Mineralogy and diagenesis: Their effect on acoustic and electrical properties of pelagic clays at DSDP Leg 86 Holes

Analysis of pelagic clay samples from Sites 576, 578, and 581 shows that physical, acoustic, and electrical trends with increasing burial depth are related to mineralogical and diagenetic changes. The properties of interest are bulk density (roo), porosity (phi), compressional-wave velocity (Vp) and velocity anisotropy (Ap), and electrical resistivity (Ro) and resistivity anisotropy (Ar). In general, as demonstrated in particular for the brown pelagic clay, the increase in roo, Vp, Ro, and to a lesser extent Ap and Ar with increasing depth is primarily caused by decreasing phi (and water content) as a result of compaction. The mineralogy and chemistry of the pelagic clays vary as a function of burial depth at all three sites. These variations are interpreted to reflect changes in the relative importance of detrital and diagenetic components. Mineralogical and chemical variations, however, play minor roles in determining variations in acoustic and electrical properties of the clays with increasing burial depth.

Sedimentology and origin of lower Cretaceous pelagic carbonates and redeposited clastics at DSDP Hole 76-534A

Drilling at Site 534 in the Blake-Bahama Basin recovered 268 m of Lower Cretaceous, Berriasian to Hauterivian, pelagic carbonates, together with volumetrically minor intercalations of claystone, black shales, and terrigenous and calcareous elastics. Radiolarian nannofossil pelagic carbonates accumulated in water depths of about 3300 to 3650 m, below the ACD (aragonite compensation depth) but close to the CCD (calcite compensation depth). Radiolarian abundance points to a relatively fertile ocean. In the Hauterivian and Barremian, during times of warm, humid climate and rising sea level, turbiditic influxes of both terrigenous and calcareous sediments, and minor debris flows were derived from the adjacent Blake Plateau. The claystones and black shales accumulated on the continental rise, then were redeposited onto the abyssal plain by turbidity currents. Dark organic-rich and pale organic-poor couplets are attributed to climatic variations on land, which controlled the input of terrigenous organic matter. Highly persistent, fine, parallel lamination in the pelagic chalks is explained by repeated algal "blooms." During early diagenesis, organic-poor carbonates remained oxygenated and were cemented early, whereas organic-rich intervals, devoid of burrowing organisms, continued to compact later in diagenesis. Interstitial dissolved-oxygen levels fluctuated repeatedly, but bottom waters were never static nor anoxic. The central western Atlantic in the Lower Cretaceous was thus a relatively fertile and wellmixed ocean basin.

Lead and strontium isotopic composition of some metalliferous and pelagic sediments and basalts at DSDP Leg 70 Holes

In recent years, metalliferous sediments have been discovered overlying newly generated oceanic crust in the East Pacific, North Atlantic, Indian Ocean, Red Sea, Gulf of Aden, and elsewhere (e.g., Boström, 1973; Lalou et al., 1977; Bischoff, 1969; Boström and Fisher, 1971; Cann et al., 1977, respectively). Such material has also been recovered by drilling from sediments lying upon older oceanic crust (Boström et al., 1972, 1976; Horowitz and Cronan, 1976). Hydrothermal circulation of seawater at a spreading ridge results in the leaching of Fe, Mn, and possibly other elements from the basaltic volcanic layer and their transport and discharge into ocean bottom waters, whereupon fine-grained Fe-Mn-rich precipitates form and settle into the ambient sediment (cf. Corliss, 1971; Dasch et al., 1971; Spooner and Fyfe, 1973; Bischoff and Dickson, 1975; Heath and Dymond, 1977; Corliss et al., 1979, Edmond et al., 1979). Mn-rich crusts have also been recovered from active ridges and are inferred to have formed in the vicinity of hydrothermal discharge areas (Scott et al., 1974; Moore and Vogt, 1976; Corliss et al., 1978; Hoffert et al., 1978). The source of the trace elements in the metalliferous deposits is generally not clear. They may be derived from seawater by adsorption onto the precipitates or crusts, or from hydrothermal solutions which have leached them from the basalts. Pb, however, can be used as a geochemical tracer because of the known isotopic compositional differences between oceanic basalts and seawater. Isotopic investigations of Pb in ferruginous sediments from the East Pacific have shown that it has been derived partly or mostly from a basaltic source (Bender et al., 1971; Dasch et al., 1971; Dymond et al., 1973). In the present study, Pb isotopic analyses have been made of a suite of metalliferous sediments (nontronite, Mn-oxide crust, Mn-Fe-oxide mud), pelagic sediments, and basalts from the Galapagos mounds area. The main purposes of the Pb study were to determine the source or sources of Pb in the metalliferous sediments, and whether or not stratigraphic variations exist in the isòtopic composition of Pb in the sediments.

