Distribution of clay minerals in surface sediments of the Eurasian Arctic Ocean

Clay-mineral distributions in the Arctic Ocean and the adjacent Eurasian shelf areas are discussed to identify source areas and transport pathways of terrigenous material in the Arctic Ocean. The main clay minerals in Eurasian Arctic Ocean sediments are illite and chlorite. Smectite and kaolinite occur in minor amounts in these sediments, but show strong variations in the shelf areas. These two minerals are therefore reliable in reconstructions of source areas of sediments from the Eurasian Arctic. The Kara Sea and the western part of the Laptev Sea are enriched in smectite, with highest values of up to 70% in the deltas of the Ob and Yenisey rivers. Illite is the dominant clay mineral in all the investigated sediments except for parts of the Kara Sea. The highest concentrations with more than 70% illite occur in the East Siberian Sea and around Svalbard. Chlorite represents the clay mineral with lowest concentration changes in the Eastern Arctic, ranging between 10 and 25%. The main source areas for kaolinite in the Eurasian Arctic are Mesozoic sedimentary rocks on Franz-Josef Land islands. Based on clay-mineral data, transport of the clay fraction via sea ice is of minor importance for the modern sedimentary budget in the Arctic basins.

Sea surface temperature reconstructions of sediment cores from the Atlantic sector of the Southern Ocean

Late Quaternary summer sea surface temperatures (SSTs) have been derived from radiolarian assemblages in the East Atlantic sector of the Southern Ocean. In the subantarctic and the polar frontal zone, glacial SSTs (oxygen isotope stages 2, 4, 6, and 8) were 3°-5°C cooler than today, indicating northward displacements of the isotherms about 2°-4° of latitudes. During interglacials, SSTs almost reached modern levels (oxygen isotope stages 7 and 9) or exceeded them by 2°-3°C (oxygen isotope stages 1 and 5.5). In the subantarctic Atlantic Ocean, changes in SST and calcium carbonate content of the sediment precede variations in global ice volume in the range of the main Milankovitch frequencies. Comparisons with the timing of North Atlantic Deep Water (NADW) proxy records suggests that this early response in the subantarctic Atlantic Ocean is not triggered by the flux of NADW to the Southern Ocean.

Data and Code archive for the interpolation of surface ocean carbon dioxide

We have developed a statistical gap-filling method adapted to the specific coverage and properties of observed fugacity of surface ocean CO2 (fCO2). We have used this method to interpolate the Surface Ocean CO2 Atlas (SOCAT) v2 database on a 2.5°×2.5° global grid (south of 70°N) for 1985-2011 at monthly resolution. The method combines a spatial interpolation based on a 'radius of influence' to determine nearby similar fCO2 values with temporal harmonic and cubic spline curve-fitting, and also fits long term trends and seasonal cycles. Interannual variability is established using deviations of observations from the fitted trends and seasonal cycles. An uncertainty is computed for all interpolated values based on the spatial and temporal range of the interpolation. Tests of the method using model data show that it performs as well as or better than previous regional interpolation methods, but in addition it provides a near-global and interannual coverage.

Geochemistry and sedimentation rates of ODP Leg 199 sites and of surface sediments in the eastern Pacific ocean

We present the first high-resolution organic carbon mass accumulation rate (MAR) data set for the Eocene equatorial Pacific upwelling region, from Sites 1218 and 1219 of the Ocean Drilling Program. A maximum Corg MAR anomaly appears at 41 Ma and corresponds to a high carbonate accumulation event (CAE). Independent evidence suggests that this event (CAE-3) was a time of rapid cooling. Throughout the Eocene, organic carbon burial fluxes were an order of magnitude lower than fluxes recorded for the Holocene. In contrast, the expected organic carbon flux, calculated from the biogenic barium concentrations for these sites, is roughly equal to modern. A sedimentation anomaly appears at 41 Ma, when both the measured and the expected organic carbon MAR increases by a factor of two-three relative to the background Eocene fluxes. The rain of estimated Corg and barium from the euphotic zone to the sediments increased by factors of three and six, respectively. We suggest that the discrepancy between the expected and measured Corg in the sediments is a direct consequence of the increased metabolic rates of all organisms throughout the Eocene oceans and sediments. This hypothesis is supported by recent work in ecology and biochemical kinetics that recognizes the fundamental basis of ecology as following from the laws of thermodynamics. This dependence is now elucidated as the Universal Temperature Dependence (UTD) "law" of metabolism and can be applied to all organisms over their biologically relevant temperature range. The general pattern of organic carbon and barium deposition throughout the Eocene is consistent with the UTD theory. In particular, the anomaly at 41 Ma (CAE-3) is associated with rapid cooling, an event that triggered slower metabolic rates for all organisms, slower recycling of organic carbon in the water and sediment column, and, consequently, higher deposition of organic carbon in the sediments. This "metabolism-based" scenario is consistent with the sedimentation patterns we observe for both Sites 1218 and 1219.

