Chemical composition of celadonite-glauconite minerals and cristobalite from altered oceanic basalts of DSDP Hole 49-407

Features of associations of newly formed minerals in Oligocene basalts from the Reykjanes Ridge (DSDP Hole 407), which consist in wide development of celadonite-glauconite group minerals, as well as saponite, cristobalite and specific Fe-Si formations is shown. Detailed mineralogical and geochemical characteristics of these newly formed minerals are reported. It is firstly shown that at underwater alteration of basalts not only celadonite can be generated, but also glauconite. Dependence of secondary mineral composition from petrochemical features of original basalts and from their permeability is revealed. It is concluded that complexes of secondary minerals formed during alteration of basalts with similar petrochemical characteristics in the ocean and on the continent are different.

Trace elements in benthic foraminifera of sediment core V30-49

Eastern tropical Atlantic benthic foraminiferal Ba/Ca and Cd/Ca data from core V30-949 (3093 m) reveal large inferred changes in nutrient concentrations of deep Atlantic waters during the last 250 kyr. Relative changes in North Atlantic Deep Water contribution to this site are estimated by scaling the V30-49 Cd/Ca record to values of modern end-member water masses; these estimates agree well with the relative structure and timing of circulation changes in the eastern tropical Atlantic reconstructed from a d13C record-based mixing model (Raymo et al., 1997, doi:10.1029/97PA01019). Temporal differences between V30-49 Cd/Ca and Ba/Ca records suggest that the Ba/Ca record reflects changes in circulation with an additional increase in the Ba composition of deep Atlantic water masses during glacial episodes, possibly resulting from increased productivity. Similarity between the d13C and Ba/Ca records suggests that carbon isotopes in the deep glacial Atlantic also reflect productivity increases.