Age determination and sea surface temperature reconstruction for the Southern Ocean

The isotopic and micropaleontological deglacial records of three deep-sea cores from 44°S to 55°S have been dated by accelerator mass spectrometry. The available records did not allow accurate dating of the initiation of the deglaciation. By 13,000 years B.P., sea surface temperatures reached values similar to the present values. A cool oscillation abruptly interrupted this warm phase between 12,000 and 11,000 years B.P. Initiation of this cooling therefore preceded the northern hemisphere Younger Dryas by approximately 1000 years. Complete warming was reached by 10,000 years B.P., more or less synchronous with the northeast Atlantic Ocean.

Geochemistry of sediments in the central equatorial Pacific Ocean

In order to quantify changes in export production and carbonate dissolution over the past 1 Myr in the central equatorial Pacific Ocean we analyzed Ba, P, Al Ti, and Ca in 1106 samples from five piston cores gathered from 5°S to 4°N at 140°W. We focused on Ba/Ti, Al/Ti, and P/Ti ratios as export proxies and employed areally integrated time slice as well as time series strategies. Carbonate maxima from 0-560 kyr are characterized by 15-30% greater export than carbonate minima. The increases in export fall on glacial delta18O transitions rather than glacial maxima. From 560-800 kyr, overlapping with the mid-Pleistocene transition, there is a very large increase in total export yet no glacial-interglacial variability. The highest latitudes (5°S and 4°N) record minimal absolute export change from glacials to interglacials and yet record the most extreme minima in percent CaCO3, indicating that carbonate records there are dominated by dissolution, whereas near the equator they are more influenced by changes in export.

Stable isotope record and age determination of ODP Site 121-758 in the northeastern Indian Ocean

Numerous studies have shown that delta18O records from benthic and planktonic foraminifera, primarily a proxy of global ice volume variations, reflect Milankovitch periodicities. To study climatic response to orbital forcing at Ocean Drilling Program site 758, we have generated continuous delta18O and delta13C records from a single benthic foraminiferal species Cibicides wuellerstorfi for the last 3.6 m.y. and extended the planktonic foraminiferal isotope records of Farrell and Janecek (1991, doi:10.2973/odp.proc.sr.121.124.1991) (0-2.5 Ma, based on Globigerinoides sacculifer) to 3.6 Ma (Chen, 1994). We then constructed an age model by matching, correlating and tuning the benthic delta18O record to a model simulation of ice volume (Imbrie and Imbrie, 1980, doi:10.1126/science.207.4434.943). The filtered 41- and 23-kyr signals based on the resultant astronomically tuned age model are highly correlated to obliquity (r=0.83) and precession (r=0.75), respectively. Although derived with methodology different from Shackleton et al. (1990) and Hilgen (1991, doi:10.1016/0012-821X(91)90206-W, 1991, doi:10.1016/0012-821X(91)90082-S), our results generally agree with their published astronomical timescales for the time interval from 0 to 3.0 Ma, providing additional support for the newly emerging chronology based on orbital tuning. Slight discrepancies exist in the time interval from 3.0 to 3.6 Ma, suggesting several possibilities, including differences in the approaches of orbital tuning and the relatively low amplitude of delta18O variations in our record. However, even if the discrepancies are due to the relatively low amplitude of the isotope signals in our record at 3.0-3.6 Ma, our resultant timescale as a whole does not adversely affect our evaluation of the paleoclimatology and paleoceanography of the Indian Ocean, such as the evolution of the 100-, 41- and 23-kyr cycles, and variation of global ice volume and deepwater temperature during the past 3.6 m.y.