Preliminary ichthyolith biostratigraphy and age profiles at DSDP Sites 91-595 and 91-596

Seventy meters of Cenozoic and Mesozoic pelagic clay cored at DSDP Sites 595 and 596 provide the basis for a preliminary analysis of ichthyolith biostratigraphy in the southwest Pacific. A most likely order of the more reliable ichthyolith events is compared with a synthesis of ichthyolith biostratigraphy in the North Pacific and with dated composite ranges. The resultant preliminary ichthyolith stratigraphy suggests that the Cenozoic is represented by the upper 20 m at Site 596 and 16 to 22 m at Site 595. Mixing of taxa precludes a clear recognition of the Cretaceous/Tertiary boundary at Site 595. The occurrence of 13 newly described subtypes is recorded in Mesozoic sediments at Sites 595 and 596. These new subtypes and previously described Mesozoic forms may be useful for recognizing Mesozoic subdivisions when their occurrences in sequences dated by other microfossils are investigated.

Spores, pollen and dinoflagellates in Cretaceous sediments of ODP Hole 129-802A

Lower Cretaceous and Jurassic sediments from Ocean Drilling Program Leg 129 (Sites 800, 801, and 802) and Deep Sea Drilling Project Sites 167, 195, 196, and 463 were analyzed for palynomorphs. In contrast to Atlantic occurrences, all Cretaceous pelagic sediments at these sites in the Pacific are barren of preserved palynomorphs. This absence of palynomorphs appears to be independent of facies, sedimentation rate, paleodepth, and paleolatitude. Except for one sample, the dinocyst-bearing sediments also contain spores and pollen grains. The only palynomorphs observed were in redeposited material having sources near former emergent seamounts. Among the dinoflagellate cysts at Site 802, Dingodinium cerviculum, Odontochitina operculata, Canninginopsis colliveri, and Oligosphaeridium complex are the most important species. Based on the presence of these species and their known biostratigraphic ranges, this basal interval of Site 802 is considered to be Aptian/earliest Albian in age. The lack of dinocysts within the Pacific pelagic sediments may be the result of ubiquitous oxygenated bottom waters throughout the Cretaceous or may indicate that open-marine dinoflagellate populations in this ocean did not produce cysts.

Pelagic, turbiditic, and contouritic sequential deposits on the Cape Verde Plateau

On the Cape Verde Plateau, Neogene deposits are composed of major pelagic and hemipelagic sediments. These sediments show climatic sequences composed of two lithologic terms that differ in their siliciclastic and carbonate contents. Several turbiditic and contouritic sequences are interbedded in these deposits. Turbidite sequences are fine grained and thin bedded with a very low frequency (about 12 sequences during the Neogene). They are composed of quartz-rich siliciclastic or volcaniclastic sediments. Quartz-rich turbidites originated from the Senegalese margin. Their slightly higher frequency during the early Pliocene indicates that the stronger turbidity currents, and probably the most abundant continental inputs, occur at that period. Volcaniclastic turbidites are only present in the early Miocene (about 17 Ma) and the early Pleistocene (1 Ma). They have flown from adjacent Cape Verde Islands and reflect two episodes of high volcanic activity in this area. Contourite sequences, composed of biogenic sandy silts, represent less than 5% of the sediment pile and seem to have been mainly deposited during the late Pleistocene. These different sequences show clay mineral variations throughout Neogene time. Kaolinite is predominant in the Miocene and lower Pliocene deposits; this mineral decreases thereafter, with an increased trend of illite in the uppermost Pliocene and Pleistocene sediments, suggesting a change in sediment sources on the Saharan continent at about 2.6 Ma.

