Microfossil cyclicity in Late Albian sediments of Kirchrode I borehole

We studied the biological response to orbital forcing in marine Upper Albian sediments recovered from the 245 m-long Kirchrode I borehole in the Lower Saxony basin in northwestern Germany. Results from quantitative analysis of planktonic and benthic foraminifera, of calcareous nannofossils, and radiolaria were used for this study. Spectral analysis in the depth domain indicates for the high sedimentation rate part of the Upper Albian dominant periods with wavelengths of 10±13 m, 5±6 m, and 2±3 m, which we interpret to represent the biological response to orbital forcing in the Milankovitch frequency bands eccentricity, obliquity, and precession, respectively. In addition, a low amplitude 40±50 m cycle was found, which would represent the long-term eccentricity variation of roughly 400 ka. Microfossil cyclicity does not change significantly within the whole core indicating sedimentation rates of 11±12 cm/ka on an average, with variations between 3.5 and 13 ka. Microfossils show greater variability in their abundance changes than the physical and chemical parameters and also greater power in the higher-frequency bands (obliquity and precession). While most of the planktonic foraminifer species studied are dominated by variations in the obliquity, most benthic foraminifer species show an additional strong influence of precession. These differences in the cyclicity of the abundance changes are interpreted as reflecting a stronger influence of low latitude water in the deep waters of the Late Albian Lower Saxony basin than in the shallow waters. This basin was part of a wide, 'Boreal' epicontinental sea, which was connected to the Tethys to the south via the Polish strait and via the Paris basin, and which was connected with the North Atlantic and Arctic to the north. In analogy to results from analysis of data from the Late Neogene, strong effects of precession interpreted as being more characteristic for changes/influences triggered in the low latitudes and those of obliquity to be more characteristic for influences from the high latitudes. The presence of a relatively strong eccentricity cycle, not only in the compound parameters, but also in the abundance changes of single species during the Late Albian means that there must have been a non-linear response to orbital forcing and internal feedbacks.

Late Pleistocene oxygen isotope record of biognic silica

We determined the isotopic composition of oxygen in marine diatoms in eight deep-sea cores recovered from the Atlantic sector of the Southern Ocean. The analytical reproducibility and core-to-core consistency of the isotopic signal suggests that diatom delta18O can be used as a new paleocenographic tool to reconstruct past variations in surface water characteristics and to generate 18O -isotope-based stratigraphy for the Southern Ocean. The data indicate that diatom delta18O reflects sea surface temperature and seawater isotopic composition and that diatoms retain their isotopic signal on timescales of a least 430 ka. The delta18O analyses of different diatom assemblages reveal that the isotopic signal is free of species effects and that the common Antarctic species have the same water-opal fractionation. The transition from the last glacial maximum (LGM) to the Holocene is fully recorded in high sedimentation rate cores. An 18O enrichment during the LGM, a post-LGM meltwater spike and an input of meltwater during the late Holocene are the main isotopic features observed in down core records. The origin of this meltwater was very likely melting icebergs and/or continental ice or by melting sea ice that had accumulated snow. The most pronounced meltwater effects are recorded in cores that are associated with the Weddel gyre. Our results provide the basis for extending isotope studies to oceanic regions devoid of carbonate; further, isotopic stratigraphies may be constructed for records and regions where they were previously not possible.

Siliceous phytoplankton in Late Quaternary sediments of ODP Site 175-1077

Late Quaternary fluctuations in the intensity of Congo River freshwater load were reconstructed using three different proxies (marine and freshwater diatoms, and the delta18O record of Globigerinoides ruber) preserved in the sediments of Ocean Drilling Program (ODP) Site 1077, located at the northern rim of the Congo River fan (5°10'S, 10°26'E). An abrupt change in the diatom assemblage is evident at Termination II: a two- to four-fold increase in (a) the relative abundance of a marine planktonic diatom tolerant of low salinity conditions (Cyclotella litoralis), and (b) in the concentration of freshwater diatoms. The microfossil data suggest a change in the environmental conditions surrounding Site 1077 from predominantly marine to mixed marine/brackish/fresh. The delta18O record of the planktic foraminifera G. ruber (pink) revealed negative deviations from the global oxygen isotope signal since Termination II which occurred during warm stage 1 and substages 3.2, 5.1, 5.3, and 5.5. Comparison of the isotopic signal of ODP Site 1077 with the record from a pelagic location (core GeoB1041 at 3°48'S, 7°05'W) confirms these results. The construction of an artificial delta18O curve using alkenone-derived sea surface temperature (SST) data from a nearby core (GeoB1008 at 6°S, 10°E) allowed us to estimate salinity and temperature effects on the ODP Site 1077 isotopic signal. Although increased SSTs may account for lighter delta18O values during warmer periods, they do not explain the extremely light values documented in the sediments of Site 1077. We used the oxygen isotope difference (Delta delta18O) between our site and GeoB1041 as a proxy for freshwater input. A general trend in the Delta delta18O was observed, with more negative values since Termination II. In addition, conspicuous Delta delta18O negative pulses coincided with periods of northern hemisphere summer insolation maxima over the African continent, suggesting an increase in the freshwater discharge from the Congo River due to enhanced precipitation on the hinterland. Here we propose that the abrupt change in environmental conditions at Site 1077 since Termination II is a consequence of a major reorganization in the depositional environment of the Congo River delta. This reorganization involved sustained equatorward displacement of the Angola-Benguela Front causing a northward deflection of the Congo River plume thus moving plume waters further north than normal and over Site 1077.

