Geochemical and rock magnetic investigation of sediment cores of the western South Atlantic

Geochemical and rock magnetic investigations of sediments from three sites on the continental margin off Argentina and Uruguay were carried out to study diagenetic alteration of iron minerals driven by anaerobic oxidation of methane (AOM). The western Argentine Basin represents a suitable sedimentary environment to study nonsteady-state processes because it is characterized by highly dynamic depositional conditions. Mineralogic and bulk solid phase data document that the sediment mainly consists of terrigenous material with high contents of iron minerals. As a typical feature of these deposits, distinct minima in magnetic susceptibility (k) are observed. Pore water data reveal that these minima in susceptibility coincide with the current depth of the sulfate/methane transition (SMT) where HS- is generated by the process of AOM. The released HS- reacts with the abundant iron (oxyhydr)oxides resulting in the precipitation of iron sulfides accompanied by a nearly complete loss of magnetic susceptibility. Modeling of geochemical data suggest that the magnetic record in this area is highly influenced by a drastic change in mean sedimentation rate (SR) which occurred during the Pleistocene/Holocene transition. We assume that the strong decrease in mean SR encountered during this glacial/interglacial transition induced a fixation of the SMT at a specific depth. The stagnation has obviously enhanced diagenetic dissolution of iron (oxyhydr)oxides within a distinct sediment interval. This assumption was further substantiated by numerical modeling in which the mean SR was decreased from 100 cm/kyr during glacial times to 5 cm/kyr in the Holocene and the methane flux from below was fixed to a constant value. To obtain the observed geochemical and magnetic patterns, the SMT must remain at a fixed position for ~9000 yrs. This calculated value closely correlates to the timing of the Pleistocene/Holocene transition. The results of the model show additionally that a constant high mean SR would cause a concave-up profile of pore water sulfate under steady state conditions.

Physical properties and sedimentology on core GeoB1510-1

Detailed information about the sediment properties and microstructure can be provided through the analysis of digital ultrasonic P wave seismograms recorded automatically during full waveform core logging. The physical parameter which predominantly affects the elastic wave propagation in water-saturated sediments is the P wave attenuation coefficient. The related sedimentological parameter is the grain size distribution. A set of high-resolution ultrasonic transmission seismograms (ca. 50-500 kHz), which indicate downcore variations in the grain size by their signal shape and frequency content, are presented. Layers of coarse-grained foraminiferal ooze can be identified by highly attenuated P waves, whereas almost unattenuated waves are recorded in fine-grained areas of nannofossil ooze. Color-encoded pixel graphics of the seismograms and instantaneous frequencies present full waveform images of the lithology and attenuation. A modified spectral difference method is introduced to determine the attenuation coefficient and its power law a = kfn. Applied to synthetic seismograms derived using a "constant Q" model, even low attenuation coefficients can be quantified. A downcore analysis gives an attenuation log which ranges from ca. 700 dB/m at 400 kHz and a power of n = 1-2 in coarse-grained sands to few decibels per meter and n ? 0.5 in fine-grained clays. A least squares fit of a second degree polynomial describes the mutual relationship between the mean grain size and the attenuation coefficient. When it is used to predict the mean grain size, an almost perfect coincidence with the values derived from sedimentological measurements is achieved.

Magnetic susceptibility and documentation of sediment cores from the Antarctic Peninsula Pacific margin

