Petrography and mineral compositions of gabbros at DSDP Leg 60 Holes

The compositions, mineralogies, and textures of gabbros recovered in polymict breccias in Hole 453 indicate that they are the cumulus assemblages of calc-alkalic crystal fractional on that occurred beneath the West Mariana Ridge. They are among a class of gabbros known only from other calc-alkalic associations (e.g., the Lesser Antilles and the Peninsular Ranges batholith of Southern California) and differ from gabbros of stratiform complexes, ophiolites, and the ocean crust. Particularly abundant in the Hole 453 breccias are olivine-bearing gabbros with extremely calcic Plagioclase (An94-97) but with fairly iron-rich olivines (Fo76-77). Other gabbros contain biotite and amphibole and occur in breccias with fairly high-grade greenschist facies (amphibole-chlorite-stilpnomelane) metabasalts. One unusual gabbro has experienced almost complete subsolidus recrystallization to an assemblage of aluminous magnesio-hornblende, anorthite, and green hercynitic spinel. This reaction, the extremely calcic Plagioclase, the occurrence of biotite and amphibole, and the association with greenschist facies metamorphic rocks suggest that crystallization of the gabbros occurred at elevated P(H2O). Comparisons with other calc-alkalic gabbro suites suggest pressures in excess of 4 kbar (about 12 km depth). The gabbros were exposed by the early stages of opening of the Mariana Trough and imply that considerable uplift may have attended rifting. They were also subjected to hydrothermal alteration after breccia formation, resulting in formation of chlorite, epidote, actinolite, and prehnite. Temperatures of at least 200°C - and probably 350°C - were reached, and most likely could not have been attained without extrusion or intrusion of magmas nearby, even though no such rocks were cored.

X-ray fluorescence scanning of discrete samples on the Schwalbenberg II loess-paleosol sequence, raw data, magnetic susceptibility, organic carbon and U-ratio as grainsize index

The Schwalbenberg II loess-paleosol sequence (LPS) denotes a key site for Marine Isotope Stage (MIS 3) in Western Europe owing to eight succeeding cambisols, which primarily constitute the Ahrgau Subformation. Therefore, this LPS qualifies as a test candidate for the potential of temporal high-resolution geochemical data obtained X-ray fluorescence (XRF) scanning of discrete samplesproviding a fast and non-destructive tool for determining the element composition. The geochemical data is first contextualized to existing proxy data such as magnetic susceptibility (MS) and organic carbon (Corg) and then aggregated to element log ratios characteristic for weathering intensity [LOG (Ca/Sr), LOG (Rb/Sr), LOG (Ba/Sr), LOG (Rb/K)] and dust provenance [LOG (Ti/Zr), LOG (Ti/Al), LOG (Si/Al)]. Generally, an interpretation of rock magnetic particles is challenged in western Europe, where not only magnetic enhancement but also depletion plays a role. Our data indicates leaching and top-soil erosion induced MS depletion at the Schwalbenberg II LPS. Besides weathering, LOG (Ca/Sr) is susceptible for secondary calcification. Thus, also LOG (Rb/Sr) and LOG (Ba/Sr) are shown to be influenced by calcification dynamics. Consequently, LOG (Rb/K) seems to be the most suitable weathering index identifying the Sinzig Soils S1 and S2 as the most pronounced paleosols for this site. Sinzig Soil S3 is enclosed by gelic gleysols and in contrast to S1 and S2 only initially weathered pointing to colder climate conditions. Also the Remagen Soils are characterized by subtle to moderate positive excursions in the weathering indices. Comparing the Schwalbenberg II LPS with the nearby Eifel Lake Sediment Archive (ELSA) and other more distant German, Austrian and Czech LPS while discussing time and climate as limiting factors for pedogenesis, we suggest that the lithologically determined paleosols are in-situ soil formations. The provenance indices document a Zr-enrichment at the transition from the Ahrgau to the Hesbaye Subformation. This is explained by a conceptual model incorporating multiple sediment recycling and sorting effects in eolian and fluvial domains.