Age model, stable isotopes, major element proportions and endmember unmixing results from four western tropical Atlantic cores

We investigate changes in the delivery and oceanic transport of Amazon sediments related to terrestrial climate variations over the last 250 ka. We present high-resolution geochemical records from four marine sediment cores located between 5 and 12° N along the northern South American margin. The Amazon River is the sole source of terrigenous material for sites at 5 and 9° N, while the core at 12° N receives a mixture of Amazon and Orinoco detrital particles. Using an endmember unmixing model, we estimated the relative proportions of Amazon Andean material ("%-Andes", at 5 and 9° N) and of Amazon material ("%-Amazon", at 12° N) within the terrigenous fraction. The %-Andes and %-Amazon records exhibit significant precessional variations over the last 250 ka that are more pronounced during interglacials in comparison to glacial periods. High %-Andes values observed during periods of high austral summer insolation reflect the increased delivery of suspended sediments by Andean tributaries and enhanced Amazonian precipitation, in agreement with western Amazonian speleothem records. Increased Amazonian rainfall reflects the intensification of the South American monsoon in response to enhanced land-ocean thermal gradient and moisture convergence. However, low %-Amazon values obtained at 12° N during the same periods seem to contradict the increased delivery of Amazon sediments. We propose that reorganizations in surface ocean currents modulate the northwestward transport of Amazon material. In agreement with published records, the seasonal North Brazil Current retroflection is intensified (or prolonged in duration) during cold substages of the last 250 ka (which correspond to intervals of high DJF or low JJA insolation) and deflects eastward the Amazon sediment and freshwater plume.

Benthic foraminiferal stable isotope stratigraphy of ODP Site 138-846 in the tropical Pacific Ocean

A stable-isotope stratigraphy at Site 846 (tropical Pacific, 3°06'S, 90°49'W, 3307 m water depth), based on the benthic foraminifers Cibicides wuellerstorfi and Uvigerina peregrina, yields a high-resolution record of deep-sea delta18O and delta13C over the past 1.8 Ma, with an average sampling interval of 3 k.y. Variance in the delta18O and delta13C records is concentrated in the well-known orbital periods of 100, 41, and 23 k.y. In the 100-k.y. band, both isotopic signals grow from relatively low amplitudes prior to 1.2 Ma, to high amplitudes in the late Quaternary since 0.7 Ma. The amplitude of delta18O and especially of delta13C decreases in the 41-k.y. band as it grows in the 100-k.y. band, consistent with a transfer of energy into an orbitally-paced internal oscillation. A weak 30-k.y. rhythm, present in both delta18O and delta13C, may reflect nonlinear interaction between the 41-k.y. and 100-k.y. bands in the evolving climate system. In the 23-k.y. and 19-k.y. bands associated with orbital precession, delta18O and delta13C are not coherent with each other on long time scales, and do not evolve like the 100-k.y. and 41-k.y. bands. This suggests that the source of the growing 100-k.y. oscillation is not a nonlinear response to precession, in contrast to predictions of some climate models. Sedimentation rates at this site also vary with a strong 100-k.y. cycle. Unlike the isotope records, the amplitude of 100-k.y. variations in sedimentation rate is relatively constant over the past 1.8 Ma, ranging from about 15 to 70 m/m.y. Prior to 0.9 Ma, sedimentation rates co-vary with orbital eccentricity, rather than with global climate as reflected by delta18O or delta13C. A source of this 100-k.y. cycle of sedimentation rate in the absence of similar ice volume fluctuations may be precessional heating of equatorial land masses, which in an energy balance climate model drives variations of monsoonal climates with a 100-k.y. rhythm. For the interval younger than 0.9 Ma, high sedimentation rates in the 100-k.y. band are consistently associated with glacial stages. This change of pattern suggests that when the amplitude of glacial cycles become large enough, their global effects overpower a local monsoon-driven variation in sedimentation rate at Site 846.

Epibenthic foraminifera stable isotope and planktic foraminifera Ba/Ca data of sediment core MD03-2664

Deep ocean circulation has been considered relatively stable during interglacial periods, yet little is known about its behavior on submillennial time scales. Using a subcentennially resolved epibenthic foraminiferal d13C record we show that North Atlantic Deep Water (NADW) influence was strong at the onset of the last interglacial period and then interrupted by several prominent, centennial-scale reductions. These NADW transients occurred during periods of increased ice rafting and southward expansions of polar water influence, suggesting that a buoyancy threshold for convective instability was triggered by freshwater and circum-Arctic cryosphere changes. The deep Atlantic chemical changes were similar in magnitude to those associated with glaciations, implying that the canonical view of a relatively stable interglacial circulation may not hold for conditions warmer/fresher than at present.