Chemical composition of bottom sediments at DSDP Sites 91-595 and 91-596 and ODP Sites 114-701 and 129-801

Subducted sediments play an important role in arc magmatism and crust-mantle recycling. Models of continental growth, continental composition, convergent margin magmatism and mantle heterogeneity all require a better understanding of the mass and chemical fluxes associated with subducting sediments. We have evaluated subducting sediments on a global basis in order to better define their chemical systematics and to determine both regional and global average compositions. We then use these compositions to assess the importance of sediments to arc volcanism and crust-mantle recycling, and to re-evaluate the chemical composition of the continental crust. The large variations in the chemical composition of marine sediments are for the most part linked to the main lithological constituents. The alkali elements (K, Rb and Cs) and high field strength elements (Ti, Nb, Hf, Zr) are closely linked to the detrital phase in marine sediments; Th is largely detrital but may be enriched in the hydrogenous Fe-Mn component of sediments; REE patterns are largely continental, but abundances are closely linked to fish debris phosphate; U is mostly detrital, but also dependent on the supply and burial rate of organic matter; Ba is linked to both biogenic barite and hydrothermal components; Sr is linked to carbonate phases. Thus, the important geochemical tracers follow the lithology of the sediments. Sediment lithologies are controlled in turn by a small number of factors: proximity of detrital sources (volcanic and continental); biological productivity and preservation of carbonate and opal; and sedimentation rate. Because of the link with lithology and the wealth of lithological data routinely collected for ODP and DSDP drill cores, bulk geochemical averages can be calculated to better than 30% for most elements from fewer than ten chemical analyses for a typical drill core (100-1000 m). Combining the geochemical systematics with convergence rate and other parameters permits calculation of regional compositional fluxes for subducting sediment. These regional fluxes can be compared to the compositions of arc volcanics to asses the importance of sediment subduction to arc volcanism. For the 70% of the trenches worldwide where estimates can be made, the regional fluxes also provide the basis for a global subducting sediment (GLOSS) composition and flux. GLOSS is dominated by terrigenous material (76 wt% terrigenous, 7 wt% calcium carbonate, 10 wt% opal, 7 wt% mineral-bound H2O+), and therefore similar to upper continental crust (UCC) in composition. Exceptions include enrichment in Ba, Mn and the middle and heavy REE, and depletions in detrital elements diluted by biogenic material (alkalis, Th, Zr, Hf). Sr and Pb are identical in GLOSS and UCC as a result of a balance between dilution and enrichment by marine phases. GLOSS and the systematics of marine sediments provide an independent approach to the composition of the upper continental crust for detrital elements. Significant discrepancies of up to a factor of two exist between the marine sediment data and current upper crustal estimates for Cs, Nb, Ta and Ti. Suggested revisions to UCC include Cs (7.3 ppm), Nb (13.7 ppm), Ta (0.96 ppm) and TiO2 (0.76 wt%). These revisions affect recent bulk continental crust estimates for La/Nb and U/Nb, and lead to an even greater contrast between the continents and mantle for these important trace element ratios. GLOSS and the regional sediment data also provide new insights into the mantle sources of oceanic basalts. The classical geochemical distinction between 'pelagic' and 'terrigenous' sediment sources is not valid and needs to be replaced by a more comprehensive understanding of the compositional variations in complete sedimentary columns. In addition, isotopic arguments based on surface sediments alone can lead to erroneous conclusions. Specifically, the Nd/Hf ratio of GLOSS relaxes considerably the severe constraints on the amount of sediment recycling into the mantle based on earlier estimates from surface sediment compositions.

Ice-rafted debris in sites of ODP Leg 114

All holes drilled during Leg 114 contained ice-rafted debris. Analysis of samples from Hole 699A, Site 701, and Hole 704A yielded a nearly complete history of ice-rafting episodes. The first influx of ice-rafted debris at Site 699, on the northeastern slope of the Northeast Georgia Rise, occurred at a depth of 69.94 m below seafloor (mbsf) in sediments of early Miocene age (23.54 Ma). This material is of the same type as later ice-rafted debris, but represents only a small percentage of the coarse fraction. Significant ice-rafting episodes occurred during Chron 5. Minor amounts of ice-rafted debris first reached Site 701, on the western flank of the Mid-Atlantic Ridge (8.78 Ma at 200.92 mbsf), and more arrived in the late Miocene (5.88 Ma). The first significant quantity of sand and gravel appeared at a depth of 107.76 mbsf (4.42 Ma). Site 704, on the southern part of the Meteor Rise, received very little or no ice-rafted debris prior to 2.46 Ma. At this time, however, the greatest influx of ice-rafted debris occurred at this site. This time of maximum ice rafting correlates reasonably well with influxes of ice-rafted debris at Sites 701 (2.24 Ma) and 699 (2.38 Ma), in consideration of sample spacing at these two sites. These peaks of ice rafting may be Sirius till equivalents, if the proposed Pliocene age of Sirius tills can be confirmed. After about 1.67 Ma, the apparent mass-accumulation rate of the sediments at Site 704 declined, but with major fluctuations. This decline may be the result of a decrease in the rate of delivery of detritus from Antarctica due to reduced erosive power of the glaciers or a northward shift in the Polar Front Zone, a change in the path taken by the icebergs, or any combination of these factors.

Diatom abundances in ODP Leg 114 holes

The practically continuous, paleomagnetically dated late Gauss-Brunhes sediment profiles of ODP Sites 699 and 701, south of the present Polar Front Zone (PFZ), and Site 704, north of the present PFZ, are used for a high-resolution study of abundance fluctuations of eight stratigraphic marker species in space and time. Ecological restrictions and preferences of the diatom species Hemidiscus karstenii, Actinocyclus ingens f. planus, Thalassiosira elliptipora, Thalassiosira kolbei, Thalassiosira vulnifica, Simonseniella barboi, Cosmiodiscus insignis, and Nitzschia weaveri are deduced. The ages of their first abundant appearance datums (FAAD), last-appearance datums (LAD), and last abundant appearance datums (LAAD) at the three sites are determined. The interpolated datum ages agree relatively well with those determined by other authors, if one interprets most of their LADs as LAADs. FAADs and LAADs produce more accurate datums than LADs. For the late Matuyama (younger than approximately 2.0 Ma), when PFZ fluctuations effected all three site sites, the datum ages determined agree within the methodically caused limits of accuracy for each datum. For the early Matuyama (older than approximately 2.0 Ma) the results can be interpreted as either that the ages of the FAAD of T. kolbei and LAAD of T. vulnifica datums determined at Sites 699 and 701 are more reliable or that these datums are diachronous between these two sites and Site 704. Such a diachroneity could be caused by different paleoceanographic conditions (stable subantarctic conditions over Site 704 and stable antarctic conditions over Sites 699 and 701). A few taxonomic changes were necessary. One new genus is defined (Simonseniella gen. nov.) and five new combinations are proposed: Simonseniella barboi (Brun) comb, nov., Simonseniella praebarboi (Schrader) comb, nov., Simonseniella curvirostris (Jousé) comb, nov., Thalassiosira elliptipora (Donahue) comb, nov., and Thalassiosira vulnifica (Gombos) comb. nov.