(Table 3) Noble gas composition of dissociated gas hydrate specimens from ODP Leg 164 sites

Fractionation of the noble gases should occur during formation of a Structure I gas hydrate from water and CH4 such that CH4 hydrate is greatly enriched in Xenon. Noble gas concentrations and fractionation factors (F[4He], F[22Ne], F[86Kr], and F[132Xe] as well as R/Ra) were determined for eight gas hydrate specimens collected on Leg 164 to evaluate this theoretical possibility and to assess whether sufficient quantities of Xe are hosted in oceanic CH4 hydrate to account for Xe "missing" from the atmosphere. The simplest explanation for our results is that samples contain mixtures of air and two end-member gases. One of the end-member gases is depleted in Ne, but significantly enriched in Kr and Xe, as anticipated if the source of this gas involves fractionation during Structure I gas hydrate formation. However, although oceanic CH4 hydrate may be greatly enriched in Xe, simple mass balance calculations indicate that oceanic CH4 hydrate probably represents only a minor reservoir of terrestrial Xe. Noble gas analyses may play an important role in understanding the dynamics of gas hydrate reservoirs, but significantly more work is needed than presented here.

Geological map of Heimefrontfjella, Dronning Maud Land, Antarctica (Scale 1:250,000)

The geological overview map was compiled from 15 geological maps (1 : 25,000) and is based on Jacobs et al. 1996. The topographic basemaps were adapted from unpublished 1:250,000 provisional topographic maps, Institut f. Angewandte Geodäsie, Frankfurt, 1983. Part of the contour lines are from Radarsat (Liu et al. 2001).

(Fig 1, page 350) A manganese nodule in the top part of the CHUBASCO station 17 core taken in the Pacific Ocean

The vast extent of pelagic deposits, covering about 70 per cent of the ocean floor, thus about half of the earth, makes them of obvious importance to all Earth Science. All the pelagic (eupelagic) sediments, whether largely of plankton remains or fine inorganic particles, have certain distinctive characteristics to reflect their environment of accumulation. The great segregation of manganese in pelagic sediments presents many problems. It is hypothesized that in the formation of present day nodules a relatively slow accumulation in order to permit deposition of more of the manganese as large nodules, rather than as the disseminated micronodules that are in larger proportion in the Tertiary.

Oceanography and stable isotopes on planktonic foraminifera from the North Atlantic

With the examination of multinet catches (63 µm mesh size), the present study analyzes the distribution of planktonic foraminifera in Polar regions: the Labrador Sea, Greenland Sea at 75°N and Fram Strait at 80°N. The community of the planktonic foraminifera, which in the study area mainly consists of six species: left and right-coiling N. pachyderma, T. quinqueloba, G. bulloides, G. glutinata and G. uvula, is primarily controlled by the temperature in the different water masses. Besides hydrographic parameters, the changes in the horizontal and vertical distribution of N. pachyderma (s.) and T. quinqueloba as well as their shell size distribution in the study area are primarily influenced by the synchrone reproduction, which is coupled to the lunar cycle. Detailed examinations of the isotope signal in dependency on the shell size and weight for N. pachyderma (s.) and T. quinqueloba from plankton tows, indicated the weight or degree of calcification to not be the primary factor controlling the isotope signal of encrusted specimens.The d18O vital effect is primarily caused by the thermal stratification of the water column, whereas the d13C vital effect mainly results from the ontogenetic development.

Atlantic 231Pa/230Th and biogenic opal compilation of the Holocene and the LGM

The strength and geometry of the Atlantic meridional overturning circulation is tightly coupled to climate on glacial-interglacial and millennial timescales, but has proved difficult to reconstruct, particularly for the Last Glacial Maximum. Today, the return flow from the northern North Atlantic to lower latitudes associated with the Atlantic meridional overturning circulation reaches down to approximately 4,000 m. In contrast, during the Last Glacial Maximum this return flow is thought to have occurred primarily at shallower depths. Measurements of sedimentary 231Pa/230Th have been used to reconstruct the strength of circulation in the North Atlantic Ocean, but the effects of biogenic silica on 231Pa/230Th-based estimates remain controversial. Here we use measurements of 231Pa/230Th ratios and biogenic silica in Holocene-aged Atlantic sediments and simulations with a two-dimensional scavenging model to demonstrate that the geometry and strength of the Atlantic meridional overturning circulation are the primary controls of 231Pa/230Th ratios in modern Atlantic sediments. For the glacial maximum, a simulation of Atlantic overturning with a shallow, but vigorous circulation and bulk water transport at around 2,000 m depth best matched observed glacial Atlantic 231Pa/230Th values. We estimate that the transport of intermediate water during the Last Glacial Maximum was at least as strong as deep water transport today.