(Table 22-30) Revised composite depth scales of IODP Sites 320-U1331, U1332, U1333, U1334 and ODP Sites 199-1218, 199-1219, 199-1220

Integrated Ocean Drilling Program (IODP) Expedition 320 recovered high-quality paleomagnetic records with over 800 dated reversals and decimeter-scale cyclic sediments which provide an outstanding framework to inter-calibrate major fossil groups and refine magnetic polarity chrons for the early Miocene, the entire Oligocene and the late Eocene Epoch. In order to reconstruct the climate history of the Equatorial Pacific one of the major objectives of the Pacific Equatorial Age Transect (PEAT) is the compilation of a Cenozoic Megasplice which integrates all available bio-, chemo-, and magnetostratigraphic data including key records from Ocean Drilling Program (ODP) Leg 199. Here we present extended post-cruise refinements of the shipboard composite depth scales and composite records of IODP Expedition 320 Sites U1331, U1332, U1333, U1334 as well as ODP Leg 199 Sites 1218, 1219 and 1220. The revised composite records were used to perform a site-to-site correlation and integration of Leg 199 and Exp. 320 sites. Based on this decimeter scale correlation a high resolution integrated paleomagnetic and biostratigraphic framework for the Equatorial Pacific is established covering the time from 20 to 40 Ma. This unprecedented sedimentary compendium from the Equatorial Pacific will be the backbone for paleoceanographic reconstructions for the late Paleogene.

Stratigraphic correlation of ODP Site 199-1218 and 199-1219

During Ocean Drilling Program Leg 199 a high-resolution (~1-2 cm/k.y.) biogenic sediment record from the late Paleocene to the early Miocene was recovered, containing an uninterrupted set of geomagnetic chrons as well as a detailed record of calcareous and siliceous biostratigraphic datum events. Shipboard lithologic proxy measurements and shore-based determinations of CaCO3 revealed regular cycles that can be attributed to climatic forcing. Discovering drill sites with well defined magneto- and biostratigraphic records that also show clear lithologic cycles is rare and valuable and creates the opportunity to develop a detailed stratigraphic intersite correlation, providing the basis to study paleoceanographic processes and mass accumulation rates at high resolution. Here we present extensive postcruise work that extends the shipboard composite depth stratigraphy by providing a high-resolution revised meters composite depth (rmcd) scale to compensate for depth distortion within individual cores. The depth-aligned data were then used to generate stacked records of lithologic proxy measurements. Making use of the increased signal-to-noise ratio in the stacked records, we then proceeded to generate a detailed site-to-site correlation between Sites 1218 and 1219 in order to decrease the depth uncertainty for magneto- and biostratigraphic datums. Stacked lithologic proxy records in combination with discrete measurements of CaCO3 were then exploited to calculate high-resolution carbonate concentration curves by regression of the multisensor track data with discrete measurements. By matching correlative features between the cores and wireline logging data, we also rescaled our core rmcd back to in situ depths. Our study identifies lithology-dependent core expansion due to unloading as the mechanism of varying stratigraphic thicknesses between cores.

Benthic foraminifera stratigraphy of sediments from ODP Leg 199 sites

Benthic foraminifers from Ocean Drilling Program Leg 199 Holes 1215A, 1220B, and 1221C were examined across the Paleocene/Eocene boundary. Assemblages were studied in 240 samples. The benthic foraminiferal extinction event that correlates with the Paleocene/Eocene epoch boundary was recognized at these sites. Benthic assemblages before the event are characterized by high diversity, but those after the event are low in diversity. An assemblage of agglutinated foraminifers without carbonate cement was recognized at Sites 1220 and 1221. These assemblages were typically found after the event. The discovery of such agglutinated assemblages has never been reported before at this boundary.

