Accumulation rates of sediments and main sedimentary components in ODP Leg 121 holes on Broken Ridge

Broken Ridge, in the eastern Indian Ocean,is overlain by about 1600 m of middle Cretaceous to Pleistocene tuffaceous and carbonate sediments that record the oceanographic history of southern hemisphere mid-to high-latitude regions. Prior to about 42 Ma, Broken Ridge formed the northern part of the broad Kerguelen-Broken Ridge Plateau. During the middle Eocene, this feature was split by the newly forming Southeast Indian Ocean Ridge; since then, Broken Ridge has drifted north from about 55° to 31°S. The lower part of the sedimentary section is characterized by Turonian to Santonian tuffs that contain abundant glauconite and some carbonate. The tuffs record a large but apparently local volcanic input that characterized the central part of Broken Ridge into the early Tertiary. Maestrichtian shallow-water(several hundred to 1000 m depth) limestones and cherts accumulated at some of the highest rates ever documented from the open ocean, 4 to 5 g/cm**2/kyr. A complete (with all biostratigraphic zones) Cretaceous-Tertiary boundary section was recovered from site 752. The first 1.5 m.y. of the Tertiary is characterized by an order-of-magnitude reduction in the flux of biogenic sediments, indicating a period of sharply reduced biological productivity at 55°S, following which the carbonate and silica sedimentation rates almost reach the previous high values of the latest Cretaceous. We recovered a complete section through the Paleocene that contains all major fossil groups and is more than 300 m thick, perhaps the best pelagic Paleocene section encountered in ocean drilling. About 42 Ma, Broken Ridge was uplifted 2500 m in response to the intra-plateau rifting event; subsequent erosion and deposition has resulted in a prominent Eocene angular unconformity atop the ridge. An Oligocene disconformity characterized by a widespread pebble layer probably represents the 30 Ma sea-level fall. The Neogene pelagic ooze on Broken Ridge has been winnowed, and thus its grain size provides a direct physical record of the energy of the southern hemisphere drift current in the Indian Ocean for the past 30 m.y.

Phosphorus components, CaCO3 and biogenic opal in sediments from ODP Leg 167 sites

The ocean history of reactive phosphorus (P) (i.e., dissolved P available to fuel oceanic primary productivity) is of interest because of the role of P as a biolimiting nutrient, and knowledge of P burial in marine sediments is key to testing hypotheses about temporal changes in P input or output fluxes. Our understanding of the history of the P cycle over the Cenozoic has increased substantially with temporal records of reactive P mass accumulation rates from open-ocean Pacific and Atlantic equatorial sites. However, questions about the relative importance of nutrient burial in ocean-margin sediments relative to burial in open-ocean sediments and about the extent of P remobilization in organic-rich, reducing environments characteristic of margin sediments remain unresolved. Nutrient burial in oceanic boundary current systems has been suggested to have a controlling role in oceanic nutrient budgets in certain time intervals (Vincent and Berger, 1985, doi:10.1029/GM032p0455), with higher sediment accumulation rates balancing the limited spatial extent of these sediments. Some investigators suggest that remobilization of P from reducing sediments in margin settings is a significant positive feedback to primary productivity (e.g., Van Cappellan and Ingall, 1994, doi:10.1029/94PA01455), whereas other results indicate that both P uptake and P release may occur in these settings depending on the balance of organic carbon and iron supply to the sediments and on the oxygenation of bottom waters (McManus et al., 1997, doi:10.1016/S0016-7037(97)00138-5). It is important to quantitatively understand the geochemistry of reactive P in margin sediments, where productivity and delivery of organic-rich material to the sediments in relatively shallow-water settings is often sufficient to promote anoxia in interstitial waters. To address these questions, we determined the P concentrations and geochemistry in sediment samples from eight sites drilled during Ocean Drilling Program (ODP) Leg 167, California margin (Sites 1010-1012, 1014, 1016-1017, and 1021-1022). These results are the first records of reactive P concentrations on long time scales-required for the calculation of P accumulation rates-for sediments from a highly productive eastern boundary current setting. In addition, we determined calcium carbonate contents and biogenic silica concentrations to define the environments of sedimentary production, burial, and diagenesis.

