Jurassic microfossils of DSDP Hole 79-547B

The first marine incursion of the incipient North Atlantic Ocean is recorded in the uppermost Triassic to Lower Jurassic sequence of DSDP Site 547 off central Morocco. A lithologic change from continental red beds below to slope breccias and hemipelagic carbonates above indicates that a carbonate ramp was probably established by Sinemurian time along the Moroccan continental margin and that subsidence in the adjacent basin was rapid in the early phases of continental rift. Foraminifers recovered from the Liassic (Sinemurian-Pliensbachian) basinal deposits are diverse and well preserved. The faunas are compositionally similar to contemporaneous neritic assemblages of Europe and the Grand Banks of Newfoundland. The Middle Jurassic in Hole 547B is characterized by regressive deposits that are poor in foraminifers. The major Late Jurassic "Atlantic" transgression is again represented by basinal deposits consisting of limestone breccias and pelagic carbonates. Foraminifers recovered from this interval are transitional between Late Jurassic assemblages reported from deep-sea deposits in the North Atlantic and typical Late Jurassic neritic assemblages of Europe. The Late Jurassic assemblages of Hole 547B are primarily dominated by nodosariids and spirillinids with moderate abundances of simple arenaceous forms. Nonreticulate epistominids occur very rarely in the Upper Jurassic of Hole 547B. It is tentatively suggested that these represent upper bathyal assemblages.

Organic matter preservation in turbidites on the Madeira Abyssal Plain

Oxidized intervals of five organic-rich Madeira Abyssal Plain (MAP) turbidites deposited during the Miocene, Pliocene, and Pleistocene all displayed comparable major loss of total organic carbon (TOC) (84 ± 3.1%) accompanied by a negative isotopic (d13C) shift ranging from -0.3 to -2.9 per mil. Major but significantly lower loss of total nitrogen (Ntot, 61 ± 7.1%) also occurred, leading to a decrease in TOC relative to Ntot (C/Ntot) and a +1.3 to 2.7 per mil Ntot isotopic (d15N) shift. Compound specific isotopic measurements on plant wax n-alkanes indicate the terrestrial organic component in the unoxidized deposits is 13C-enriched owing to significant C4 contribution. Selective preservation of terrestrial relative to marine organic carbon could account for the d13C behavior of TOC upon oxidation but only if a 13C-depleted component of the bulk terrestrial signal is selectively preserved in the process. Although the C/Ntot decrease and positive d15N shift seems inconsistent with selective terrestrial organic preservation, results from analysis of a Modern eolian dust sample collected in the vicinity indicate these observations are compatible. Regardless of the specific explanation for these isotopic observations, however, our findings provide evidence that paleoreconstruction of properties such as pCO2 using the d13C of TOC is a goal fraught with uncertainty whether or not the marine sedimentary record considered is 'contaminated' with significant terrestrial input. Nonetheless, despite major and selective loss of both marine and terrestrial components as a consequence of postdepositional oxidation, intensive organic geochemical proxies such as the alkenone unsaturation index, UK'37, appear resistant to change and thereby retain their paleoceanographic promise.

Radiocarbon dates of Mytilus shells and peat and wood samples collected on Drayton Island

A multidisciplinary study was undertaken at the Qijurittuq Site (IbGk-3) on Drayton Island in Low-Arctic Quebec (Canada) to document the relationships between climatic, environmental, and cultural changes and the choice of Thule/Inuit dwelling style in the eastern Arctic. Several marine terraces were 14C-dated with shells in order to reconstruct the area's uplift (glacioisostatic rebound) curve. Plant macrofossil analysis of peat was conducted to reconstruct past vegetation and, indirectly, past climate. Archaeological surveys and excavations characterized the structure of subterranean sod houses at the Qijurittuq Site and were supplemented with open interviews with Inuit elders for a better understanding of site location and the use of household space. The sites selected for habitation were well-drained sandy marine terraces in a valley sheltered from prevailing winds. Sod houses were in turn made possible by the abundance of driftwood on the island and the presence of nearby peatland. Thule/Inuit people used semi-subterranean houses rather than igloos at the Qijurittuq Site during the dry, cold conditions toward the end of the Little Ice Age. Stable environmental conditions and food supply during winter possibly explain the use of those semipermanent houses on Drayton Island. However, it does not exclude the use of igloos during short expeditions on ice.

Carbon 14 age dating of wood samples from the Alps

Glacially deformed pieces of wood, organic lake sediments and clasts of reworked peat have been collected in front of Alpine glaciers since AD 1990. The palaeoglaciological interpretation of these organic materials is related to earlier phases of glacier recession surpassing that of today's shrunken glaciers and to tree growth and peat accumulation in the valleys now occupied by the glaciers. Glacial transport of the material is indicated by wood anatomy, incorporated silt, sand and gravel particles, missing bark and deformed treerings. A total of 65 samples have been radiocarbon dated so far, and clusters of dates provide evidence of eight phases of glacier recession: 9910-9550, 9010-7980, 7250-6500, 6170-5950, 5290-3870, 3640-3360, 2740-2620 and 1530-1170 calibrated years BP. Allowing for the timelag between climatic fluctuations, glacier response and vegetation colonization, these recession phases may lag behind climatic changes by 100-200 years.

