Stable oxygen isotope composition of planktonic foraminifera in the Canary Islands region

Seasonal depth stratified plankton tows, sediment traps and core tops taken from the same stations along a transect at 29°N off NW Africa are used to describe the seasonal succession, the depth habitats and the oxygen isotope ratios (delta18O(shell)) of five planktic foraminiferal species. Both the delta18O(shell) and shell concentration profiles show variations in seasonal depth habitats of individual species. None of the species maintain a specific habitat depth exclusively within the surface mixed layer (SML), within the thermocline, or beneath the thermocline. Globigerinoides ruber (white) and (pink) occur with moderate abundance throughout the year along the transect, with highest abundances in the winter and summer/fall season, respectively. The average delta18O(shell) of G. ruber (w) from surface sediments is similar to the delta18O(shell) values measured from the sediment-trap samples during winter. However, the delta18O(shell) of G. ruber (w) underestimates sea surface temperature (SST) by 2 °C in winter and by 4 °C during summer/fall indicating an extension of the calcification/depth habitat into colder thermocline waters. Globigerinoides ruber (p) continues to calcify below the SML as well, particularly in summer/fall when the chlorophyll maximum is found within the thermocline. Its vertical distribution results in delta18O(shell) values that underestimate SST by 2 °C. Shell fluxes of Globigerina bulloides are highest in summer/fall, where it lives and calcifies in association with the deep chlorophyll maximum found within the thermocline. Pulleniatina obliquiloculata and Globorotalia truncatulinoides, dwelling and calcifying a part of their lives in the winter SML, record winter thermocline (~180 m) and deep surface water (~350 m) temperatures, respectively. Our observations define the seasonal and vertical distribution of multiple species of foraminifera and the acquisition of their delta18O(shell).

Pore water measurements of sediment cores from the Helgoland mud area, North Sea

Iron reduction in subseafloor sulfate-depleted and methane-rich marine sediments is currently a subject of interest in subsurface geomicrobiology. While iron reduction and microorganisms involved have been well studied in marine surface sediments, little is known about microorganisms responsible for iron reduction in deep methanic sediments. Here, we used quantitative PCR (Q-PCR)-based 16S rRNA gene copy numbers and pyrosequencing-based relative abundances of bacteria and archaea to investigate covariance between distinct microbial populations and specific geochemical profiles in the top 5 m of sediment cores from the Helgoland mud area, North Sea. We found that gene copy numbers of bacteria and archaea were specifically higher around the peak of dissolved iron in the methanic zone (250-350 cm. The higher copy numbers at these depths were also reflected by the relative sequence abundances of members of the candidate division JS1, methanogenic and Methanohalobium/ANME-3 related archaea. The distribution of these populations was strongly correlated to the profile of pore-water Fe2+ while that of Desulfobacteraceae corresponded to the pore-water sulfate profile. Furthermore, specific JS1 populations also strongly co-varied with the distribution of Methanosaetaceae in the methanic zone. Our data suggest that the interplay among JS1 bacteria, methanogenic archaea and Methanohalobium/ANME-3-related archaea may be important for iron reduction and methane cycling in deep methanic sediments of the Helgoland mud area and perhaps in other methane-rich depositional environments. .

Cenozoic radiolaria in the western North Atlantic

Eight Cenozoic radiolarian zones were recognized in samples from two holes at Site 603, drilled on the lower continental rise off North America during Leg 93 of the Deep Sea Drilling Project. Paleocene to early Eocene radiolarian zones (Bekoma bidartensis, Buryella clinata, and Phormocyrtis striata striata zones) and early to late Miocene radiolarian zones (Calocycletta costata, Dorcadospyris alata, Diartus petterssoni, and Didymocyrtis antepenultima zones) were recognized in sediments from Holes 603 and 603B. In addition, a new Paleocene Bekoma campechensis radiolarian Zone is defined by the interval between the first morphotypic appearance of B. campechensis and the B. campechensis-B. bidartensis evolutionary transition. This zone is immediately below the B. bidartensis Zone of Foreman (1973), and has previously been discussed as a Paleocene "unnamed zone" by other investigators. A hiatus between Neogene and Paleogene sequences was also recognized in the radiolarian faunas.