Distribution of Cretaceous redeposited benthic foraminifers at DSDP Site 89-585

Cretaceous benthic foraminifers from Site 585 in the East Mariana Basin, western Pacific Ocean, provide an environmental and tectonic history of the Basin and the surrounding seamounts. Age diagnostic species (from a fauna of 155 benthic species identified) range from late Aptian to Maestrichtian in age. Displaced species in sediments derived from the tops and flanks of nearby seamounts were deposited sporadically on the Basin floor well below the carbonate compensation depth (CCD) at abyssal depths of 5000 to 6000 m. These depths, characterized by an indigenous assemblage of benthic foraminifers, recrystallized radiolarians, fish debris, and sponge spicules, existed in the Mariana Basin from late Aptian to the present. Early Albian and older edifice-building volcanism had reached the photic zone with associated shallow-water bank or reef environments. By middle Albian, the dominant source areas subsided to outer-neritic to upper-bathyal depths. Major volcanic activity ceased and fine-grained sediments were deposited by distal turbidites, although intermittent volcanism and the influx of rare neritic material continued until the late Albian. By the Cenomanian to Turonian, upper- to middle-bathyal depths were reached by the dominant source areas, and the sediments recovered from this interval include organic carbon-rich layers. Rare benthic foraminifers from the Coniacian-Santonian interval indicate a continuation of dominantly middle-bathyal source areas. A change in sedimentation during the Campanian-Maestrichtian from older zeolitic claystone to abundant chert in the Campanian, and nannofossil chalk and claystone in the Maestrichtian resulted from migration of the site beneath the equatorial productive zone due to northwestward plate motion. The appearance of rare middle-neritic and upper-bathyal species in the Maestrichtian interval associated with volcanogenic debris gives evidence of the remobilization and downslope transport of pelagic deposits due to thermally induced uplift. Episodic redeposition of shallow-water material during the Aptian-Albian was produced by edifice-building volcanism perhaps combined with eustatic lowering of sea level. The Cenomanian-Turonian pulse coincided with a low global sea-level stand as does the transported material during the Coniacian-Santonian. The Maestrichtian pulse was caused by renewed midplate volcanism that extended over a large area of the central Pacific.

Quaternary isotope stratigraphy of DSDP Hole 90-593 from the Challenegr Plateau, South Tasman Sea

A moderate-resolution isotope stratigraphy (with an average of one sample per 17,500 yr.) derived from the benthic foraminifer Uvigerina (or Cibicides), the planktonic foraminifer Globigerina bulloides, and calcareous nannofossil concentrates is presented for the entire Quaternary (and latest Pliocene) section of mid-upper bathyal calcareous oozes from DSDP Site 593, western Challenger Plateau, south Tasman Sea. Superimposed on a trend of gradually increasing average delta18O values through the Pleistocene, reflecting the progressive buildup of polar ice sheets, is a record of highfrequency but generally low amplitude (0.5-1?) isotope fluctuations in the early Quaternary (1.9-1.0 m.y.), followed by a greatly increased intensity (1.5-2.0 ?) of glacial-interglacial fluctuations during the late Quaternary (< 1.0 m.y.). The standard late Quaternary isotope stages 1 to 24 are mainly resolvable. Significant excursions in both delta18O and delta13C values at various times during the Quaternary are suggested to be due to periodic, fundamental changes in ocean circulation properties over the plateau. For example, intensified upwelling of Antarctic Intermediate Waters during several glacial periods is indicated by the convergence of benthic and planktonic foraminiferal delta18O data, and productivity variations may account for certain delta13C spikes in the record. With increasingly higher resolution analysis this core will provide a useful Quaternary isotope reference section for southern temperate waters in the southwest Pacific, centered on New Zealand.

Geochemistry of DSDP Leg 65 basalts

Leg 65 of the Deep Sea Drilling Project successfully recovered basalts from four sites in the mouth of the Gulf of California, thus completing a transect begun during Leg 64 from the continental margin of Baja California to the east side of the East Pacific Rise (EPR). Sixty-three whole-rock samples from Sites 482, 483, and 485 have been analyzed by X-ray fluorescence techniques, and a further eleven samples by instrumental neutron-activation techniques, in order to assess magma variability within and between sites. Although the major element compositions and absolute hygromagmatophile (HYG) element abundances are quite variable, all of the basalts are subalkaline tholeiites exhibiting strong more-HYG element (e.g., Rb, La, Nb, Ta) depletion (LaN/YbN ~ 0.4; Nb/Zr ~ 0.02; Ba/Zr ~ 0.23; Th/Hf ~ 0.05). These ratios, together with La/Ta ratios of 20 and Th/Ta ratios of 1.25, demonstrate that the Leg 65 basalts resemble the depleted "N-type" ocean ridge basalts recovered from the Mid-Atlantic Ridge (MAR) at 22 °N and other sections of the EPR. Zr/Ti, Zr/Y, and La/Yb ratios increase with increasing fractionation. It is clear that the basalts recovered from Sites 482, 483, and 485 were all derived from a compositionally similar source and that the compositional differences observed between lithological units can be explained by varying degrees of open system fractional crystallization (magma mixing) in subridge magma chambers. The basaltic rocks recovered from Site 474 near the margin of Baja California, and Sites 477, 478, and 481 in the Guaymas Basin, all drilled during Leg 64, have consistently higher Th/Hf, La/Sm, Zr/Ti, and Zr/Y ratios and higher absolute Sr contents than the Leg 65 basalts. While some of these variations may be explained by different conditions of partial melting, it is considered more likely that the mantle source underlying the Guaymas Basin is chemically distinct from that feeding the EPR at the mouth of the Gulf. These source variations probably reflect the complex tectonic setting of the Gulf of California, the magmas formed at the inception of spreading and in the central part of the Gulf containing a minor but significant component of sub-continental (calc-alkaline) material.