Sea surface temperature calculated from UK37 and UK'37 in the Pacific sector of the Southern Ocean

In spite of the important role played by the Southern Ocean in global climate, the few existing paleoceanographic records in the east Pacific sector do not extend beyond one glacial-interglacial cycle, hindering circumpolar comparison of past sea surface temperature (SST) evolution in the Southern Ocean. Here we present three alkenone-based Pleistocene SST records from the subantarctic and subtropical Pacific. We use a regional core top calibration data set to constrain the choice of calibrations for paleo SST estimation. Our core top data confirm that the alkenone-based UK37 and UK'37 values correlate linearly with the SST, in a similar fashion as the most commonly used laboratory culture-based calibrations even at low temperatures (down to ~1°C), rendering these calibrations appropriate for application in the subantarctic Pacific. However, these alkenone indices yield diverging temporal trends in the Pleistocene SST records. On the basis of the better agreement with d18O records and other SST records in the subantarctic Southern Ocean, we propose that the UK37 is a better index for SST reconstruction in this region than the more commonly used UK'37 index. The UK37-derived SST records suggest glacial cooling of ~8°C and ~4°C in the subantarctic and subtropical Pacific, respectively. Such extent of subantarctic glacial cooling is comparable to that in other sectors of the Southern Ocean, indicating a uniform circumpolar cooling during the Pleistocene. Furthermore, our SST records also imply massive equatorward migrations of the Antarctic Circumpolar Current (ACC) frontal systems and an enhanced transport of ACC water to lower latitudes during glacials by the Peru-Chile Current.

Global database of surface ocean particulate organic carbon export fluxes diagnosed from the 234Th technique

Through the processes of the biological pump, carbon is exported to the deep ocean in the form of dissolved and particulate organic matter. There are several ways by which downward export fluxes can be estimated. The great attraction of the 234Th technique is that its fundamental operation allows a downward flux rate to be determined from a single water column profile of thorium coupled to an estimate of POC/234Th ratio in sinking matter. We present a database of 723 estimates of organic carbon export from the surface ocean derived from the 234Th technique. Data were collected from tables in papers published between 1985 and 2013 only. We also present sampling dates, publication dates and sampling areas. Most of the open ocean Longhurst provinces are represented by several measurements. However, the Western Pacific, the Atlantic Arctic, South Pacific and the South Indian Ocean are not well represented. There is a variety of integration depths ranging from surface to 220m. Globally the fluxes ranged from -22 to 125 mmol of C/m**2/d. We believe that this database is important for providing new global estimate of the magnitude of the biological carbon pump.

Distribution of Uvigerina proboscidea in Late Neogene sediments of DSDP Hole 22-214 in the northern Indian Ocean (Table 1)

This study attempts to understand the significance of Uvigerina proboscidea in paleoceanographic reconstructions at the northern (tropical) Indian Ocean DSDP Site 214 from the Late Miocene through the Pleistocene. In this interval at this site, U. proboscidea is the most abundant species of the benthic assemblage and shows abrupt frequency changes (about 1-74%). Based on relative percentages of U. proboscidea calibrated with oxygen and carbon isotope record and the sediment accumulation rates, the modern distribution of the species in the Indian Ocean, and other evidence, the peaks of abundance of U. proboscidea are inferred to represent times of high-surface productivity, This productivity is related to intensified trade winds during strong southwest (SW) Indian monsoons, causing widespread upwelling along equatorial divergemce in the Indian Ocean. The sudden increase of U. proboscidea abundance at approximately 8.5-7.5 Ma reflects significant upwelling at the equatorial divergence. This event corresponds to the permanent build-up of West Antarctic ice sheets, and a major increase in SW Indian monsoons related upwelling in the northwestern Indian Ocean. The Chron-6 carbon shift at approximately 6.2 Ma is marked by another peak of abundance, reflecting widespread ocean fertility. The highest abundances of U. proboscidea and highest sediment accumulation rates occur between 5.8 and 5.1 Ma, which coincidies with the greatest development of Antarctic ice sheets and strong southwest monsoons. The higher percentages at 3.2-3.1 Ma, approximately 2.4 Ma, and 1.6 Ma all represent phases of high productivity at the equatorial divergence.