Composition of recent carbonate bottom sediments from the Guiana shelf an off the West Africa

This work was based on a study of the upper layer of recent carbonate bottom sediments of the Atlantic Ocean. Biogenic carbonate of recent sediments is represented by metastable and stable minerals. In the ocean metastable phases can exist indefinitely long, but the structure of polymorphism determines inevitability of transformation of metastable phases into stable ones. This transformation occurs in the solid phase. In the absence of a critical point between the two phases of the transition process is not available for study by microscopic methods. It is estimated indirectly by studying the nature and extent of changes in mineral and chemical compositions. With aging of sediments their mineral composition alters in direction of increasing contents of resistant minerals. Fine grained sediments and fractions are subject to more intensive effects of early diagenesis processes, rather than coarse ones; this is reflected in their mineral composition. Regularities of distribution of carbonate minerals in size fractions consistent with the direction of polymorphic transformations in calcium carbonate. Such transformations can occur in a particular dimension of grains. Concrete grain size depends on environmental conditions. This situation explains presence of metastable biogenic carbonates at different depths of the ocean and suggests presence of diagenetic calcite in sediments occurring below expected for each case depth of the transition.

Lower Cretaceous nannofossils of ODP Holes 113-682B and 113-693A

Organic-rich, moderately to sparsely nannofossiliferous Lower Cretaceous claystones ("black shales") were cored at two Ocean Drilling Program Leg 113 sites on the continental slope of East Antarctica off Dronning Maud Land. A 39 m section at Site 692 yielded a Neocomian assemblage of limited diversity with rare Cyclagelosphaera deflandrei, Diadorhombus rectus, and Cruciellipsis cuvillieri, and is probably Valanginian in age. A 70-m section at Site 693 is assigned to the Rhagodiscus angustus Zone (late Aptian-early Albian in age). The latter zone is represented at DSDP sites on the Falkland Plateau, but equivalents to the Neocomian section are absent there, probably due to a disconformity. Watznaueria barnesae is the dominant species at both ODP sites, but it shares dominance with Repagulum parvidentatum at Site 693, where they total 70%-90% of the assemblage; their dominance is attributed to a paleogeographic setting within a restricted basin rather than to postdepositional dissolution of other species. The evolutionary development of this restricted basin and its eventual ventilation in early Albian times is discussed in terms of the regional stratigraphy and the breakup and dispersal of southwestern Gondwanaland. One new species, Corollithion covingtonii, is described.

Composition of sediments, rocks, and ores from the Northern and Equatorial Indian Ocean

The monograph has been written on the base of data obtained from samples and materials collected during the 19-th cruise of RV ''Akademik Vernadsky'' to the Northern and Equatorial Indian Ocean. Geological features of the region (stratigraphy, tectonic structure, lithology, distribution of ore-forming components in bottom sediments, petrography of igneous rocks, etc.) are under consideration. Regularities of trace element concentration in Fe-Mn nodules, nodule distribution in bottom sediments, and engineering-geological properties of sediments within the nodule fields have been studied. Much attention is paid to ocean crust rocks. The wide range of ore mineralization (magnetite, chromite, chalcopyrite, pyrite, pentlandite, and other minerals) has been ascertained.