Occurrence and abundance of diatoms at DSDP Holes 72-515B and 72-516F

Samples from the upper Oligocene and lower Miocene of Holes 515B (Brazil Basin) and 516F (Rio Grande Rise) were examined for fossil marine diatom content. The preservation of the diatoms was poor and the species diversity low in both holes. However, it was possible to zone portions of the intervals studied using the zonation proposed by Gombos and Ciesielski (1983), which is based, as far as possible, on common and robust species. Thus, the interval in Hole 515B represented by Cores 515B-15 and 515B-16 is assigned to the Coscinodiscus rhombicus Zone and the interval represented by Cores 515B-17 through 515B-44 is assigned to the Rocella gelida Zone. The C. rhombicus Zone is early Miocene in age and the R. gelida Zone is late Oligocene to early Miocene in age. In Hole 516F the interval represented by Cores 516F-6 through 516F-10 is assigned to the R. gelida Zone Gate Oligocene to early Miocene), and the interval represented by Cores 516F-11 through 516F-15 is assigned to the Triceratium groningensis Zone (late Oligocene). Two new fossil diatom taxa are defined herein: Coscinodiscus lewisianus Greville f. concavus n. f. and Rocella semigelida n. sp.

Mineral chemistry of basalts at DSDP Leg 55 Holes

Microprobe mineral compositions of olivine, plagioclase, clinopyroxene, chrome spinel, ilmenite, and titanomagnetite are presented for 7 samples from 4 flows of hawaiite and one flow of tholeiitic basalt from Hole 430A at Ojin Seamount, 4 samples from 3 flows of alkalic basalt from Hole 432A at Nintoku Seamount, and 29 samples from 2 flows of alkalic basalt and 24 flows of tholeiitic basalt from Holes 433A, 433B, and 433C at Suiko Seamount. The four hawaiite flows from Hole 430A on Ojin Seamount have nearly identical mineralogy. The plagioclase phenocrysts and calculated equilibrium olivine appear to have crystallized at about 1175°C; the groundmass plagioclase crystallized from about 1135° to 1010°C; and the Fe-Ti oxides equilibrated at temperatures from 1000°C to 720°C under oxygen fugacities of 10**-11 to 10**-17. The single tholeiitic flow contains glomerocrysts of plagioclase (An80 to An65) and clinopyroxene (Wo43En46Fsn to Wo42En45Fs13). The plagioclase phenocrysts give calculated temperatures as high as 1400°C, indicating that they were not equilibrated with a magma having the bulk rock composition. The plagioclase groundmass crystallized at 1120° to 1070°C, and the Fe-Ti oxides equilibrated at 1070° to 930°C under oxygen fugacities of 10**-10 to 10**-12. Using mineral compositions of Hawaiian basalts as a guide, we infer that the hawaiite flows were erupted during the post-caldera alkalic eruptive stage and the tholeiite was erupted during the shield-building or caldera collapse stage. The three alkalic basalt flows from Hole 432A on Nintoku Seamount have similar mineralogy, although Flow Units 1 and 2 contain much more abundant plagioclase phenocrysts. The groundmass plagioclase crystallized at temperatures between 1175° and 1000°C. The olivine and plagioclase phenocrysts do not appear to be in equilibrium with the enclosing magmas. The mineral compositions suggest that these samples are intermediate between alkalic basalt and hawaiite; they probably erupted during the post-caldera alkalic stage of eruption. The two analyzed alkalic basalt flows are the two youngest flows recovered at Holes 433A, 433B, and 433C. Flow Unit 1 contains abundant sector-zoned clinopyroxene, and Flow Unit 2 contains rare kink-banded olivine xenocrysts. The plagioclase phenocrysts yield calculated temperatures of 1440° to 1250°C, indicating that they are probably not cognate. Calculated-equilibrium olivine indicates crystallization of olivine at about 1170°C. The Fe-Ti oxides equilibrated at temperatures of 1140° to 870°C under oxygen fugacities of 10**-9 to 10**-14. The groundmass plagioclase crystallized at temperatures of 1178° to 1035 °C. The mineral compositions indicate that these alkalic basalts erupted during the post-caldera alkalic eruptive stage. The 24 analyzed tholeiitic basalts are subdivided on the basis of phenocryst abundances into olivine tholeiites, plagioclase tholeiites, and tholeiites. The crystallization sequence appears to have been chrome spinel, olivine, plagioclase, and clinopyroxene as phenocryst phases, followed by and overlapping with groundmass crystallization of plagioclase (1180° to 920°C), clinopyroxene, and Fe-Ti oxides (1140° to 670°C). At least three flows contain pigeonite. The mineral compositions indicate that all the samples from Flow Unit 4 downward are tholeiitic basalts, although Flow Unit 64 has mineral compositions transitional to those in alkalic basalts.