Palynology from surface sediment samples of the Arctic Ocean

Freshwater chlorophycean algae are characteristic organic-walled microfossils in recent coastal and shelf sediments from the Beaufort, Laptev and Kara seas (Arctic Ocean). The persistent occurrence of the chlorophycean algae Pediastrum spp. and Botryococcus cf. braunii in marine palynomorph assemblages is related to the discharge of freshwater and suspended matter from the large Siberian and North American rivers into the Arctic shelf seas. The distribution patterns of these algae in the marine environments reflect the predominant deposition of riverine sediments and organic matter along the salinity gradient from the outer estuaries and prodeltas to the shelf break. Sedimentary processes overprint the primary distribution of these algae. Resuspension of sediments by waves and bottom currents may transport sediments in the bottom nepheloid layer along the submarine channels to the shelf break. Bottom sediments and microfossils may be incorporated into sea ice during freeze-up in autumn and winter leading to an export from the shelves into the deep sea. The presence of these freshwater algae in sea-ice and bottom sediments in the central Arctic Ocean confirm that transport in sea ice is an important process which leads to a redistribution of shallow water microfossils.

Sea surface temperatures and UK37 of three sediment cores from the Arctic Ocean

Sediment proxy data from the Norwegian, Greenland, and Iceland seas (Nordic seas) are presented to evaluate surface water temperature (SST) differences between Holocene and Eemian times and to deduce from these data the particular mode of surface water circulation. Records from planktic foraminiferal assemblages, CaCO3 content, oxygen isotopes of foraminifera, and iceberg-rafted debris form the main basis of interpretation. All results indicate for the Eemian comparatively cooler northern Nordic seas than for the Holocene due to a reduction in the northwardly flow of Atlantic surface water towards Fram Strait and the Arctic Ocean. Therefore, the cold polar water flow from the Arctic Ocean was less influencial in the southwestern Nordic seas during this time. As can be further deduced from the Eemian data, slightly higher Eemian SSTs are interpreted for the western Iceland Sea compared to the Norwegian Sea (ca. south of 70°N). This Eemian situation is in contrast to the Holocene when the main mass of warmest Atlantic surface water flows along the Norwegian continental margin northwards and into the Arctic Ocean. Thus, a moderate northwardly decrease in SST is observed in the eastern Nordic seas for this time, causing a meridional transfer in ocean heat. Due to this distribution in SSTs the Holocene is dominated by a meridional circulation pattern. The interpretation of the Eemian data imply a dominantly zonal surface water circulation with a steep meridional gradient in SSTs.

Sea surface temperature reconstruction for the Southwest Pacific Ocean

Paleoceanographic archives derived from 17 marine sediment cores reconstruct the response of the Southwest Pacific Ocean to the peak interglacial, Marine Isotope Stage (MIS) 5e (ca. 125?ka). Paleo-Sea Surface Temperature (SST) estimates were obtained from the Random Forest model-an ensemble decision tree tool-applied to core-top planktonic foraminiferal faunas calibrated to modern SSTs. The reconstructed geographic pattern of the SST anomaly (maximum SST between 120 and 132?ka minus mean modern SST) seems to indicate how MIS 5e conditions were generally warmer in the Southwest Pacific, especially in the western Tasman Sea where a strengthened East Australian Current (EAC) likely extended subtropical influence to ca. 45°S off Tasmania. In contrast, the eastern Tasman Sea may have had a modest cooling except around 45°S. The observed pattern resembles that developing under the present warming trend in the region. An increase in wind stress curl over the modern South Pacific is hypothesized to have spun-up the South Pacific Subtropical Gyre, with concurrent increase in subtropical flow in the western boundary currents that include the EAC. However, warmer temperatures along the Subtropical Front and Campbell Plateau to the south suggest that the relative influence of the boundary inflows to eastern New Zealand may have differed in MIS 5e, and these currents may have followed different paths compared to today.