Annotated record of the detailed examination of Mn deposits from VEMA 15 Expedition stations

The cores and dredges described in this report were taken during the VEMA 15 Expedition from October 1958 until July 1959 by the Lamont Geological Observatory, Columbia University from the R/V Vema. A total of 410 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

(Table 8.2, Page 178) Annotated record of the detailed examination of Mn deposits from submarine photographs acquired by the R/V Vityaz in the Pacific Ocean

Prof. H. H. W. Menard has brought together nearly all that was known of the Pacific geology in the early 1960s. His book contains a particular chapter on manganese nodules giving a stimulating review of the features and processes known to govern their distribution and chemical composition.

Observation of ferromanganese deposits in the Baltic Sea

Baltic sediments have been studied by Behrens, Munthe, Küppers, Spethmann, Apstein, Sjöstedt, Pratje and the writer. The following types of sediments have been observed: varved and non-varved late-glacial clays, gray and black, post-glacial muds, and sands. The organic content of late-glacial clays ordinarily is less than 1.3 per cent, and of post-glacial muds more than 3 per cent. Sediments containing intermediate quantities are scarce. This can be explained as a result of the changed balance between organic and inorganic sedimentation when the glacial period ended; the abundance of fresh detritus then suddenly ceased and inorganic sedimentation became very much slower than before; consequently, the relative amount of organic detritus increased. As most of the material was not subjected to biological analysis, it has not been possible to distinguish different ages among post-glacial sediments.

Annotated record of the detailed examination of Mn deposits from RIDA cruise stations

The cores and dredges described at this site were taken on the RIDA cruise from 1 May until 25 May 1984 by the Muséum National d'Histoire Naturelle from the R/V Marion Dufresne. A total of 45 cores and dredges were recovered along with underwater camera runs. They are available at MNHN for sampling and study.

Annotated record of the detailed examination of Mn deposits from the H.M.S. Egeria, H.M.S. Fling Fish and H.M.S. Investigator expeditions in the Indian Ocean and Southern Seas

Captain Wharton, the Hydrographer of the Admiralty sent to the author a series of the deposit-samples collected in the Indian and Antarctic Oceans during the expeditions in 1887 of H.M.S. Flying Fish, H.M.S. Egeria and H.M.S. Investigator. These deposits were submitted to careful microscopical examination and chemical analysis.

Annotated record of the detailed examination of Mn deposits from the TRANSINDIK R/V Valdivia (VA 07) cruise stations

The studied material was taken from Central Indian Ocean central, during the "TRANSINDIK" campaign of the R/V Valdivia. The campaign was conducted from 14 December 1973 until 23 January 1974, between Beira (Mozambique) and Singapore via Port Louis (Mauritius). The samples were taken on 14 stations aligned on a profile trending West, following approximately the 15th parallel (south). This profile cuts through the Mascarene plateau Basin. The preliminary study presented in this report was carried out as part of a study into the genesis and diagenesis the ocean deposits of the central and southern areas of the Indian Ocean (Laboratoire de GÈologie du MusÈum d'Histoire Naturelle - R.C.P. 212) and under the CNEXO No. 74/1017 contract. The data collected supplements the results of the OSIRIS campaign (R/V Marion Dufresne - TAAF) concerning relations existing between morphostructure and sedimentation and, more particularly, the nature and age of metalliferous deposits associated with Mn concretions.

Annotated record of the detailed examination of Mn deposits from the VERMILION SEA Expedition stations

On Vermilion Sea Expedition two research vessels among which the R/V Spencer F. Baird conducted a geological and geophysical exploration of the Gulf of California from February to May, 1959. Support was obtained from the Office of Naval Research and the Bureau of Ships of the U. S. Navy and from a grant of the American Petroleum Institute. Study of the canyons was one feature of the first part of the expedition. Submarine canyon studies were directed by Francis P. Shepard, Professor of Submarine Geology, aboard the research vessel Spencer F. Baird. The expedition found that the narrow channel between Angel de la Guarda Island, toward the head of the Gulf, and the peninsula is scoured almost free of sediments by strong currents. On the other side of Angel de la Guarda Island, between it and the mainland, one of the dredge hauls brought up a manganese nodule. It came from a depth of approximately 1500 feet. This is the shallowest water in which the nodules have been found. Studies have been under way some time on the feasibility of mining such nodules from the sea floor. They contain cobalt, nickel, copper and other valuable metals. (also in, Scripps Institution of Oceanography Vermilion Sea Expedition to the Gulf of California, http://library.ucsd.edu/dc/object/bb34484017)

Iron isotope and chemical compositions of sediments and basalts drilled seaward of the Mariana Trench

The purpose of this work is to study the mobility and budget of Fe isotopes in the oceanic crust and in particular during low-temperature interaction of seawater with oceanic basalt. We carried out this investigation using samples from Ocean Drilling Program (ODP) Site 801C drilled during Leg 129 and Leg 185 in Jurassic Pacific oceanic crust seaward of the Mariana Trench. The site comprises approximately 450 m of sediment overlying a section of 500 m of basalt, which includes intercalated pelagic and chemical sediments in the upper basaltic units and two low-temperature (10-30°C) ocherous Si-Fe hydrothermal deposits. Fe was chemically separated from 70 selected samples, and 57Fe/54Fe ratios were measured by MC-ICP-MS Isoprobe. The isotopic ratios were measured relative to an internal standard solution and are reported relative to the international Fe-standard IRMM-14. Based on duplicate measurements of natural samples, an external precision of 0.2? (2 sigma) has been obtained. The results indicate that the deep-sea sediment section has a restricted range of d57Fe, which is close to the igneous rock value. In contrast, large variations are observed in the basaltic section with positive d57Fe values (up to 2.05?) for highly altered basalts and negative values (down to ?2.49?) for the associated alteration products and hydrothermal deposits. Secondary Fe-minerals, such as Fe-oxyhydroxides or Fe-bearing clays (celadonite and saponite), have highly variable d57Fe values that have been interpreted as resulting from the partial oxidation of Fe(2+) leached during basalt alteration and precipitated as Fe(3+)-rich minerals. In contrast, altered basalts at Site 801C, which are depleted in Fe (up to 80%), display an increase in d57Fe values relative to fresh values, which suggest a preferential leaching of light iron during alteration. The apparent fractionation factor between dissolved Fe(2+) and Fe remaining in the mineral is from 0.5? to 1.3? and may be consistent with a kinetic isotope fractionation where light Fe is stripped from the minerals. Alternatively, the formation of secondary clays minerals, such as celadonite during basalt alteration may incorporate preferentially the heavy Fe isotopes, resulting in the loss of light Fe isotopes in the fluids. Because microbial processes within the oceanic crust are of potential importance in controlling rates of chemical reactions, Fe redox state and Fe-isotope fractionation, we evaluated the possible effect of this deep biosphere on Fe-isotope signatures. The Fe-isotope systematics presented in this study suggest that, even though iron behavior during seafloor weathering may be mediated by microbes, such as iron-oxidizers, d57Fe variations of more than 4? may also be explained by abiotic processes. Further laboratory experiments are now required to distinguish between various processes of Fe-isotope fractionation during seafloor weathering.

Annotated record of the detailed examination of Mn deposits from stations of R.R.S. "Discovery" Cruise 16

The cores and dredges described in this report were taken on Cruise 16 of the R.R.S. "Discovery" from January until May 1967 by the National Institute of Oceanography, Wormley, United Kingdom. A total of 73 cores and dredges were recovered and are available through the British Oceanographic Data Centre for sampling and study.