Siliceous components of Pliocene-Holocene sediments of the South Atlantic

The Pliocene-Holocene sediments recovered on ODP Leg 114 from Holes 699A, 701C, and 704B are the subject of a detailed investigation to interpret changes in the Oceanographic environment of the South Atlantic in the vicinity of the Polar Front Zone (PFZ). The cores sample sediments at shallow (Hole 704B, 2532 m), intermediate (Hole 699A, 3716 m), and basinal (Hole 701C, 4647 m) depths. Sites 699 and 704 come under the influence of the Antarctic Circumpolar Current (ACC) and Circumpolar Deep Water. It is possible that the upper reaches of Antarctic Bottom Water (AABW) may also affect Hole 699A. Site 701 is influenced by AABW. Closely spaced samples were analyzed for grain-size distribution, sand fraction components, biosiliceous microfossils, organic carbon, and water content. PFZ migrations are traced using changes in bulk sedimentaccumulation rates and the abundance of the diatoms Actiniscus ssp. and Genus et species indet. 1 Fenner (1991), as well as changes in sediment grain size and composition. Diatomaceous sediments of Gilbert age in Hole 699A indicate that the PFZ was positioned over this site, but during the Gauss it migrated north, bringing in less productive Antarctic Surface Water. All cores document a very gradual southerly movement of the PFZ throughout the Matuyama (with some sharp fluctuations of the northen PFZ border over Site 704 between 1.45 and 1.83 m.y.). This regressive shift culminated in the late Matuyama. The latest Matuyama to earliest Brunhes record in Hole 699A has been removed by a hiatus lasting from 1.0 to 0.6 m.y., which was probably caused by intensification of the deep-reaching ACC. The corresponding interval in Hole 704B, the shallowest core, contains evidence of winnowing. Sharp fluctuations of large amplitude and high frequency in the lithology of the sediments from Hole 704B in the eastern South Atlantic, starting at about 0.75 m.y. and characterizing the whole Brunhes Epoch, record the rapid movement of the northern border of the PFZ over the site. These reflect strong glacial/interglacial alternations in climate. To a lesser extent, lithologic fluctuations in Hole 701C reflect the same phenomenon, whereas in Hole 699A the lithology does not vary as dramatically.

Concentrations and accumulation rates of chemical elements and sediment components in sediments of central equatorial Pacific, DSDP data

Accumulation rates of Mg, Al, Si, Mn, Fe, Ni, Cu, Zn, opal, and calcium carbonate have been calculated from their concentrations in samples from equatorial Deep Sea Drilling Project sites. Maps of element accumulation rates and of Q-mode factors derived from raw data indicate that the flux of trace metals to equatorial Pacific sediments has varied markedly through time and space in response to changes in the relative and absolute influence of several depositional influences: biogenic, detrital, authigenic, and hydrothermal sedimentation. Biologically derived material dominates the sediment of the equatorial Pacific. The distributions of Cu and Zn are most influenced by surface-water biological activity, but Ni, Al, Fe, and Mn are also incorporated into biological material. All of these elements have equatorial accumulation maxima similar to those of opal and calcium carbonate at times during the past 50 m.y. Detritus distributed by trade winds and equatorial surface circulation contributes Al, non-biogenic Si, Fe, and Mg to the region. Detrital sediment is most important in areas with a small supply of biogenic debris and low bulk-accumulation rates. Al accumulation generally increases toward the north and east, indicating its continental source and distribution by the northeast trade winds. Maxima in biological productivity during middle Eocene and latest Miocene to early Pliocene time and concomitant well-developed surface circulation contributed toward temporal maxima in the accumulation rates of Cu, Zn, Ni, and Al in sediments of those ages. Authigenic material is also important only where bulk-sediment accumulation rates are low. Ni, Cu, Zn, and sometimes Mn are associated with this sediment. Fe is almost entirely of hydrothermal origin. Mn is primarily hydrothermal, but some is probably scavenged from sea water by amorphous iron hydroxide floes along with other elements concentrated in hydrothermal sediments, Ni, Cu, and Zn. During the past 50 m.y. all of these elements accumulated over the East Pacific Rise at rates nearly an order of magnitude higher than those at non-rise-crest sites. In addition, factor analysis indicates that some of this material is carried substantial distances to the west of the rise crest. Accumulation rates of Fe in basal metalliferous sediments indicate that the hydrothermal activity that supplied amorphous Fe oxides to the East Pacific Rise areas was most intense during middle Eocene and late Miocene to early Pliocene time.

Carbonat-free sediment components of ODP Leg 115 holes

From the equatorial Indian Ocean, carbonate-free portions of sediment samples of Paleocene to Miocene calcareous oozes and chalks from Sites 707, 709, and 711 were studied using X-ray diffraction measurements and the scanning electron microscope. Downhole variations in biogenic opal, quartz, barite, and clinoptilolite were investigated. The abundance patterns of these major mineral phases show several similarities and may be used for additional lithologic correlations. Variations in biogenic opal contents reflect biogenic silica productivity. Beside the general pattern, a succession in biogenic silica decrease through time is generally recorded since the Oligocene. This succession started earliest at northernmost Site 711 and latest at southernmost Site 707, including Site 709 within these two. Opal-A variations as well as the barite distribution may be influenced by the paleoposition of the sites in relation to the high-productivity zone, which today lies south of the equator. Authigenic clinoptilolite apparently formed in two different modes. In deeper sediment intervals, clinoptilolite was the last mineral phase formed associated with enhanced silica diagenesis. In late Oligocene to middle Miocene sediments, clinoptilolite was the only authigenic silica phase encountered where otherwise strong opal dissolution was observed. The sponge spicules showed special dissolution features probably related to microbiological activity. Silica concretions mainly composed of opal-CT and authigenic quartz occur in carbonate-rich environments and are formed during later diagenesis when burial depth causes the sediments to reach higher temperatures. Opal-CT concretions in carbonate-free siliceous oozes were found at Site 711 and are probably formed during an early stage of silica diagenesis.