Biogeochemical measurements associated to deep-sea wood falls

Large organic food falls to the deep sea - such as whale carcasses and wood logs - support the development of reduced, sulfidic niches in an otherwise oxygenated, oligotrophic deep-sea environment. These transient hot spot ecosystems may serve the dispersal of highly adapted chemosynthetic organisms such as thiotrophic bivalves and siboglinid worms. Here we investigated the biogeochemical and microbiological processes leading to the development of sulfidic niches. Wood colonization experiments were carried out for the duration of one year in the vicinity of a cold seep area in the Nile deep-sea fan (Eastern Mediterranean) at depths of 1690 m. Wood logs were deployed in 2006 during the BIONIL cruise (RV Meteor M70/2 with ROV Quest, Marum, Germany) and sampled in 2007 during the Medeco-2 cruise (RV Pourquoi Pas? with ROV Victor 6000, Ifremer, France). Wood-boring bivalves played a key role in the initial degradation of the wood, the dispersal of wood chips and fecal matter around the wood log, and the provision of colonization surfaces to other organisms. Total oxygen uptake measured with a ROV-operated benthic chamber module was higher at the wood (0.5 m away) in contrast to 10 m away at a reference site (25 mmol m-2 d-1 and 1 mmol m-2 d-1, respectively), indicating an increased activity of sedimentary communities around the wood falls. Bacterial cell numbers associated with wood increased substantially from freshly submerged wood to the wood chip/fecal matter layer next to the wood experiments, as determined with Acridine Orange Direct Counts (AODC) and DAPI-stained counts. Microsensor measurements of sulfide, oxygen and pH were conducted ex situ. Sulfide fluxes were higher at the wood experiments when compared to reference measurements (19 and 32 mmol m-2 d-1 vs. 0 and 16 mmol -2 d-1, respectively). Sulfate reduction (SR) rates at the wood experiments were determined in ex situ incubations (1.3 and 2.0 mmol m-2 d-1) and fell into the lower range of SR rates previously observed from other chemosynthetic habitats at cold seeps. There was no influence of wood deposition on phosphate, silicate and nitrate concentrations, but ammonium concentrations were elevated at the wood chip-sediment boundary layer. Concentrations of dissolved organic carbon were much higher at the wood experiments (wood chip-sediment boundary layer) in comparison to measurements at the reference sites, which may indicate that cellulose degradation was highest under anoxic conditions and hence enabled by anaerobic benthic bacteria, e.g. fermenters and sulfate reducers. Our observations demonstrate that, after one year, the presence of wood at the seafloor had led to the creation of sulfidic niches, comparable to what has been observed at whale falls, albeit at lower rates.

Foraminiferal abundances and preservation in ODP Hole 130-805C

Downcore changes in various carbonate dissolution indexes are documented for Hole 805C for the last 1.2 m.y. These indexes include degree of fragmentation of planktonic foraminifers, percent sand, abundance ratio of species of contrasting solution susceptibilities (Globigerinoides sacculifer vs. Pulleniatina, Globorotalia tumida, and Globorotalia menardii), and the difference in d18O between species of contrasting solution susceptibilities (G. sacculifer vs. Pulleniatina). These preservation indexes have been combined into a single composite dissolution index that corresponds closely to the d18O record. The rate of change of the oxygen isotope signal is also important, with glacial-to-interglacial transitions corresponding to maximum preservation events and vice versa. For information on changing productivity (which is important because an increased supply of organic matter may enhance dissolution by lowering pH upon degradation), we present the abundance of coarse-fraction benthic foraminifers per gram and the ratio between two planktonic foraminiferal species, one of which is strongly associated with equatorial upwelling (Globorotalia tumida vs. Pulleniatina). Our results suggest that productivity plays a subordinate role in determining foraminifer preservation. Furthermore, our results confirm previous observations that associate enhanced preservation events with glacial periods and with glacial-to-interglacial transitions. A correlation between preservation and sedimentation rates of these carbonate-rich sediments could not be established. Notable differences are present between the responses of individual dissolution indexes, indicating that processes other than dissolution determine proxy indexes to varying degrees.

Geochemistry and degree of organic carbon preservation in non-bioturbated, shaly sediments

Based on 13 published porewater H2S and sulphate profiles the amount of H2S escaping from non-bioturbated shales varies between some few % to 45% of the amount of bacterially generated H2S. This finding permits calculation of the original organic carbon (TOCor) content of immature nonbioturbated shales using TOC and sulphur content data. In two immature non-bioturbated sequences from Hungary (Toarcian and Oligocene) the first-order correlation between HI and TOC/TOCor was found to be stronger than that between HI and TOC, indicating that sulphate reduction was the leading process both in decrease in TOC content and degradation of kerogen source potential.

Investigations on fossil bivalves and wood from Seymour Island, Antarctica

Quasi-periodic variation in sea-surface temperature, precipitation, and sea-level pressure in the equatorial Pacific known as the El Niño - Southern Oscillation (ENSO) is an important mode of interannual variability in global climate. A collapse of the tropical Pacific onto a state resembling a so-called 'permanent El Niño', with a preferentially warmed eastern equatorial Pacific, flatter thermocline, and reduced interannual variability, in a warmer world is predicted by prevailing ENSO theory. If correct, future warming will be accompanied by a shift toward persistent conditions resembling El Niño years today, with major implications for global hydrological cycles and consequent impacts on socioeconomic and ecological systems. However, much uncertainty remains about how interannual variability will be affected. Here, we present multi-annual records of climate derived from growth increment widths in fossil bivalves and co-occurring driftwood from the Antarctic peninsula that demonstrate significant variability in the quasi-biennial and 3-6 year bands consistent with ENSO, despite early Eocene (~50 Mya) greenhouse conditions with global average temperature -10 degrees higher than today. A coupled climate model suggests an ENSO signal and teleconnections to this region during the Eocene, much like today. The presence of ENSO variation during this markedly warmer interval argues for the persistence of robust interannual variability in our future greenhouse world.