Organic geochemistry of DSDP Leg 41 holes

The black shale encountered in Cretaceous cores of the Cape Verde area during the DSDP Leg 41 are of marine origin and correspond to excellent potential oil source rocks. They have a low content of humic compounds. Pyrolysis assays, chloroformic extracts, and kerogen data attest to a relatively low stage of evolution for samples at Site 367 (Cape Verde Basin). The samples from Site 368 (Cape Verde Rise) are more evolved, and the deeper ones would be located at the beginning of the principal zone of oil formation.

Organic geochemistry of Cretaceous black shales at DSDP Hole 75-530A

Five-hundred ten meters of Cretaceous sediments were drilled north of the Walvis escarpment in Hole 530A during Leg 75. An immature stage of evolution for organic matter can be assigned to all the samples studied. Black shales are interbedded with red and green claystone in the bottom sedimentary unit, Unit 8, which is of Coniacian to late Albian age. The richest organic carbon contents and petroleum potentials occur in the black shales. Detrital organic matter is present throughout the various members of a sequence, mixed with largely oxidized organic matter in the gray and green claystone or marlstone members on both sides. Detrital organic matter also characterizes the black streaks observed in the claystones. Vertical discontinuities in organic matter distribution are assigned to slumping. Several types of black shales can be identified, according to their content of detrital organic matter, the more detrital black levels corresponding to the Albian-Cenomanian period. Cyclic variations of organic matter observed for a sequence can occur for a set of sequences and even for some consecutive sets of sequences. Climatic factors are proposed to account for the cyclic sedimentation and distribution of organic matter for every sequence that includes a black bed.

Sedimentology and planktonioc foraminifera of core SU90-08

The observation by Heinrich (1988) that, during the last glacial period, much of the input of ice-rafted detritus to the North Atlantic sediments may have occurred as a succession of catastrophic events, rekindled interest on the history of the northern ice sheets over the last glacial period. In this paper, we present a rapid method to study the distribution of these events (both in space and time) using whole core low-field magnetic susceptibility. We report on approximately 20 cores covering the last 150 to 250 kyr. Well-defined patterns of ice-rafted detritus appear during periods of large continental ice-sheet extent, although these are not always associated within their maxima. Most of the events may be traced across the North Atlantic Ocean. For the six most recent Heinrich layers (HL), two distinct patterns exist: HL1, HL2, HL4, HL5 are distributed along the northern boundary of the Glacial Polar Front, over most of the North Atlantic between ~40° and 50°N; HL3 is more restricted to the central and eastern part of the northern Atlantic. The Nd-Sr isotopic composition of the material constituting different Heinrich events indicates the different provenance of the two patterns: HL3 has a typical Scandinavia-Arctic-Icelandic 'young crust' signature, and the others have a large component of northern Quebec and northern West Greenland 'old crust' material. These isotopic results, obtained on core SU-9008 from the North American basin, are in agreement with the study by Jantschik and Huon (1992), who used K-Ar dating of silt- and clay-size fractions of an eastern basin core (ME-68-89). These data confirm the large spatial scale of these events, and the enormous amount of ice-rafted detritus they represent.

Marine and terrigenous lipids in ODP Leg 175 holes

Lipid compositions of sediments recovered during Ocean Drilling Program Leg 175 in the eastern South Atlantic reflect a variety of oceanographic and climatological environments. Most of the identified lipids can be ascribed to marine sources, notably haptophytes, eustigmatophytes, dinoflagellates, archaea, and diatoms. Elevated concentrations of cholesterol suggest zooplankton herbivory, characteristic for sites influenced by upwelling. At these sites, sulfurized highly branched isoprenoids from diatoms are also present in high amounts. Sterols, sterol ethers, hopanoids, and midchain hydroxy fatty acids could also be detected. Terrigenous lipids are n-alkanes, fatty acids, n-alcohols, and triterpenoid compounds like taraxerol and -amyrine. n-Alkanes, fatty acids, and n-alcohols are derived from leaf waxes of higher land plants and transported to the sea by airborne dust or fresh water. Triterpenoid compounds are most probably derived from mangroves and transported solely by rivers. Lipid compositions below the Congo low-salinity plume are strongly influenced by terrigenous material from the Congo River. Elevated organic carbon contents and predominantly marine lipid distributions at the Angola margin may indicate a highly productive plankton population, probably sustained by the Angola Dome. Sedimentary lipids in the Walvis Basin contain an upwelling signal, likely transported by the Benguela Current. Sedimentary lipids off Lüderitz Bay and in the southern Cape Basin are dominated by plankton lipids in high to intermediate amounts, reflecting persistent and seasonal upwelling, respectively.

