Age determination and paleotemperatures of sediment cores TTR17-1_384B and TTR17-1_436B in the Alboran Sea

Climate conditions in the westernmost Mediterranean (Alboran Sea basin) over the last two millennia have been reconstructed through integration of molecular proxies applied for the first time in this region at such high resolution. Two temperature proxies, one based on isoprenoid membrane lipids of marine Thaumarchaeota (TEXH86-tetraether index of compounds consisting of 86 carbons) and the other on alkenones produced by haptophytes (UK'37 ratio) were applied to reconstruct sea surface temperature (SST). Both records reveal a progressive long term decline in SST over the last two millennia and an increased rate of warming during the second half of the twentieth century. This is in accord with previous temperature reconstructions for the Northern Hemisphere. TEXH86 temperature values are higher than those inferred from UK'37, probably due to differences in the bloom season of haptophytes and Thaumarchaeota, and reflect summer SST. The branched vs. isoprenoid tetraether index (BIT index) suggests a low contribution of soil organic matter (OM) to the sedimentary OM. The stable carbon isotopic composition of long chain n-alkanes indicates a predominant C3 plant contribution, with no major change in vegetation over the last 2000 yr. The distribution of long chain 1,14-diols (most likely sourced by Proboscia species in this setting) provided insight into variation in upwelling conditions during the last 2000 yr and depicts a correlation with the North Atlantic Oscillation (NAO) index, providing evidence of enhanced wind induced upwelling during periods of a persistent positive mode of the NAO.

Age determination of sediment core M1_251, Persian Gulf (Table 1)

Sediments from a 3.40 m core out of the Persian Gulf were investigated for their content of straight chain paraffins and fatty acids. The samples range in age between 2000 and 9000 years (C-14-age of organic C). They contain 100-300 ppm of extractable fatcompounds and 20-70 ppm of hydrocarbons. There is no connection between the original distribution of the homologous series of n-fatty acids and n-paraffins. However, there is evidence that part of the n-fatty acids was reduced to n-paraffins, although the sediment itself does not look as if it were deposited under reducing conditions.

Paleomagnetic and stable isotope measurements and distribution of benthic foraminifera in sediment core PS1388-3 from the Antarctic continental margin in the eastern Weddell Sea

A stable isotope record from the eastern Weddell Sea from 69°S is presented. For the first time, a 250,000-yr record from the Southern Ocean can be correlated in detail to the global isotope stratigraphy. Together with magnetostratigraphic, sedimentological and micropalaeontological data, the stratigraphic control of this record can be extended back to 910,000 yrs B.P. A time scale is constructed by linear interpolation between confirmed stratigraphic data points. The benthic d18O record (Epistominella exigua) reflects global continental ice volume changes during the Brunhes and late Matuyama chrons, whereas the planktonic isotopic record (Neogloboquadrina pachyderma) may be influenced by a meltwater lid caused by the nearby Antarctic ice shelf and icebergs. The worldwide climatic improvement during deglaciations is documented in the eastern Weddell Sea by an increase in production of siliceous plankton followed, with a time lag of approximately 10,000 yrs, by planktonic foraminifera production. Peak values in the difference between planktonic and benthic d13C records, which are 0.5 per mil higher during warm climatic periods than during times with expanded continental ice sheets, also suggest increased surface productivity during interglacials in the Southern Ocean.

Age model of ODP Site 113-697 (Table 2)

