Core scans and lithologic analysis of Subglacial Lake Whillans sediment cores

The hydrologic system beneath the Antarctic Ice Sheet is thought to influence both the dynamics and distribution of fast flowing ice streams, which discharge most of the ice lost by the ice sheet. Despite considerable interest in understanding this subglacial network and its affect on ice flow, in situ observations from the ice sheet bed are exceedingly rare. Here we describe the first sediment cores recovered from an active subglacial lake. The lake, known as Subglacial Lake Whillans, is part of a broader, dynamic hydrologic network beneath the Whillans Ice Stream in West Antarctica. Even though "floods" pass through the lake, the lake floor shows no evidence of erosion or deposition by flowing water. By inference, these floods must have insufficient energy to erode or transport significant volumes of sediment coarser than silt. Consequently, water flow beneath the region is probably incapable of incising continuous channels into the bed and instead follows preexisting subglacial topography and surface slope. Sediment on the lake floor consists of till deposited during intermittent grounding of the ice stream following flood events. The fabrics within the till are weaker than those thought to develop in thick deforming beds suggesting subglacial sediment fluxes across the ice plain are currently low and unlikely to have a large stabilizing effect on the ice stream's grounding zone.

Magnetostratigraphy of ODP Leg 178 holes

We present revised magnetostratigraphic interpretations for Ocean Drilling Program Sites 1095, 1096, and 1101, cored in sediment drifts located off the Pacific margin of the Antarctic Peninsula. The revised interpretations incorporate a variety of observations and results obtained since the end of Leg 178, of which the most significant are new paleomagnetic measurements from U-channel samples, composite depth scales that allow stratigraphic correlation between multiple holes cored at a site, and revised biostratigraphic interpretations. The U-channel data, which include more than 102,000 paleomagnetic observations from more than 13,400 intervals along U-channel samples, are included as electronic files. The magnetostratigraphic records at all three sites are consistent with sedimentation being continuous over the intervals cored, although the data resolution does not preclude short hiatuses less than a few hundred thousand years in duration. The magnetostratigraphic records start at the termination of Subchron C4Ar.2n (9.580 Ma) at ~515 meters composite depth (mcd) for Site 1095, at the onset of Subchron C3n.2n (4.620 Ma) at ~489.68 mcd for Site 1096, and at the onset of Subchron C2An.1n (3.040 Ma) at 209.38 meters below seafloor for Site 1101. All three sites provide paleomagnetic records that extend upward through the Brunhes Chron.

Chemical and Sr isotopic compositions of 3 step leachates and residues of bulk samples, zeolites, and smectites from Lower Miocene sediments at ODP Site 166-1007

Massive clinoptilolite authigenesis was observed at about 1105 meters below sea floor (mbsf) in lower Miocene wellcompacted carbonate periplatform sediments from the Great Bahama Bank [Ocean Drilling Program, ODP Leg 166, Site 1007]. The diagenetic assemblage comprises abundant zeolite crystallized within foraminifer tests and sedimentary matrix, as well as Mg smectites. In carbonate-rich deposits, the formation of the zeolite requires a supply of silica. Thus, the objective of the study is to determine the origin of the silica supply, its diagenetic evolution, and consequently the related implications on interpretation of the sedimentary record, in terms of local or global paleoceanographic change. For lack of evidence for any volcaniclastic input or traces of Si-enriched deep fluids circulation, an in situ biogenic source of silica is validated by isotopic data and chemical modeling for the formation of such secondary minerals in shallow-water carbonate sequences. Geochemical and strontium isotopic data clearly establish the marine signature of the diagenetic zeolite, as well as its contemporaneous formation with the carbonate deposition (Sr model ages of 19.6-23.2 Ma). The test of saturation for the pore fluids specifies the equilibrium state of the present mineralogical assemblage. Seawater-rock modeling specifies that clinoptilolite precipitates from the dissolution of biogenic silica, which reacts with clay minerals. The amount of silica (opal-A) involved in the reaction has to be significant enough, at least 10 wt.%, to account for the observed content of clinoptilolite occurring at the most zeolite-rich level. Modeling also shows that the observed amount of clinoptilolite (~19%) reflects an in situ and short-term reaction due to the high reactivity of primary biogenic silica (opal-A) until its complete depletion. The episodic occurrence of these well-lithified zeolite-rich levels is consistent with the occurrence of seismic reflectors, particularly the P2 seismic sequence boundary located at 1115 mbsf depth and dated as 23.2 Ma. The age range of most zeolitic sedimentary levels (biostratigraphic ages of 21.5-22 Ma) correlates well with that of the early Miocene glaciation Mi-1 and Mi-1a global events. Thus, the clinoptilolite occurrence in the shallow carbonate platform environment far from volcanogenic supply, or in other sensitive marine areas, is potentially a significant new proxy for paleoproductivity and oceanic global events, such as the Miocene events, which are usually recognized in deep-sea pelagic sediments and high latitude deposits.

