Accumulation rates, carbon composition and Eocene carbonate compensation depths of ODP Sites 199-1218 and 199-1219

CaCO3, Corg, and biogenic SiO2 were measured in Eocene equatorial Pacific sediments from Sites 1218 and 1219, and bulk oxygen and carbon isotopes were measured on selected intervals from Site 1219. These data delineate a series of CaCO3 events that first appeared at ~48 Ma and continued to the Eocene/Oligocene boundary. Each event lasted 1-2 m.y. and is separated from the next by a low CaCO3 interval of a similar time span. The largest of these carbonate accumulation events (CAE-3) is in Magnetochron 18. It began at ~42.2 Ma, lasted until ~40.3 Ma, and was marked by higher than average productivity. The end of CAE-3 was abrupt and was associated with a large-scale carbon transfer to the oceans prior to warming of high-latitude regions. Changes in carbonate compensation depth associated with CAE excursions were small in the early part of the middle Eocene but increased to as much as 800 m by the late middle Eocene before decreasing into the late Eocene. Oxygen isotope data indicate that the carbonate events are associated with cooling conditions and may mark small glaciations in the Eocene.

High resolution stable isotope and Mg/Ca record of sediment core MD02-2550C2

An early Holocene record from the Gulf of Mexico (GOM) reveals climatic and hydrologic changes during the interval from 10.5 to 7 thousand calendar years before present from paired analyses of Mg/Ca and d18O on foraminiferal calcite. The sea surface temperature record based on foraminiferal Mg/Ca contains six oscillations and an overall ~1.5°C warming that appears to be similar to the September-March insolation difference. The d18O of seawater in the GOM (d18OGOM) record contains six oscillations, including a -0.8 per mil excursion that may be associated with the "8.2 ka climate event" or a broader climate anomaly. Faunal census records from three GOM cores exhibit similar changes, suggesting subcentennial-scale variability in the incursions of Caribbean waters into the GOM. Overall, our results provide evidence that the subtropics were characterized by decadal- to centennial-scale climatic and hydrologic variability during the early Holocene.

Stable oxygen isotope, UK'37, productivity, CaCO3 and XRF records from sediment core MD06-3075

Proxy records of hydrologic variability in the West Pacific Warm Pool (WPWP) have revealed wide-scale changes in past convective activity in response to orbital and sub-orbital climate forcings. However, attributing proxy responses to regional changes in WPWP hydrology versus local variations in precipitation requires independent records linking the terrestrial and marine realms. We present high-resolution stable isotope, UK'37 sea-surface temperature, X-ray fluorescence (XRF) core scanning and coccolithophore-derived paleoproductivity records covering the past 120 ka from International Marine Global Change (IMAGES) Program Core MD06-3075 (6°29' N, 125°50' E, water depth 1878 m), situated in the Davao Gulf on the southern side of Mindanao. XRF-derived log(Fe/Ca) records provide a robust proxy for runoff-driven sedimentary discharge from Mindanao, whilst past changes in local productivity are associated with variable freshwater runoff and stratification of the surface layer. Significant precessional-scale variability in sedimentary discharge occurred during Marine Isotope Stage (MIS) 5, with peaks in discharge contemporaneous with Northern Hemisphere summer insolation minima. We attribute these changes to the latitudinal migration of the Intertropical Convergence Zone (ITCZ) over the WPWP together with variability in the strength of the Walker circulation acting on precessional timescales. Between 60 and 15 ka sedimentary discharge at Mindanao was muted, displaying little orbital- or millennial-scale variability, likely in response to weakened precessional insolation forcing and lower sea level driving increased subsidence of air masses over the exposed Sunda Shelf. These results highlight the high degree of local variability in the precipitation response to past climate changes in the WPWP.

Seawater carbonate chemistry and processes during an experiment with coral reef, 2000

The concentration of CO2 in the atmosphere is projected to reach twice the preindustrial level by the middle of the 21st century. This increase will reduce the concentration of [CO3]2- of the surface ocean by 30% relative to the preindustrial level and will reduce the calcium carbonate saturation state of the surface ocean by an equal percentage. Using the large 2650 m3 coral reef mesocosm at the BIOSPHERE-2 facility near Tucson, Arizona, we investigated the effect of the projected changes in seawater carbonate chemistry on the calcification of coral reef organisms at the community scale. Our experimental design was to obtain a long (3.8 years) time series of the net calcification of the complete system and all relevant physical and chemical variables (temperature, salinity, light, nutrients, Ca2+,pCO2, TCO2, and total alkalinity). Periodic additions of NaHCO3, Na2CO3, and/or CaCl2 were made to change the calcium carbonate saturation state of the water. We found that there were consistent and reproducible changes in the rate of calcification in response to our manipulations of the saturation state. We show that the net community calcification rate responds to manipulations in the concentrations of both Ca2+ and [CO3]2- and that the rate is well described as a linear function of the ion concentration product, [Ca2+]0.69[[CO3]2-]. This suggests that saturation state or a closely related quantity is a primary environmental factor that influences calcification on coral reefs at the ecosystem level. We compare the sensitivity of calcification to short-term (days) and long-term (months to years) changes in saturation state and found that the response was not significantly different. This indicates that coral reef organisms do not seem to be able to acclimate to changing saturation state. The predicted decrease in coral reef calcification between the years 1880 and 2065 A.D. based on our long-term results is 40%. Previous small-scale, short-term organismal studies predicted a calcification reduction of 14-30%. This much longer, community-scale study suggests that the impact on coral reefs may be greater than previously suspected. In the next century coral reefs will be less able to cope with rising sea level and other anthropogenic stresses.