We examined diatom preservation patterns in Pliocene age sediments of Jane Basin (ODP Site 697) and compared them with diatom distribution in more northerly sites at various sectors of the Southern Ocean. Our data from Site 697, as well as other sites from around the Southern Ocean, support the view that there was significant ice growth on Antarctica during the late Pliocene. DSDP Site 514 in the Atlantic sector shows increased relative abundance of Eucampia antarctica, an ice-related form, in the upper part of the Gauss Chron with a larger increase just above it. With one exception, all sites included in the present study show increased relative abundance of E. antarctica in the upper part of the Gauss. Our view that there was ice growth on Antarctica during the late Gauss Chron is supported by the results from ODP Site 697. While diatoms are present and percent opal is high in the early and middle Gauss Chron (suggesting more open-ocean conditions), late Gauss sediments contain low percentages of opal and few or no diatoms. This is also true for the early Matuyama Chron. If we accept spring and summer sea-ice cover as the major suppressant of diatom productivity in the Southern Ocean, then we conclude that sea-ice covered the region around Site 697 through much of the year during this interval. Further, the absence of diatoms and the low percentages of opal in middle and late Matuyama chron sediments suggests increased sea-ice cover over the Jane Basin during this time. Although warmer openocean intervals are inferred for intervals near the Olduvai and Jaramillo Subchrons, most of the Matuyama Chron was marked by extensive sea-ice cover with low seasonal contrast. Our results for the early part of the Brunhes Chron are similar, at least for the Jane Basin. During this time, sea-ice cover over the basin apparently extended well into the growing season. In contrast, the later Brunhes Chron is marked by alternating open water (during the growing season) and extensive, almost year-round, sea-ice.

Distribution of foraminifera, pre-Pliocene foraminifera and macrofossil debris in sediment core CRP-2 (Table 1)

The stratigraphic distribution, assemblage content, paleoecology and age of foraminifera recovered in fourteen of sixteen samples from the 5.63 m thick CRP-2 (Lithostratigraphic Unit 2.2) are discussed. LSU 2.2 comprises four discrete lithologic beds. The upward sequence is informally referred to as the lower sand bed, diamicton bed, middle sand bed, and upper sand bed and it is surmised that these four units are closely related in time. The lower sand bed (~1.5m), which overlies lower Miocene sediments and from which it is separated by the Ross Sea Unconformity, contains traces of recycled Miocene diatoms but is otherwise barren of biogenic material. The diamicton bed (~2.42 m) contains 21 species of benthic foraminifera, with assemblages consistently dominated by Cassidulinoides porrectus, Ammoelphidiella antarctica, Rosalina cf. globularis, Cibicides refulgens, and Ehrenbergina glabra. The overlying middle sand bed (~1.9 m) contains 13 species. with C. porrectus and E. glabra dominant and A. antarctica less common than in the underlying diamicton bed. The upper sand bed (~0.46 m) contains four species and very few tests. The diamicton bed and middle sand bed assemblages are considered to be near in situ thanatocoenoses; and sediments interpreted as marine in origin but influenced by hyposaline waters and nearby ice. Planktic taxa are absent, perhaps indicating the presence of tidewater glaciers, sea ice and/or hyposaline surface waters. The small assemblage in the upper sand bed is more problematic and may be recycled. On the basis of foraminifera in the diamicton and middle sand beds. LSU 2.2 is assigned to the Pliocene. The overlying diamicton in LSU 2.1 contains abundant Quaternary foraminifera.

(Table 1) Age of sediments with anomalously high Hg concentrations in core BDP-98, Lake Baikal

Mercury distribution was examined in the sediments of Lake Baikal that were sampled within the scope of the Baikal Drilling International Project in 1996-1999. The Hg concentrations in the ancient sediments are close to those in the modern sediments with the exception of a few peak values, whose ages coincide with those of active volcanism in adjacent areas. Mercury was demonstrated to be contained in the sediments in the adsorbed Hg0 mode, predominantly in relation with organic matter. When the organic matter of the bottom sediments is decomposed in the course of lithification, Hg is retained in the sediments adsorbed on the residual organic matter, and the concentration of this element corresponds to its initial content in the bottom sediments during their accumulation. Mercury concentrations in lithologically distinct bottom sediments of Lake Baikal and its sediments as a whole depend on the climate. Sediments that were formed during warm periods of time contain more Hg than those produced during cold periods or glaciation. Periodical variations in the Hg concentrations in the bottom sediments of Lake Baikal reflect the variations in the contents of this element in the Earth's atmosphere in the Late Cenozoic, which were, in turn, controlled by the climatic variations on the planet and, thus, can be used for detailed reconstructions of variations in the average global temperature near the planet's surface.