Paleotemperature reconstructions from high Late Jurassic paleolatitudes

Oxygen and carbon isotopes have been determined from Late Jurassic (Oxfordian-Tithonian) belemnites and inoceramid bivalves from two Deep Sea Drilling Project (DSDP) sites located on the Falkland Plateau. Mean belemnite delta18O values, derived from well preserved skeletal material, were -1.29? from DSDP site 330 and -1.45? from DSDP site 511. Assuming a seawater SMOW value of -1.0?, mean palaeotemperatures calculated from the oxygen isotopic composition are 17.2°C and 17.9°C, respectively. The inoceramid bivalves yielded much lighter delta18O values (mean -3.58?). Petrographic and geochemical evidence points to the inoceramid bivalves being altered by diagenesis which accordingly accounts for the observed differences in isotopic values. "Vital effects" or the importation of belemnites or inocerarnids from another area, are considered not to account for the observed isotopic trends. The palaeotemperatures interpreted from the belemnites are significantly warmer than other recent estimates of Late Jurassic temperature (from oxygen isotope studies and climate model predictions) from similar southern palaeolatitudes. We suspect our apparent warmer temperatures are because of a combination of increased freshwater runoff depleting surface waters with respect to delta18O and related to the semi-enclosed nature of the depositional basin retaining warmth, relative to the open ocean of similar latitudes.

Major element chemistr yof fallout tephra from ODP Hole 125-782A

New and published analyses of major element oxides (SiO2, TiO2, Al2O3, FeO*, MnO, MgO, CaO, K2O, Na2O and P2O5) from the central Izu Bonin and Mariana arcs (IBM) were compiled in order to investigate the evolution of the IBM in terms of major elements since arc inception at ~49 million years ago. The database comprises ?3500 volcanic glasses of distal tephra fallout and ?500 lava samples, ranging from the Quaternary to mid-Eocene in age. The data were corrected to 4 wt% MgO in order to display the highly resolved temporal trends. These trends show that the IBM major elements have always been "arc-like" and clearly distinct from N-MORB. Significant temporal variations of some major element oxides are apparent. The largest variations are displayed by K4.0. The data support a model wherein the K2O variability is caused by the addition of slab component with strongly differing K2O contents to a fairly depleted subarc mantle; variable extents of melting, or mantle heterogeneity, appear to play a negligible role. The other major element oxides are controlled by the composition and processes of the subarc mantle wedge. The transition from the boninitic and tholeiitic magmatism of the Eocene and Oligocene to the exclusively tholeiitic magmatism of the Neogene IBM is proposed to reflect a change in the composition of the subarc mantle wedge. The early boninitic magmas originate from an ultra-depleted subarc mantle, that is residual to either the melting of E-MORB mantle, or of subcontinental lithospheric mantle. During the Eocene and Oligocene, this residual mantle is gradually replaced by Indian MORB mantle advected from the backarc regions. The Indian MORB mantle is more radiogenic in Nd isotope ratios but also more fertile with respect to major and trace elements. Therefore the Neogene tholeiites have higher Al2O3 and TiO2 contents and lower mg# numbers at given SiO2 content. After the subarc mantle replacement was complete in the late Oligocene or early Miocene, the Neogene IBM entered a "steady state" that is characterized by the continuous advection of Indian MORB mantle from the reararc, which is fluxed by fluids and melt components from slab. The thickness of the IBM crust must have grown with time, but any effects of crustal thickening on the major element chemistry of the IBM magmas appear to be minor relative to the compositional changes that are related to source composition. Therefore next to the processes of melting, the composition of the mantle sources must play a major role in creating substantiative heterogeneities in the major element chemistry of the arc crust.