Analysis of organic matter from DSDP Leg 81 Holes

Organic geochemical and visual kerogen analyses were carried out on approximately 50 samples from Leg 81 (Rockall Plateau, North Atlantic). The sediments are from four sites (Sites 552-555), Pleistocene to Paleocene in age, and represent significantly different depositional environments and sources of organic matter. The Pleistocene glacial-interglacial cycles show differences in sedimentary organic matter based on Rock-Eval pyrolysis, organic phosphorus, and pyrolysis/mass-spectrometry analyses. Glacial samples contain more organic carbon, with a larger proportion of reworked organic matter. This probably reflects increased erosion of continental and shelf areas as a result of low sea level stands. Inter glacial samples contain a larger proportion of marine organic matter as determined by organic phosphorus and pyrolysis analyses. This immature, highly oxidized marine organic matter may be associated with the skeletal organic matrix of calcareous organisms. In addition, Rock-Eval data indicate no significant inorganic-carbonate contribution to the S3 pyrolysis peak. The Pliocene-Miocene sediments consist of pelagic, biogenic carbonates. The organic matter is similar to that of the Pleistocene interglacial periods; a mixture of oxidized marine organic matter and reworked, terrestrial detritus. The Paleocene-Oligocene organic matter reflects variations in source and depositional factors associated with the isolation of Rockall from Greenland. Paleocene sediments contain primarily terrestrial organic matter with evidence of in situ thermal stress resulting from interbedded lava flows. Late Paleocene and early Eocene organic matter suggests a highly oxidized marine environment, with major periods of deposition of terrestrially derived organic matter. These fluctuations in organic-matter type are probably the result of episodic shallowing and deepening of Rockall Basins. The final stage of Eocene/Oligocene sedimentation records the accelerating subsidence of Rockall and its isolation from terrestrial sources (Rockall and Greenland). This is shown by the increasingly marine character of the organic matter. The petroleum potential of sediments containing more than 0.5% organic carbon is poor because of their thermal immaturity and their highly oxidized and terrestrial organic-matter composition.

Miocene to Pleistocene sedimentation at ODP Site 133-823

More than 2000 turbidite, debris-flow, and slump deposits recovered at Site 823 record the history of the Queensland Trough since the middle Miocene and provide new insights about turbidites, debris flow, and slump deposits (herein termed gravity deposits). Changes in the composition and nature of gravity deposits through time can be related to tectonic movements, fluctuations in eustatic sea level, and sedimentological factors. The Queensland Trough is a long, relatively narrow, structural depression that formed as a result of Cretaceous to Tertiary rifting of the northeastern Australia continental margin. Thus, tectonics established the geometry of this marginal basin, and its steep slopes set the stage for repeated slope failures. Seismic data indicate that renewed faulting, subsidence, and associated tectonic tilting occurred during the early late Miocene (continuing into the early Pliocene), resulting in unstable slopes that were prone to slope failures and to generation of gravity deposits. Tectonic subsidence, together with a second-order eustatic highstand, resulted in platform drowning during the late Miocene. The composition of turbidites reflects their origin and provides insights about the nature of sedimentation on adjacent shelf areas. During relative highstands and times of platform drowning, planktonic foraminifers were reworked from slopes and/or drowned shelves and were redeposited in turbidites. During relative lowstands, quartz and other terrigenous sediment was shed into the basin. Quartzose turbidites and clay-rich hemipelagic muds also can record increased supply of terrigenous sediment from mainland Australia. Limestone fragments were eroded from carbonate platforms until the drowned platforms were buried under hemipelagic sediments following the late Miocene drowning event. Bioclastic grains and neritic foraminifers were reworked from neritic shelves during relative lowstands. During the late Pliocene (2.6 Ma), the increased abundance of bioclasts and quartz in turbidites signaled the shallowing and rejuvenation of the northeastern Australia continental shelf. However, a one-for-one relationship cannot be recognized between eustatic sea-level fluctuations and any single sedimentologic parameter. Perhaps, tectonism and sedimentological factors along the Queensland Trough played an equally important role in generating gravity deposits. Turbidites and other gravity deposits (such as those at Site 823) do not necessarily represent submarine fan deposits, particularly if they are composed of hemipelagic sediments reworked from drowned platforms and slopes. When shelves are drowned and terrigenous sediment is not directly supplied by nearby rivers/point sources, muddy terrigenous sediments blanket the entire slope and basin, rather than forming localized fans. Slope failures affect the entire slope, rather than localized submarine canyons. Slopes may become destabilized as a result of tectonic activity, inherent sediment weaknesses, and/or during relative sea-level lowstands. For this reason, sediment deposits in this setting reflect tectonic and eustatic events that caused slope instabilities, rather than migration of different submarine fan facies.