Radiolarian biostratigraphy and chronology of radiolarian events of ODP Leg 199 sites and EW9709 sediment cores

A generally rich radiolarian fauna ranging in age from Quaternary to early Eocene (Zone RP7) was found at five of the eight sites drilled during Ocean Drilling Program (ODP) Leg 199. Of particular interest are the stratigraphically complete assemblages that range in age from middle Miocene (Zone RN5) to early Eocene (Zone RP7), composites of Sites 1218, 1219, and 1220. At the same sites, multisensor track (MST) data show consistent cycles in gamma ray attenuation density, color, and carbonate content that can be correlated on a submeter scale from the early Miocene to early Eocene. In addition, the magnetic reversal records from these three sites allow construction of an absolute timescale. A series of 305 radiolarian morphologic first and last occurrences and evolutionary transitions for radiolarians were determined and correlated directly with the accompanying MST and paleomagnetic data, resulting in a detailed and accurate dating of events. Since many of the bioevents are found at more than one site, it was also possible to test their reliability within the study area. Twelve new species are described: Calocycletta (Calocycletta) anekathen, Dorcadospyris anastasis, Dorcadospyris copelata, Dorcadospyris cyclacantha, Dorcadospyris ombros, Dorcadospyris scambos, Eucyrtidium mitodes, Theocyrtis careotuberosa, Theocyrtis perpumila, Theocyrtis perysinos, Theocyrtis setanios, and Thyrsocyrtis (Pentalacorys) orthotenes.

Phosphorus components and barite in untreated and in carbonate-free sediments of ODP Hole 199-1221C

We determined changes in equatorial Pacific phosphorus (µmol P/g) and barite (BaSO4; wt%) concentrations at high resolution (2 cm) across the Paleocene/Eocene (P/E) boundary in sediments from Ocean Drilling Program (ODP) Leg 199 Site 1221 (153.40 to 154.80 meters below seafloor [mbsf]). Oxide-associated, authigenic, and organic P sequentially extracted from bulk sediment were used to distinguish reactive P from detrital P. We separated barite from bulk sediment and compared its morphology with that of modern unaltered biogenic barite to check for diagenesis. On a CaCO3-free basis, reactive P concentrations are relatively constant and high (323 µmol P/g or ~1 wt%). Barite concentrations range from 0.05 to 5.6 wt%, calculated on a CaCO3-free basis, and show significant variability over this time interval. Shipboard measurements of P and Ba in bulk sediments are systematically lower (by ~25%) than shore-based concentrations and likely indicate problems with shipboard standard calibrations. The presence of Mn oxides and the size, crystal morphology, and sulfur isotopes of barite imply deposition in sulfate-rich pore fluids. Relatively constant reactive P, organic C, and biogenic silica concentrations calculated on a CaCO3-free basis indicate generally little variation in organic C, reactive P, and biogenic opal burial across the P/E boundary, whereas variable barite concentrations indicate significant changes in export productivity. Low barite Ba/reactive P ratios before and immediately after the Benthic Extinction Event (BEE) may indicate efficient nutrient burial, and, if nutrient burial and organic C burial are linked, high relative organic C burial that could temporarily drawdown CO2 at this site. This interpretation requires postdepositional oxidation of organic C because organic C to reactive P ratios are low throughout the section. After the BEE, higher barite Ba/reactive P ratios combined with higher barite Ba concentrations may imply that higher export productivity was coupled with unchanged reactive P burial, indicating efficient nutrient and possibly also organic C recycling in the water column. If the nutrient recycling is decoupled from organic C, the high export production could be indicative of drawdown of CO2. However, the observation that organic C burial is not high where barite burial is high may imply that either C sequestration was restricted to the deep ocean and thus occurred only on timescales of the deep ocean mixing or that postdepositional oxidation (burn down) of organic matter affected the sediments. The decoupling of barite and opal may result from low opal preservation or production that is not diatom based.

Chemical composition of bulk sediments from ODP Hole 199-1221C

A record of inorganic geochemical variability was produced from a contiguous sequence of 35 samples, with 1 cm spacing, recovered from Hole 1221C. This record covers from 153.91 to 154.27 meters below seafloor and spans the Carbon Isotope Excursion (CIE) associated with the Paleocene/Eocene boundary interval. Elemental concentrations were determined for Al, As, Ba, Ca, Fe, K, Mg, Mn, P, Si, Sr, Ti, Cd, Co, Cr, Cu, Hf, Mo, Nb, Ni, Pb, Pt, Re, Sc, V, Y, Zn, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Most concentration profiles exhibit a marked peak coincident with or just prior to the CIE. In addition, the rare earth element pattern exhibits a significant flattening of the typical, prominent negative Ce anomaly across the same interval.