The effects of glaciation on sediment drifts is recognised from marked sedimentary facies variation in deep sea cores taken from the continental rise of the Antarctic Peninsula Pacific margin. Nineteen sediment cores were visually described, logged for magnetic susceptibility, and X-radiographed. About 1000 analyses were performed for grain size, clay minerals and biostratigraphy (foraminifera, nannofossils and diatoms). Four sediment types associated with distinct sedimentary processes are recognised based on textural/compositional analysis. (1) Hemipelagic mud forms the bulk of the interglacial sediment, and accumulated from the pelagic settling of bioclasts and ice-rafted/windtransported detritus. (2) Terrigenous mud forms the bulk of the glacial sediment, and accumulated from a combination of sedimentary processes including turbidity currents, turbid plumes, and bottom current reworking of nepheloid layers. (3) Silty deposits occurring as laminated layers and lenses, represent the lateral spillout of lowdensity turbidity currents. (4) Lastly, glacial/interglacial gravelly mud layers derive from settling of ice-rafted detritus. Five depositional settings are interpreted within sediment Drift 7, each characterised by the dominance/interaction of one or several depositional processes. The repetitive succession of typical sedimentary facies is inferred to reflect a sequence of four climatic stages (glaciation, glacial, deglaciation, and interglacial), each one characterised by a distinctive clay mineral assemblage and bioclastic content. Variations in clay mineral assemblage within interglacial stage 5 (core SED-06) suggest minor colder climatic fluctuations, possibly correlatable with substages 5a to 5e.

Analytical results from sediment core MD03-2698

It is well established that orbital scale sea-level changes generated larger transport of sediments into the deep-sea during the last glacial maximum than the Holocene. However, the response of sedimentary processes to abrupt millennial-scale climate variability is rather unknown. Frequency of distal turbidites and amounts of advected detrital carbonate are estimated off the Lisbon-Setúbal canyons, within a chronostratigraphy based on radiometric ages, oxygen isotopes and paleomagnetic key global anomalies. We found that: 1) Higher frequency of turbidites concurred with Northern Hemisphere coldest temperatures (Greenland Stadials [GS], including Heinrich [H] events). But more than that, an escalating frequency of turbidites starts with the onset of global sea-level rising (and warming in Antarctica) and culminates during H events, at the time when rising is still in its early-mid stage, and the Atlantic Meridional Overturning Circulation (AMOC) is re-starting. This short time span coincides with maximum gradients of ocean surface and bottom temperatures between GS and Antarctic warmings (Antarctic Isotope Maximum; AIM 17, 14, 12, 8, 4, 2) and rapid sea-level rises. 2) Trigger of turbidity currents is not the only sedimentary process responding to millennial variability; land-detrital carbonate (with a very negative bulk d18O signature) enters the deep-sea by density-driven slope lateral advection, accordingly during GS. 3) Possible mechanisms to create slope instability on the Portuguese continental margin are sea-level variations as small as 20 m, and slope friction by rapid deep and intermediate re-accommodation of water masses circulation. 4) Common forcing mechanisms appear to drive slope instability at both millennial and orbital scales.

North Atlantic IODP Site 303-U1308 Middle Pleistocene Heinrich Events record

Heinrich events are well documented for the last glaciation, but little is known about their occurrence in older glacial periods of the Pleistocene. Here we report scanning XRF and bulk carbonate d18O results from Integrated Ocean Drilling Program Site U1308 (reoccupation of Deep Sea Drilling Project Site 609) that are used to develop proxy records of ice-rafted detritus (IRD) for the last ~1.4 Ma. Ca/Sr is used as an indicator of IRD layers that are rich in detrital carbonate (i.e., Heinrich layers), whereas Si/Sr reflects layers that are poor in biogenic carbonate and relatively rich in detrital silicate minerals. A pronounced change occurred in the composition and frequency of IRD at ~640 ka during marine isotope stage (MIS) 16, coinciding with the end of the middle Pleistocene transition. At this time, "Hudson Strait" Heinrich layers suddenly appeared in the sedimentary record of Site U1308, and the dominant period of the Si/Sr proxy shifted from 41 ka prior to 640 ka to 100 ka afterward. The onset of Heinrich layers during MIS 16 represents either the initiation of surging of the Laurentide Ice Sheet (LIS) off Hudson Strait or the first time icebergs produced by this process survived the transport to Site U1308. We speculate that ice volume (i.e., thickness) and duration surpassed a critical threshold during MIS 16 and activated the dynamical processes responsible for LIS instability in the region of Hudson Strait. We also observe a strong coupling between IRD proxies and benthic d13C variation at Site U1308 throughout the Pleistocene, supporting a link between iceberg discharge and weakening of thermohaline circulation in the North Atlantic.