Coccoliths and carbonate grain-size compositions in sediment samples from the Mid-Atlantic Ridge

This study presents a differentiated carbonate budget for marine surface sediments from the Mid-Atlantic Ridge of the South Atlantic, with results based on carbonate grain-size composition. Upon separation into sand, silt, and clay sub-fractions, the silt grain-size distribution was measured using a SediGraph 5100. We found regionally characteristic grain-size distributions with an overall minimum at 8 µm equivalent spherical diameter (ESD). SEM observations reveal that the coarse particles (>8 µm ESD) are attributed to planktic foraminifers and their fragments, and the fine particles (<8 µm ESD) to coccoliths. On the basis of this division, the regional variation of the contribution of foraminifers and coccoliths to the carbonate budget of the sediments are calculated. Foraminifer carbonate dominates the sediments in mesotropic regions whereas coccoliths contribute most carbonate in oligotrophic regions. The grain size of the coccolith share is constant over water depth, indicating a lower susceptibility for carbonate dissolution compared to foraminifers. Finally, the characteristic grain-size distribution in fine silt (<8 µm ESD) is set into context with the coccolith assemblage counted and biometrically measured using a SEM. The coccoliths present in the silt fraction are predominantly large species (length > 4 µm). Smaller species (length < 4 µm) belong to the clay fraction (<2 µm ESD). The average length of most frequent coccolith species is connected to prominent peaks in grain-size distributions (ESD) with a shape factor. The area below Gaussian distributions fitted to these peaks is suggested as a way to quantitatively estimate the carbonate contribution of single coccolith species more precisely compared to conventional volume estimates. The quantitative division of carbonate into the fraction produced by coccoliths and that secreted by foraminifers enables a more precise estimate for source/sink relations of consumed and released CO2 in the carbon cycle. The allocation of coccolith length and grain size (ESD) suggests size windows for the separation or accumulation of distinct coccolith species in investigations that depend on non to slightly-mixed signals (e.g., isotopic studies).

Grain size record of Oligocene to Pleistocene sediments from Broken Ridge

At Ocean Drilling Program Sites 752 and 754, located on Broken Ridge in the eastern Indian Ocean, we recovered a sequence of shallow-water pelagic sediments that span the past 90 m.y. The Oligocene to Pleistocene portion of these sediments are unconsolidated carbonate oozes that display a coherent variation in bulk grain size. We believe these sediments to be winnowed, and suggest that their grain size is a measure of that winnowing energy. The largest increase in grain size, interpreted to represent an enhancement in the energy of ocean currents, occurs in the earliest late Miocene. This increase occurs about 20 m upcore from the oxygen isotope indication of ice-volume increase about 13 Ma, and is about 3 m.y. younger. If this distinct temporal separation between proxy indicators of ice volume and of current intensity observed in the Broken Ridge cores is correct, the general impression of paleoclimatologists that the planetary temperature gradient and therefore atmospheric and oceanic circulation intensity varies directly with ice volume needs to be reconsidered.

The downhole variation of the rock-magnetic properties of DSDP Leg 73 Holes

The magnetic stability and mean intensity of the natural remanent magnetization (NRM) of Leg 73 sediments (Holes 519 to 523) decreases with the age of the sediment. We demonstrate that these variations are linked with physical and chemical changes in the magnetic grains themselves. Alteration of the magnetic component occurs most rapidly shortly after deposition. A significant magnetic alteration over the topmost few meters of the sediments is thought to be the result of oxidation. The modification of the NRM characteristics through the partial dissolution of the carbonate is largely accounted for by the effects of concentraion of the magnetic minerals. We apply the techniques of rock-magnetism and X-ray fluorescence analysis to clarify the physical and chemical mechanisms that affect the magnetic character of the sediment.