Sedimentary mineralogy of argillaceous sediments at DSDP Legs 56-57 Holes

Mineral assemblages of DSDP Holes 436 and 438A and the upper section of Hole 439 (871.5-911.0 m sub-bottom) resemble each other and are composed of montmorillonite (probably a small portion of montmorillonite/illite mixed-layer clays), illite, chlorite, kaolinite, quartz, plagioclase, hornblende, calcite, dolomite, siderite, gypsum, pyrite, and halite. In the middle section of Hole 439 (933.5-1041.0 m), clinoptilolite is also found. In the lower section of Hole 439 (1077.5-1150.0 m), montmorillonite is not confirmed, and clinoptilolite and mixed-layer illite are found. These assemblages, which also contain detrital kaolinite, are generally found in sediments from brackish-water environments. At Site 439, more than 1000 meters of sediment might have been removed by erosion at the base.

Pebbles and carbonate nodules Legs 56-57 Holes

At all DSDP Leg 56 drilling sites, exotic pebbles occur commonly, throughout the cores. Chips of carbonate nodules occur only at Site 434 on the lower inner trench wall. Both exotic pebbles and carbonate nodule chips sometimes tend to be concentrated at particular levels of cores. Exotic pebbles are generally well rounded and consist of various rock types, such as dacite, andesite, basalt, tuff, gabbro, granodiorite, metaquartzite, biotite hornfels, lithic wacke, mudstone, etc., of which dacite occurs commonly at all the sites. Almost all pebbles at Site 436 and most at Sites 434 and 435 may have been rafted by ice. Some at the latter sites may have been derived by down-slope slumping. Carbonate nodules consist of microcrystalline dolomite, manganoan calcite, and siderite; CaCO3 content ranges from 22 to 65 per cent. They are also generally characterized by a high content of P2O5. The nodules are commonly rich in diatom remains, some of which indicate that the nodules are autochthonous. Some nodules contain abundant glass shards, with a modal refractive index of 1.499, almost identical to shards in the surrounding mud and ooze. These facts suggest that the carbonate nodules may have been formed diagenetically, in situ. This may throw light on problems of the formation of carbonate nodules in ancient "geosynclinal" sediments. It is also very important to point out that these carbonate nodules were formed within sediment deposited well below the CCD.

Products of chlorophyll diagenesis from DSDP Leg 57 Holes

Tetrapyrrole pigments isolated from sediments retrieved during Leg 57 include pheophytin-a, a myriad of chlorins, free-base deoxophylloerythroetioporphyrin (DPEP), as well as copper and nickel porphyrins. Their richness, both qualitatively and quantitatively, in chlorin tetrapyrroles affords a relatively complete study on the early diagenesis of chlorophyll. Our studies, coupled with those in the preceding chapter by Louda et al., point out the influence of pre- and postdepositional environments upon the mode of chlorophyll diagenesis. Formation of tetrapyrroles, collectively called "petroporphyrins," is seen to occur in only a limited set of environmental conditions (see Baker and Palmer, 1978). The more generalized route of chlorophyll diagenesis, at least in the ocean, results in removal of tetrapyrrole pigment, from the fossil record. Late diagenetic products, metalloporphyrins, are found to represent an extremely minor component of the tetrapyrrole assemblage in sediments studied from the Japan Trench. The products of chlorophyll diagenesis isolated from Japan Trench sediments allow expansion of previous diagenetic schemes (Baker and Palmer, 1978; Triebs, 1936) and indicate directions for future studies.

Geochemistry at DSDP Hole 57-439

Dating of a hornblende concentrate by the 40Ar/39Ar method gives an age of 23.4±5.5 m.y. for a dacite boulder from conglomerate in Deep Sea Drilling Project Hole 439. The conglomerate clasts range up to 1 meter in diameter and are nearly monolithologic, suggesting that a nearby former volcano erupted the dacite. The dacite is only 90 km landward from the Japan Trench, whereas modern trench-related volcanoes lie at least 120 km from their trenches. The dacite locality is on strike with and is probably an extension of a magmatic arc on the island of Hokkaido that crosses the Kuril arc at an angle of 65° and which was active 16 to 36 m.y. ago. The part of the former arc landward from the Kuril arc argues against an origin from a leaking subduction zone or from subduction of an active spreading ridge. The part seaward both from the Kuril and Japan arcs weakens an explanation based on migration of a trench-trenchtrench triple junction. The magmatic rocks probably formed along a middle-Tertiary plate boundary that had stepped seaward from a more-landward Cretaceous position. Later, the boundary stepped farther seaward at the Kuril arc and landward again at the Japan arc. If so, the present Japan subduction zone must have consumed most of the strata that had accumulated between it and the earlier trench.

Geochemistry at DSDP Hole 57-439

Acidic to intermediate volcanic rocks were obtained as boulders, pebbles, and clasts with intercalated matrix sediments near the Japan Trench. A 47.5-meter conglomerate bed unconformably overlies acoustic basement consisting of Upper Cretaceous siltstone and is overlain in turn by massive coarse-sandstone and siltstone beds with many fossil mollusks. The volcanic cobbles and boulders in the conglomerate show pronounced porphyritic texture. Their phenocrysts are plagioclase, hornblende, and biotite; the groundmass consists of plagioclase, K-feldspar, quartz, iron oxide, and altered interstitial glass. The Plagioclase content of these volcanic rocks is very high, whereas iron oxide minerals are rare. The chemical composition of these volcanic rocks was analyzed to determine the rock series. Matrix sediments were also analyzed chemically, and their chemical composition was found to be similar to that of volcanic rocks, except for a lower CaO content. SiO2 content of the volcanic rocks ranges from 60.23 to 73.90, corresponding to that of andesite to rhyolite. All the samples show extremely high Al2O3 content, which reflects the high amounts of modal plagioclase. These volcanic rocks belong to both the calc-alkalic and tholeiitic rock series, and the differentiation trend is controlled by fractional crystallization, mainly of plagioclase, K-feldspar, and hornblende. The assemblage of calc-alkalic and tholeiitic rock series is frequently observed in island arcs and active continental margins. These volcanic rocks are derived from the Oyashio ancient landmass, which is a slightly matured island arc.

Concentrations of major-element oxides and minor and trace elements at DSDP Legs 87, 57, 56 and 31

Sediments from Sites 582 (11 samples), 583 (19 samples), 584 (31 samples), 294 (1 sample), 296 (9 samples), 297 (3 samples), 436 (11 samples), and 439 (3 samples) were analyzed by X-ray fluorescence and/or instrumental neutron activation analysis. Ten major elements and 24 minor and trace elements (including 7 rare earth elements) were determined with these methods. Geochemistry varies systematically with both the site location and sediment age. Such variations are explained in terms of changes in sedimentation processes caused by plate motion and changes in ocean currents.