delta Deuterium of alkenone and BIT index of sediment core 64PE304-80 samples

Reconstructing past ocean salinity is important for assessing paleoceanographic change and therefore past climatic dynamics. Commonly, sea water salinity reconstruction is based on foraminifera oxygen isotope ratio values combined with sea surface temperature reconstruction. However, the approach relies on multiple proxies, resulting in relatively large uncertainty and, consequently, relatively low accuracy of salinity estimates. An alternative tool for past ocean salinity reconstruction is the hydrogen isotope composition of long chain (C37) alkenones (dDalkenone). Here, we applied dDalkenone to a 39 ka long coastal sediment record from the Eastern South African continental shelf in the Mozambique Channel, close to the Zambezi River mouth. Despite changes in global sea water dD related to glacial - interglacial ice volume effects, no clear changes were observed in the dDalkenone record throughout the entire 39 ka. The BIT index record from the same core showed high BIT values during the glacial and low values during the Holocene. This indicates a more pronounced freshwater influence at the core location during the glacial, resulting in alkenones depleted in deuterium during that time and, thereby, explains the lack of a clear glacial-interglacial alkenone dD shift. Correlation between the BIT index and dDalkenone during the glacial period suggests that increased continental runoff potentially changed the growth conditions of the alkenone producing haptophytes, promoting coastal haptophyte species with generally more enriched dDalkenone values. We therefore suggest that the application of dDalkenone for reconstructing past salinity in coastal settings may be complicated by changes in the alkenone producing haptophyte community.

(Table 1) Iron and manganese speciations in surface layer bottom sediments of the Pacific Ocean

Distribution of iron and manganese speciations in ocean sediments of a section from the coast of Japan to the open Pacific Ocean is under consideration. Determinations of total iron, as well as of reactive iron contents and of total manganese, as well as of Mn4+ contents have been done. Significant increase of total Fe content in sediments from the coast to the pelagic zone occurs without noticeable increase in reactive Fe content. Presence of layers of volcanic and terrigenous coarse clastic material in clayey sediments results to sharp change in iron content. Manganese content increases from near coastal to pelagic sediments more than 10 times; oxidation degree of sediments also increases. There are three types of bottom sediments different by contents of iron and manganese forms: reduced, oxidized (red clay), and transitional. Content of total Fe is almost does not change with depth in sediments, content of reactive Fe increases in reduced sediments, and decreases in oxidized ones. Manganese content in red clay mass increases several times.

Barite accumulation rates throughout Pliocene-Pleistocene in Eastern Equatorial Pacific at ODP Site 138-849

Export production is an important component of the carbon cycle, modulating the climate system by transferring CO2 from the atmosphere to the deep ocean via the biological pump. Here we use barite accumulation rates to reconstruct export production in the eastern equatorial Pacific over the past 4.3 Ma. We find that export production fluctuated considerably on multiple time scales. Export production was on average higher (51 g C/m**2/yr) during the Pliocene than the Pleistocene (40 g C/m**2/yr), decreasing between 3 and 1 Ma (from more than 60 to 20 g C/m**2/yr) followed by an increase over the last million years. These trends likely reflect basin-scale changes in nutrient inventory and ocean circulation. Our record reveals decoupling between export production and temperatures on these long (million years) time scale. On orbital time scales, export production was generally higher during cold periods (glacial maxima) between 4.3 and 1.1 Ma. This could be due to stronger wind stress and higher upwelling rates during glacial periods. A shift in the timing of maximum export production to deglaciations is seen in the last ~1.1 million years. Results from this study suggest that, in the eastern equatorial Pacific, mechanisms that affect nutrient supply and/or ecosystem structure and in turn carbon export on orbital time scales differ from those operating on longer time scales and that processes linking export production and climate-modulated oceanic conditions changed about 1.1 million years ago. These observations should be accounted for in climate models to ensure better predictions of future climate change.

Seawater carbonate chemistry, and Lithophyllum sp. and Feldmannia spp. coverage and dry weight during experiments, 2009

Climate-driven change represents the cumulative effect of global through local-scale conditions, and understanding their manifestation at local scales can empower local management. Change in the dominance of habitats is often the product of local nutrient pollution that occurs at relatively local scales (i.e. catchment scale), a critical scale of management at which global impacts will manifest. We tested whether forecasted global-scale change [elevated carbon dioxide (CO2) and subsequent ocean acidification] and local stressors (elevated nutrients) can combine to accelerate the expansion of filamentous turfs at the expense of calcifying algae (kelp understorey). Our results not only support this model of future change, but also highlight the synergistic effects of future CO2 and nutrient concentrations on the abundance of turfs. These results suggest that global and local stressors need to be assessed in meaningful combinations so that the anticipated effects of climate change do not create the false impression that, however complex, climate change will produce smaller effects than reality. These findings empower local managers because they show that policies of reducing local stressors (e.g. nutrient pollution) can reduce the effects of global stressors not under their governance (e.g. ocean acidification). The connection between research and government policy provides an example whereby knowledge (and decision making) across local through global scales provides solutions to some of the most vexing challenges for attaining social goals of sustainability, biological conservation and economic development.

Seawater carbonate chemistry, pigments and biological processes during experiments with coralline alga Corallina sessilis

Previous studies have shown that increasing atmospheric CO2 concentrations affect calcification in some planktonic and macroalgal calcifiers due to the changed carbonate chemistry of seawater. However, little is known regarding how calcifying algae respond to solar UV radiation (UVR, UVA+UVB, 280-400 nm). UVR may act synergistically, antagonistically or independently with ocean acidification (high CO2/low pH of seawater) to affect their calcification processes. We cultured the articulated coralline alga Corallina sessilis Yendo at 380 ppmv (low) and 1000 ppmv (high) CO2 levels while exposing the alga to solar radiation treatments with or without UVR. The presence of UVR inhibited the growth, photosynthetic O2evolution and calcification rates by13%, 6% and 3% in the low and by 47%, 20% and 8% in the high CO2 concentrations, respectively, reflecting a synergistic effect of CO2 enrichment with UVR. UVR induced significant decline of pH in the CO2-enriched cultures. The contents of key photosynthetic pigments, chlorophyll a and phycobiliproteins decreased, while UV-absorptivity increased under the highpCO2/low pH condition. Nevertheless, UV-induced inhibition of photosynthesis increased when the ratio of particulate inorganic carbon/particulate organic carbon decreased under the influence of CO2-acidified seawater, suggesting that the calcified layer played a UV-protective role. Both UVA and UVB negatively impacted photosynthesis and calcification, but the inhibition caused by UVB was about 2.5-2.6 times that caused by UVA. The results imply that coralline algae suffer from more damage caused by UVB as they calcify less and less with progressing ocean acidification.

Projections for Land Use Change in Brazil:2000-2050, links to files in ArcGIS shapefile format

This data set contains the inputs and the results of the REDD+ Policy Assessment Centre project (REDD-PAC) project (http://www.redd-pac.org), developed by a consortium of research institutes (IIASA, INPE, IPEA, UNEP-WCMC), supported by Germany's International Climate Initiative. Taking a new land use map of Brazil for 2000 as input, the research team used the global economic model GLOBIOM to project land use changes in Brazil up to 2050. Model projections show that Brazil has the potential to balance its goals of protecting the environment and becoming a major global producer of food and biofuels. The model results were taken into account by Brazilian decision-makers when developing the country's intended nationally determined contribution (INDC).