Geochemistry of some manganese nodules

The manganese nodules occur in greater or less quantity all over the ocean-bed, and most abundantly in the Pacific. They occur in all sizes, from minute grains to masses of a pound weight, and even greater, and form nodular concretions of concentric shells, round a nucleus, which is very frequently a piece of pumice or a shark's tooth. Their outside has a peculiar and very characteristic mammillated surface, which enables them to be identified at a glance. When freshly brought up they are very soft, being easily scraped to powder with a knife. They gradually get harder on exposure to the air. The powder, heated in a closed tube, gives out water which re-acts alkaline, and has an empyreumatic odour. Heated with strong hydrochloric acid, it liberates abundance of chlorine, and the residue which remains is white, consisting of silica, clay, and sand, the sand being the same as is found in the bottom mud from the same locality. Their composition varies greatly, different nodules containing different quantities of mechanically admixed mud, and the number of different elements found in them is very large. Copper, iron, cobalt, nickel, manganese, alumina, lime, magnesia, silica, and phosphoric acid have been detected in a large number; but I have not as yet been able to make a complete analysis of any of them. I have, however, made a few determinations of the most important component substances. For this purpose the outside and densest layers of the nodules were selected, and portions of them were pulverised and dried for ten or twelve hours at 140° C. The amount of chlorine liberated on treatment with hydrochloric acid was determined by Bunsen's method, and the iron was determined by titration with stannous chloride. The samples analysed were from four different localities.

Upper Cretaceous sediments of ODP Hole 122-762C

Well-developed Campanian to Maestrichtian pelagic cyclic sediments were recovered from Hole 762C on the Exmouth Plateau, off northwest Australia, during Ocean Drilling Program Leg 122. The cycles consist of nannofossil chalk (light beds) and clayey nannofossil chalk (dark beds). Both light and dark beds are strongly to moderately bioturbated, alternate on a decimeter scale, and exhibit gradual boundaries. Bioturbation introduces materials from a bed of one color into an underlying bed of another color, indicating that diagenesis is not responsible for the cyclicity. Differences in composition between the light and dark beds, revealed by calcium carbonate measurement and X-ray diffraction analysis, together with trace fossil evidence, indicate that the cycles in the sediments are a depositional feature. Diagenetic processes may have intensified the appearance of the cycles. Spectral analysis was applied to the upper Campanian to lower Maestrichtian cyclic sediments to examine the regularity of the cycles. Power spectra were calculated from time series using Walsh spectral analysis. The most predominant wavelengths of the color cycles are 34-41 cm and 71-84 cm. With an average sedimentation rate of 1.82 cm/k.y. in this interval, we found the time durations of the cycles to be around 41 k.y. and 21 k.y., respectively, comparable to the obliquity and precession periods of the Earth's rotation, which strongly suggests an orbital origin for the cycles. On the basis of sedimentological evidence and plate tectonic reconstruction, we propose the following mechanism for the formation of the cyclic sediments from Hole 762C. During the Late Cretaceous, when there was no large-scale continental glaciation, the cyclic variations in insolation, in response to cyclic orbital changes, controlled the alternation of two prevailing climates in the area. During the wetter, equable, and warmer climatic phases under high insolation, more clay minerals and other terrestrial materials were produced on land and supplied by higher runoff to a low bioproductivity ocean, and the dark clayey beds were deposited. During the drier and colder climatic phases under low insolation, fewer clay minerals were produced and put into the ocean, where bioproductivity was increased and the light beds were deposited.

Hydraulic conductivity and experiments of sediment beds

In marine environments, sediments from different sources are stirred and dispersed, generating beds that are composed of mixed and layered sediments of differing grain sizes. Traditional engineering formulations used to predict erosion thresholds are however, generally for unimodal sediment distributions, and so may be inadequate for commonly occurring coastal sediments. We tested the transport behavior of deposited and mixed sediment beds consisting of a simplified two-grain fraction (silt (D50 = 55 µm) and sand (D50 = 300 µm)) in a laboratory-based annular flume with the objective of investigating the parameters controlling the stability of a sediment bed. To mimic recent deposition of particles following large storm events and the longer-term result of the incorporation of fines in coarse sediment, we designed two suites of experiments: (1) "the layering experiment": in which a sandy bed was covered by a thin layer of silt of varying thickness (0.2 - 3 mm; 0.5 - 3.7 wt %, dry weight in a layer 10 cm deep); and (2) "the mixing experiment" where the bed was composed of sand homogeneously mixed with small amounts of silt (0.07 - 0.7 wt %, dry weight). To initiate erosion and to detect a possible stabilizing effect in both settings, we increased the flow speeds in increments up to 0.30 m/s. Results showed that the sediment bed (or the underlying sand bed in the case of the layering experiment) stabilized with increasing silt composition. The increasing sediment stability was defined by a shift of the initial threshold conditions towards higher flow speeds, combined with, in the case of the mixed bed, decreasing erosion rates. Our results show that even extremely low concentrations of silt play a stabilizing role (1.4% silt (wt %) on a layered sediment bed of 10 cm thickness). In the case of a mixed sediment bed, 0.18% silt (wt %, in a sample of 10 cm depth) stabilized the bed. Both cases show that the depositional history of the sediment fractions can change the erosion characteristics of the seabed. These observations are summarized in a conceptual model that suggests that, in addition to the effect on surface roughness, silt stabilizes the sand bed by pore-space plugging and reducing the inflow in the bed, and hence increases the bed stability. Measurements of hydraulic conductivity on similar bed assemblages qualitatively supported this conclusion by showing that silt could decrease the permeability by up to 22% in the case of a layered bed and by up to 70% in the case of a mixed bed.

