Sea ice measurements during POLARSTERN cruise ANT-XXIII/7 (Winter Weddell Outflow Study)

Various physical properties of snow and sea ice were measured during ice stations in the Western Weddell Sea, Antarctic, during the POLARSTERN cruise ANT-XXIII/7 (WWOS) in 2006. Most stations were reached via a gangway directly from the vessels others by helicopter. All vertical positions are corrected to freeboard, e.g. z=0 represents the snow-ice interface. More detailed information about the data sets and methods are available from the cruise report (section 4 sea-ice physics).

(Table 1) Concentrations of the main organochlorine pesticides in liver and plasma samples of ringed seals (Phoca hispida)

The present study investigates the concentrations and patterns of organochlorine pesticides (OCPs) and their metabolites in liver and plasma of two ringed seal populations (Phoca hispida): lower contaminated Svalbard population and more contaminated Baltic Sea population. Among OCPs, p,p'-DDE and sum-chlordanes were the highest in concentration. With increasing hepatic contaminant concentrations and activities of xenobiotic-metabolizing enzymes, the concentrations of 3-methylsulfonyl-p,p'-DDE and the concentration ratios of pentachlorophenol/hexachlorobenzene increased, and the toxaphene pattern shifted more towards persistent Parlar-26 and -50 and less towards more biodegradable Parlar-44. Relative concentrations of the chlordane metabolites, oxychlordane and -heptachlorepoxide, to sum-chlordanes were higher in the seals from Svalbard compared to the seals from the Baltic, while the trend was opposite for cis- and trans-nonachlor. The observed differences in the OCP patterns in the seals from the two populations are probably related to the catalytic activity of xenobiotic-metabolizing enzymes, and also to differences in dietary exposure.