Miocene radiolarians of the Sulu Sea

Radiolarians are sporadic in sediments collected in the Sulu Sea during ODP Leg 124. Due to the generally poor preservation and low abundance of radiolarians in Sulu Sea sediments, no biostratigraphic datums are well defined, although three radiolarian zones are identified. Most samples containing radiolarians are pelagic or hemipelagic clays with varying proportions of volcanic ash. Detailed analysis of Sulu Sea radiolarians was limited to Miocene successions. Pliocene and Quaternary occurrences of radiolarians were noted but have not been zoned. The late middle Miocene of Sites 769 and 771 is represented by an assemblage of radiolarians (Diartus petterssoni Zone) that is entirely replaced by massive pyrite. This type of preservation develops only under anoxic conditions. The development of widespread anoxia in Sulu Sea waters in the late middle Miocene was probably the result of hydrologic isolation of basin waters, and may be associated with eustatic sea level fall over the silled basin. Upper lower Miocene pelagic and hemipelagic sediments that overlie pyroclastics and basalt flows in the Sulu Sea sites contain moderately to very poorly preserved radiolarians of the Calocycletta costata Zone. A thin unit of marine claystone was recovered from between the thick pyroclastics and basement rocks at Site 768. Radiolarians present in these claystones are rare and very poorly preserved. This radiolarian assemblage probably represents the C. costata Zone, although very poor preservation and low abundance make this interpretation equivocal. The radiolarian zones identified constrain the age of basin formation to late early Miocene or earlier.

Elemental and stable isotopic composition of some metalliferous and pelagic sediments at DSDP Leg 70 Holes

Nontronite, the main metalliferous phase of the Galapagos mounds, occurs at subsurface depths of about 2 to 20 meters; Mn-oxide material is limited to the upper 2 meters of the mounds. The nontronite forms intervals of up to a few meters' thickness, consisting essentially of 100% nontronite granules, which alternate with intervals of normal pelagic sediment. Electron microprobe analyses of nontronite granules from different core samples indicate that: (1) there is little difference in major element composition between nontronites from varying locations within the mounds, with adjacent granules from a given sample having very similar compositions; (2) individual granules show little internal variation in composition. This indicates that the granules are composed of a single mineral of essentially constant composition, consistent with relatively uniform conditions of Eh and composition during nontronite formation. Mn-oxide crusts have very low Fe contents, a feature characteristic of rapidly deposited Mn-oxide crusts formed under hydrothermal influences. The rare-earth element (REE) abundances of the nontronites are generally extremely low, totalling less than several ppm. Two samples have the negatively Ce anomaly typical of authigenic precipitates formed relatively rapidly from seawater. A Mn-oxide crust sample has low REE contents, typical of Mn-oxide crusts formed under hydrothermal influences, but no negative Ce anomaly. A sample of unusual Mn-Fe-oxide mud has relatively high REE concentrations and a seawater-type pattern; both of these features are also found for metalliferous sediments from the East Pacific Rise. The oxygen and hydrogen isotopic composition of the nontronites define a restricted field within a d18O-dD plot. In manganiferous sediments, d18O and dD appear to decrease with increase in the Mn-oxide content of the sediment. From the d18O values of the nontronites, formation temperatures in the range of about 20-30°C have been estimated. By comparison, temperatures of up to 11.5 °C at a 9-meter depth have been directly measured within the mounds (Corliss et al., 1979), and heat-flow data suggest present basement/sediment interface temperatures of 15-25°C. In a plot of Fe + Mn vs. d18O, the Mn-oxide crust and Mn-Fe-ooze plot near the tie-lines for authigenic Mn nodules and silicate phases, implying that they have formed in isotopic equilibrium with seawater at or close to bottom-water temperatures.

