Chemical composition of phosphorites, Fe-Mn nodules and crusts, and basalts from the West Pacific

The monograph gives the first systematic description of ore-bearing guyots from the West Pacific. It is mostly based on data obtained in numerous expeditions of Russian vessels during 1984-1992. Ore deposits located on upper parts of all slopes and tops of the guyots include phosphorites associated with cobalt- and platinum-rich ferromanganese crusts. Location, origin and prospecting of mineral deposits are discussed on the base of new data on metallogenic factors (geodynamics, tectonics, magmatism, sedimentation and morphostructures).

Detailed description, geochemistry and radioactivity of manganese nodules taken during the R/V Vityaz cruise to the Indian Ocean

During the 33th voyage of the R/V "Vityaz" in the Indian Ocean iron-manganese nodules were collected at several stations. Both nodules and associated sediments were analysed by spectral analysis over 30 chemical elements. Radioactivity measurements were also performed on these samples.

Geochemistry of Pliocene-Pleistocene volcanic rocks from the Izu Arc

The igneous geochemistry of lavas and breccias from the basement of Sites 790 and 791, and pumice clasts from the Pliocene-Pleistocene sedimentary section of Sites 788, 790, 791, and 793 were studied. Arc volcanism became silicic about 1.5 m.y. before the inception of rifting in the Sumisu Rift at 2 Ma, but eruption of these silicic magmas reflects changes in stress regime, especially during the last 130,000 yr, rather than crustal anatexis. Arc magmas have had a larger proportion of slab-derived components since the inception of rifting than before, but are otherwise similar. Rift basalts and rhyolites are derived from a different source than are arc andesites to rhyolites. The rift source has less slab-derived material and is an E-MORB-like source, in contrast to an N-MORB-type source overprinted with more slab-derived material beneath the arc. Rift magma types, in the form of rare pumice and lithic clasts, preceded the rift, and the earliest magmas that erupted in the rift already differed from those of the arc. The earliest large rift eruption produced an exotic explosion breccia ("mousse") despite eruption at >1800 mbsl. Although this rock type is attributed primarily to high magmatic water content, the clasts are more MORB-like in trace element and isotopic composition than are modern Mariana Trough basalts. After rifting began, arc volcanism continued to be predominantly silicic, with individual pumice deposits containing clasts that vary in composition by about 5 wt% SiO2, or about as much as in historical eruptions of submarine Izu Arc volcanoes. The overall variations in magma composition with time during the inception of arc rifting are broadly similar in the Sumisu Rift and Lau Basin, though newly tapped OIB-type mantle seems to be present earlier during basin formation in the Sumisu than Lau case.

Paleomagnetic of Cretaceous basalts from ODP Hole 129-802A

Cretaceous basalts have been recovered at several Ocean Drilling Program and Deep Sea Drilling Project sites where basement of Jurassic age was predicted. Sites 800 and 802, Leg 129, both fall in this category. We have examined the paleomagnetic properties of 25 basalt samples from Site 802 in order to establish a paleolatitude for the site at the time of basalt emplacement and to compare the results to those from Deep Sea Drilling Project Site 462. Mean natural remanent magnetization intensity for the Site 802 basalts was found to be approximately 12 A/m consistent with typical oceanic basalts. Mean stable inclination is -34.7° ± 2.2 which implies a paleolatitude of approximately 19.4°S. This is very similar to the paleolatitudes calculated for Site 462 basalts and suggests - along with similarities in geochemistry, magnetic properties, and projected age of Site 802 basalt emplacement - both contemporaneity of and a possible source link between the two sites.

Geochemistry of sediments in the central equatorial Pacific Ocean

In order to quantify changes in export production and carbonate dissolution over the past 1 Myr in the central equatorial Pacific Ocean we analyzed Ba, P, Al Ti, and Ca in 1106 samples from five piston cores gathered from 5°S to 4°N at 140°W. We focused on Ba/Ti, Al/Ti, and P/Ti ratios as export proxies and employed areally integrated time slice as well as time series strategies. Carbonate maxima from 0-560 kyr are characterized by 15-30% greater export than carbonate minima. The increases in export fall on glacial delta18O transitions rather than glacial maxima. From 560-800 kyr, overlapping with the mid-Pleistocene transition, there is a very large increase in total export yet no glacial-interglacial variability. The highest latitudes (5°S and 4°N) record minimal absolute export change from glacials to interglacials and yet record the most extreme minima in percent CaCO3, indicating that carbonate records there are dominated by dissolution, whereas near the equator they are more influenced by changes in export.

Isotopic composition of Manihiki and Ontong Java basalts

Pb, Nd, and Sr isotopic results for lavas of the Cretaceous Ontong Java and Manihiki oceanic plateaus fall well within the modern-day oceanic island or hot pot field. The data provide no evidence of old continental basements but indicate a major involvement of 'Kerguelen-type' or 'EM-I'-like mantle in the sources of both plateaus, which appear to have probably been formed, at least in part, by hotspots. However, the presently active hotspots that Pacific plate reconstructions suggest might have been possible plateau sources lack Kerguelen-type isotopic compositions. Either these hotspots did not participate in the formation of the two plateaus, or if they did, Kerguelen-type material must have been volumetrically much more important early in their existence. Two hypotheses for the origins of these plateaus which involve hotspot sources are consistent with the sparse available geochemical, geochronological and geophysical data. The first holds that the plateaus formed cataclysmically in association with surfacing plume heads; the second posits a relatively steady but robust hotspot at or near a ridge crest and requires a much longer period of formation. A near-ridge origin appears to be indicated by evidence that most of the Pacific plateaus were built largely on relatively young ocean crust. However, we suggest that a near-ridge origin is also compatible with the plume head concept in that plume heads appear very likely to become associated with spreading axes through their influence on rift propagation, which should be substantially greater than for ordinary hotspots. In either case, the lack of hotspot tracks (seamount chains) attached to the two plateaus would be a consequence of ridge migration or rift propagation in a near-ridge setting.

K-Ar ages of basalts from islands of the Franz Josef Land archipelago

New K-Ar age determinations of basalt samples from three drill holes and outcrops on the Franz Josef Land suggest that flood volcanism throughout the archipelago fits in a very narrow age interval (116±5 Ma). For 95% of the samples we studied, age scatter is within analytical uncertainty. New data on basaltic bulk-rock, trace element, and REE compositions point to mantle plume affinity for Early Cretaceous magmatism on the Franz Josef Land, which preceded the onset of seafloor spreading in the Canada Basin.