(Table 1) Distribution of Cretaceous-Tertiary benthic foraminifers in ODP Hole 129-802A

Reworked shallow-water larger and deep-water calcareous benthic foraminifers were recovered from foraminiferal packstones and nannofossil chalks in Hole 802A. The autochthonous zeolitic pelagic claystone is characterized by late Campanian abyssal agglutinated foraminifers that allow correlation with the North Atlantic and the adjacent Pigafetta Basin. Assemblages of DendrophryalRhizammina in graded beds within the zeolitic claystone indicate reworking through entrainment in the flocculent E layer of turbidites, rather than recolonization following a biosiliceous event. Background sedimentation of the claystone took place below the carbonate compensation depth. The nannofossil chalk contains reworked lower bathyal to abyssal calcareous foraminifers of late Paleocene to early Miocene age. The topmost bed of the nannofossil chalk unit commences with an algal foraminiferal packstone containing Lepidocyclina sumatrensis, Heterostegina borneensis, Amphistegina hauerina, Asterigerina marshallana, and A. tentoria, which indicate that the source area was a shallow-water reef and allow the bed to be dated as early Miocene. The absence of obviously younger planktonic microfossils in the graded bed indicates that the resedimentation event was generally contemporaneous with original deposition and took place during an early Miocene global sea-level highstand. An early Miocene shallow-water assemblage is also seen in the graded beds at the base of a volcaniclastic turbidite sequence overlying the nannofossil chalks. Resedimentation of this unit was associated with volcanic activity some distance away.

Analysis of radioactive manganiferous nodules from Tanokami, Japan

Characteristic black nodules have been retrieved in 1922 from the bed of the Kichijo River, that runs along the Tanakamiyama mountain in the Oni Province and ends into Lake Biwa in Japan. Their radiocativity has been studied along with that of crusts of similar nature found covering rock formations in the vicinity overlooking the stream. The high content in radium observed may be due to the high uranium content of the granite host rock typical of the Tanakamiyama formation.

Composition of sediments samples spanning the Cretaceous-Tertiary boundary at ODP Site 207-1259

Ocean Drilling Program (ODP) Leg 207, on the Demerara Rise in the western tropical North Atlantic, recovered multiple Cretaceous-Paleogene boundary sections containing an ejecta layer. Sedimentological, geochemical, and paleontological changes across the boundary closely match patterns expected for a mass extinction caused by a single impact. A normally graded, ~2-cm-thick bed of spherules that is interpreted as a primary air-fall deposit of impact ejecta occurs between sediments of the highest Cretaceous Plummerita hantkeninoides foraminiferal zone and the lowest Paleogene P0 foraminiferal zone. There are no other spherule layers in the section. In addition to extinction of Cretaceous taxa, foraminiferal abundance drops from abundant to rare across the boundary. Ir concentrations reach a maximum of ~1.5 ppb at the top of the spherule bed, and the Ir anomaly is associated with enrichment in other siderophile elements. We attribute the unusually well-preserved and relatively simple stratigraphy to the fact that Demerara Rise was close enough (~4500 km) to the Chicxulub impact site to receive ~2 cm of ejecta, yet was far enough away (and perhaps sheltered by the curve of northern South America) to have been relatively unaffected by impact-induced waves.

Investigation of Manganese rich river pebbles from Poland and Austria

The author is studying various manganese coated river pebbles which had been given to him for evaluating their chemical properties. Samples were provided for the confluence of the Vistula and the Dunajec river in Poland by Mr. W. Petraschek. Other samples had been acquired earlier from Pr. A. Fraunhofer in the river bed of the Enns river near the town of Ernsthofen in Austria.