CaCO3 content, terrigenous components, foraminifera abundance and age of sediment core MD95-2006, Barra Fan, UK

Lithology, lithic petrology, planktonic foraminiferal abundances, and clastic grain sizes have been determined in a 30 m-long core recovered from the Barra Fan off northwest Scotland. The record extends back to around 45 kyr B.P., with sedimentation rates ranging between 50 and 200 cm/kyr. The abundance of ice-rafted debris indicates 16 glacimarine events, including temporal equivalents to Heinrich events 1-4. Enhanced concentrations of basaltic material derived from the British Tertiary Province suggest that the glacimarine sediments record variations in a glacial source on the Hebrides shelf margin. Glacimarine zones are separated by silty intervals with high planktonic foraminifera concentrations that reflect an interstadial circulation regime in the Rockall Trough. The results suggest that the last British Ice Sheet fluctuated with a periodicity of 2000-3000 years, in common with the Dansgaard-Oeschger climate cycle.

Main components and isotopic composition of gases from mineral waters of the Taman Peninsula and Caucasus

Helium isotope composition as an indicator of the mantle-derived component was studied in gases from mineral springs, stratal waters, and mud volcanoes developed west of the Teberda River valley (10 objects) and two springs in the central segment of the Greater Caucasus orogen between the active El'brus and Kazbek volcanoes. In the western segment of the orogen ratios of 3He/4He = R_corr vary from 46x10**-8 to 114x10**-8 (from 0.33 to 0.81 R_atm, where R_atm = 1.4x10**-6 is the atmospheric ratio). They are substantially lower relative to ratios in the vicinity of El'brus and Kazbek and close to those in samples from the central segment (from 70x10**-8 to 134x10**-8 (from 0.50 to 0.96 R_atm), as well as to ratios previously recorded in the Caucasian Mineral Waters (CMW) area. Moreover, concentration of 3He in them is notably higher than its crustal radiogenic level characteristic of mud volcanoes in the Taman Peninsula, where 3He/4He varies from 1.4x10**-8 to 2.8x10**-8 (from 0.01 to 0.02 R_atm). Nitrogen-methane gas from northern piedmonts of the western Caucasus also contains nonatmogenic components including radiogenic 40Ar (40Ar/36Ar = 900), excessive nitrogen (~87% of total N2 concentration in sample) and mantle He. These data specify distribution of mantle derivates along the orogen strike and age of intrusive magmatic activity in its different segments.

Biogenic and terrigeneous components in Pliocene-Pleistocene sediments of the equatorial Atlantic

High-resolution analyses of sediments at equatorial Atlantic Sites 662, 663, and 664 define the accumulation rates of biogenically produced CaC03 and opal and of eolian dust from North Africa over the last 3.7 m.y. The mean flux of opal increased abruptly by 60%-70% near 2.5 Ma (2.65 to 2.3 Ma), reflecting pulses of increased opal productivity along the equator due mainly to increased upwelling. The mean winter-plume dust influx from Sahelian and Saharan Africa also increased at this time by between 35% and 75%, following smaller increases earlier in the late Pliocene. The increased opal flux implies a stronger zonal component of the southern trade winds in Southern Hemisphere winter. Consistent with this wind configuration, the stronger dust flux suggests a weaker southwesterly monsoonal flow into Africa in Northern Hemisphere summer, thus increasing Sahelian aridity and winter-plume dust fluxes. Dust fluxes to the equator may possibly have also been enhanced by stronger Northern Hemisphere winter trade winds and a more southerly position of the Intertropical Convergence Zone over Africa. These late Pliocene biogenic and terrigenous flux changes coincided with the appearance of Northern Hemisphere ice sheets, implying an ultimate causal link. The immediate control on changes in tropical circulation may, however, have been changes in the Atlantic sector of the Southern Ocean. A steady background trend of increasing winter-plume dust flux occurred from the late Pliocene until the middle Pleistocene. This may reflect a progressive, tectonically induced aridification of northern and eastern Africa because of the gradual uplift of the Tibetan Plateau.