Step-heating degassing data for argon-39 from volcanic rocks drilled in the Shikoku Basin and Mariana trench, DSDP Legs 58 and 60

From the experimental data on stepwise thermal release of neutron induced 39Ar (39K (n, p) 39Ar) from rocks and minerals, Arrhenius plots were constructed, which gave activation energies for the thermal release process. The activation energies for DSDP Leg 58 and Leg 60 submarine volcanic rocks range from 12 to 20 kcal/mol, whereas those for granodiorites and the K-feldspar separates have activation energies ranging from 37 to 48 kcal/mol. The smaller activation energies for the submarine volcanic rocks reflect the grain boundary diffusion process, while the thermal diffusion of 39Ar from granodiorites and K-feldspar is essentially controlled by a volume diffusion. The grain boundary diffusion for the submarine volcanic rocks suggests that K resides essentially in the grain boundaries.

Selective destructive demagnetization of breccias from DSDP Hole 83-504B

The magnetization of four breccia samples from the Leg 83 section of DSDP Hole 504B was analyzed by selective destructive demagnetization in order to study the origin and stability of hydrothermally altered basalts. The NRM directions of the clasts for three of the four samples are randomly oriented and much more strongly magnetized than the bulk sample. Clasts which were individually demagnetized show two or more components of magnetization, but neither are coincident with those of the bulk sample, indicating that NRM was probably acquired prior to the consolidation of the breccia and suggesting that any overprint (VRM or otherwise) can be removed by AF demagnetization to at most 50 Oe. Reflected light microscopy and electron microprobe analysis of two samples show that the unexpectedly high NRM of the matrix regions is apparently the result of secondary magnetic phases precipitated from hydrothermal solutions.

Plio-Pleistocene magnetic polarity stratigraphies of ODP Leg 177 Sites from the South Atlantic

Magnetic polarity stratigraphies from ODP Leg 177 'high resolution' sites indicate Brunhes sedimentation rates in the 12-25 cm/kyr range, with a trend of decreasing sedimentation rates with increasing age. Magnetite is the principal remanence-carrying mineral. Downcore alteration of magnetite and authigenic growth of iron sulfides introduces a high coercivity diagenetic remanence carrier (pyrrhotite). The change in pore water sulfate with depth in the sediment tends to be in step with the decrease in magnetization intensity, indicating the link between sulfate reduction and magnetite dissolution. Shipboard pass-through magnetometer data are generally very noisy due to a combination of weak magnetization intensities, drilling-related core deformation, and the influence of authigenic iron sulfides. Post-cruise progressive demagnetization of discrete samples aids the magnetostratigraphic interpretation, as these measurements are less influenced by low magnetization intensities and drilling-related deformation. The magnetostratigraphic interpretations provide much-needed calibration for biostratigraphic events in the high latitude southern oceans. Apart from the ODP Hole 745B (Kerguelen Plateau), published Plio-Pleistocene magnetostratigraphies from ODP sites in the Southern Ocean are poorly constrained. For this reason, we compare interpolated ages of 11 radiolarian events and one diatom event that occur at Hole 745B and Leg 177 sites.