Geochemistry of pelagic and hemipelagic sediments of ODP Leg 126 sites

Chemical analyses were performed on major, minor, and rare-earth elements of pelagic and hemipelagic sediments of the forearc, arc, and backarc sites of the Izu-Bonin Arc, Ocean Drilling Program Leg 126. Analyses of the hemipelagic and pelagic sediments of this area indicate that the chemical composition of this arc is highly affected by the chemical composition of rocks of this arc as a source of sediments. The Oligocene sediments, which are characterized by high MgO contents, reflect the chemical composition of the Paleogene volcanic rocks of the immature arc. Moreover, the late Miocene to Quaternary sediments with low MgO contents are attributed to the composition of the present arc. We also suggest that the sedimentation rates and topography of the sedimentary basin affect the MnO and SiO2 contents of pelagic and hemipelagic sediments.

Middle Eocene to Miocene calcareous nannofossil of ODP Leg 125

During Ocean Drilling Program Leg 125, a thick sequence of middle Eocene to Pleistocene pelagic sediments, volcanogenic sediments, and predominantly extrusive volcanic rocks was recovered. Calcareous nannofossils were examined from 15 holes at nine sites, but Eocene to Miocene calcareous nannofossils were found only from Holes 782A, 784A, 786A, and 786B. In portions of Holes 786A and 786B, datable nannofossil oozes were found intercalated among volcanic flows. The nannofossil biostratigraphy of these holes indicates the presence of three well-defined hiatuses: within the lower Oligocene, between the upper Oligocene and middle Miocene, and between the middle and upper Miocene. An attempt was made to correlate the magnetochronological data with the first or last occurrences of the following species: Sphenolithus distentus, Reticulofenestra bisecta, Reticulofenestra reticulata, and Cyclicargolithus floridanus abisectus n. comb. The results indicate that the FO of Sphenolithus distentus can extend down to Zone CP16 (34.7 Ma), the LO of Reticulofenestra bisecta best defines the boundary between CP19a and CP19b (23.5 Ma), and the LO of Cyclicargolithus f. abisectus n. comb, can extend up to Subzone CN5a (12.5 Ma). No latest Oligocene Cyclicargolithus f. abisectus n. comb, acme was observed. Cyclicargolithus abisectus is considered a subspecies or variant of Cyclicargolithus floridanus because their LOs coincide. As a consequence of these observations, we have modified the definitions of Bukry's Subzones CP14a, CP14b, and CNla. Analyses of sediment-accumulation rates indicate that the rates increased gradually from the Eocene to Miocene. This is especially evident since the late Miocene in Hole 782A. In different parts of the Izu-Bonin forearc basin, however, the rate is not everywhere the same and appears to vary according to the import of volcanogenic materials.

Concentrations and isotopic ratios of thorium and uranium in pelagic sediments

The predictable in situ production of 230Th from the decay of uranium in seawater, and its subsequent removal by scavenging onto falling particles, provides a valuable tool for normalizing fluxes to the seafloor. We describe a new application, determination of the 232Th that dissolves in the water column and is removed to the seafloor. 232Th is supplied to the ocean in continental minerals, dissolution of which leads to a measurable standing stock in the water column. Sedimentary adsorbed 232Th/230Th ratios have the potential to provide a proxy for estimating the amount of dissolved material that enters the ocean, both today and in the past. Ten core top samples were treated with up to eight different leaching techniques in order to determine the best method for the separating adsorbed from lattice bound thorium. In addition, separate components of the sediments were analyzed to test whether clay dissolution was an important contribution to the final measurement. There was no systematic correlation between the strength of acid used in the leach and the measured 232Th/230Th ratios. In all cases clean foraminifera produced the same ratio as leaches on bulk sediment. In three out of five samples leaches performed on non-carbonate detritus in the <63 µm size fraction were also identical. Without additional water column data it is not yet clear whether there is a simple one to one correlation between the expected deep-water 232Th/230Th and that produced by leaching, especially in carbonate-rich sediments. However, higher ratios, and associated high 232Th adsorbed fluxes, were observed in areas with high expected detrital inputs. The adsorbed fraction was ~35-50% of the total 232Th in seven out of ten samples. Our 230Th normalized 232Th fluxes are reasonable by comparison to global estimates of detrital inputs to the ocean. In nine cases out of ten, the total 230Th-normalized 232Th flux is greater than predicted from the annual dust fall at each specific location, but lower than the average global detrital input from all sources.