Calcareous dinoflagellates in Cretaceous to Recent sediments of DSDP Hole 39-356

Calcareous dinoflagellates often dominate the dinoflagellate cyst assemblage in Cretaceous to Recent oceanic sediments. However, their distribution in Paleogene sediments has scarcely been studied. The investigation of samples from DSDP Site 356 for their calcareous dinoflagellate content revealed 35 mainly long-ranging taxa. The associations and characteristic wall types (pithonelloid, oblique, radial, tangential) fluctuate quantitatively and qualitatively in distinct stratigraphic patterns. Significant shifts, primarily at the K/T boundary and the Paleocene/Eocene boundary, reflect changes in environmental conditions. Certain dinoflagellates forming calcareous cysts, such as Operculodinella operculata, were well adapted to the relatively rapid change of environmental conditions at the K/T boundary, thus blooming to dominate the carbonate flux to the ocean floor. In contrast to the stable Paleocene associations, Eocene calcareous dinoflagellates show fluctuations in relative abundances. These fluctuations can possibly be attributed to redeposition related to increased seaward transport of specimens, due to strengthened western boundary currents. The flora includes two new genera, one new species, and two new forms: Retesphaera diadema Hildebrand-Habel, Willems et Versteegh, gen. et. sp. nov., Cervisiella saxea (Stradner, 1961) Hildebrand-Habel, Willems et Versteegh, gen. et comb. nov., Sphaerodinella? tuberosa forma elongata Hildebrand-Habel, Willems et Versteegh, comb. et forma nov., Sphaerodinella? tuberosa forma variospinosa Hildebrand-Habel, Willems et Versteegh, comb. et forma nov. Three new combinations are proposed: Cervisiella saxea (Stradner, 1961) Hildebrand-Habel, Willems et Versteegh, gen. et comb. nov., Operculodinella operculata (Bramlette et Martini, 1964) Hildebrand-Habel, Willems et Versteegh, comb. nov., and Sphaerodinella? tuberosa (Kamptner, 1963) Hildebrand-Habel, Willems et Versteegh, comb. nov. The genus Operculodinella Kienel, 1994 is emended.

Sedimentary lipids and palynomorphs of sediment core ABC26 from the Eastern Mediterranean

Selective degradation of organic matter in sediments is important for reconstructing past environments and understanding the carbon cycle. Here, we report on compositional changes between and within lipid classes and kerogen types (represented by palynomorph groups) in relation to the organic matter flux to the sea floor and oxidation state of the sediments since the early Holocene for central Eastern Mediterranean site ABC26. This includes the initially oxic but nowadays anoxic presapropelic interval, the still unoxidised lower part of the organic rich S1 sapropel, its postdepositionally oxidised and nowadays organic-poor upper part as well as the overlying postsapropelic sediments which have always been oxic. A general ~ 2.3 times increase in terrestrial and marine input during sapropel formation is estimated on the basis of the total organic carbon (TOC), pollen, spore, dinoflagellate cyst, n-alkane, n-alkanol and n-alkanoic acid concentration changes in the unoxidised part of the sapropel. The long-chain alkenones, 1,15 diols and keto-ols, loliolides and sterols indicate that some plankton groups, notably dinoflagellates, may have increased much more. Apart from the terrestrial and surface water contributions to the sedimentary organic matter, anomalous distributions and preservation of some C23-C27 alkanes, alkanols and alkanoic acids have been observed, which are interpreted as a contribution by organisms living in situ. Comparison of the unoxidised S1 sapropel with the overlying oxidised sapropel and the organic matter concentration profiles in the oxidised postsapropelic sediments demonstrates strong and highly selective aerobic degradation of lipids and palynomorphs. There seems to be a fundamental difference in degradation kinetics between lipids and pollen which may be possibly related with the absence of sorptive preservation as a protective mechanism for palynomorph degradation. The n-alkanes, Impagidinium, and Nematosphaeropsis are clearly more resistant than TOC. The n-alkanols and n-carboxylic acids are about equally resistant whereas the pollen, all other dinoflagellate cysts and other lipids appear to degrade considerably faster, which questions the practice of normalising to TOC without taking diagenesis into account. Selective degradation also modifies the relative distributions within lipid classes, whereby the longer-chain alkanes, alcohols and fatty acids disappear faster than their shorter-chain equivalents. Accordingly, interpretation of lipid and palynomorph assemblages in terms of pre- or syndepositional environmental change should be done carefully when proper knowledge of the postdepositional preservation history is absent. Two lipid-based preservation proxies are tested the diol-keto-ol oxidation index based on the 1,15C30 diol and keto-ols (DOXI) and the alcohol preservation index (API) whereby the former seems to be the most promising.