Faunal turnovers in the central Pacific benthic foraminifera during the Paleocene-Eocene thermal maximum

Although it is well known that the Paleocene/Eocene thermal maximum (PETM) coincided with a major benthic foraminiferal extinction event, the detailed pattern of the faunal turnover has not yet been clarified. Our high-resolution benthic foraminiferal and carbon isotope analyses at the low latitude Pacific Ocean Shatsky Rise have revealed the following record of major faunal transitions: (1) An initial turnover which involved the benthic foraminiferal extinction event (BFE). The BFE, marked by a sharp transition from Pre-extinction fauna to Disaster fauna represented by small-sized Bolivina gracilis, expresses the onset of the PETM and the abrupt extinction of about 30% of taxa. This faunal transition lasted about 45-74 kyr after the initiation of the PETM and was followed by: (2) the appearance of Opportunistic fauna represented by Quadrimorphina profunda, which existed for about 74-91 kyr after the initiation of the PETM. These two faunas, which appeared after the extinction event, are characterized by low diversity and dwarfism, possibly due to lowered oxygen condition and decreased surface productivity. The second pronounced turnover involved the gradual recovery from Opportunistic Fauna to the establishment of Recovery fauna, which coincided with the recovery about 83-91 kyr after its initiation.

14C ages, grain size distribution and foraminifer abundance of sediments from the Barents Sea shelf

The origin of friable sediments blanketing the Barents Sea shelf is considered. It is shown that their characteristic seismoacoustic record patterns reflect low degree of diagenetic transformations and indicates continuous sedimentation. According to traditional views, this single sedimentary complex also includes diamicton, and the section is interpreted as a three-unit structure: diamicton, which is considered a till; the overlying friable sediments accumulated under different conditions of deglaciation in glaciomarine settings; and the postglacial marine sediments. It is demonstrated that such views are inconsistent with geomorphologic features (datings by physical methods included) indicating a prolonged hiatus that separates epochs of the diamicton accumulation and formation of friable sediments. The analysis revealed that the composition, vertical succession, and lateral distribution of different lithological types of friable sediments are related to the regular spatiotemporal replacements of different facies settings in the transgressing Arctic sea rather than by the glacial process. This inference is confirmed by the composition of foraminiferal assemblages.

Age determination and stable oxygen isotope record of ODP Hole 167-1017E

Oxygen isotopic (d18O) climatic stratigraphy and radiocarbon chronology, at high resolution, have been used to establish an age model for Ocean Drilling Program Hole 1017E, a continuous 25-m sequence of hemipelagic sediments from the continental slope (956 m water depth), east of Point Arguella, Southern California. The upper part of Hole 1017E from ~33 ka (7.445 mbsf) was dated using 13 calendar-corrected radiocarbon ages of mixed planktonic foraminiferal assemblages. Benthic oxygen isotopic stratigraphy records a continuous 130-k.y. sequence ranging from marine isotope Stage 6 to the present day. The benthic d18O curve, representing the last two interglacial and glacial cycles, closely resembles the well-dated, deep-sea reference sequence, providing a detailed chronologic framework. Sedimentation rates remained relatively constant throughout the sequence at ~18 cm/k.y. and were sufficiently rapid to provide considerable potential for high-resolution paleoceanographic/paleoclimatic investigations. Planktonic foraminiferal oxygen isotopic stratigraphy based on the surface-dwelling form Globigerina bulloides defines an almost complete sequence of interstadial/stadial oscillations (Dansgaard/Oeschger cycles [D/O]). Combined use of radiocarbon chronology, deep-sea oxygen isotopic datums, and visual pattern matching has enabled us to identify the sequence of D/O cycles as described for the Greenland (GRIP2) ice core. This has strengthened the stratigraphic framework for the last 60 k.y. in the sequence as a basis for further paleoenvironmental investigations.

Core alignment and composite depth scale of DSDP Site 86-577

Deep Sea Drilling Project Site 577 on Shatsky Rise (North Pacific Ocean) recovered a series of cores at three holes that contain calcareous nannofossil ooze of latest Cretaceous (late Maastrichtian) through early Eocene age. Several important records have been generated using samples from these cores, but the stratigraphy has remained outdated and confusing. Here we revise the stratigraphy at Site 577. This includes refining several age datums, realigning cores in the depth domain, and placing all stratigraphic markers on a current time scale. The work provides a template for appropriately bringing latest Cretaceous and Paleogene data sets at old drill sites into current paleoceanographic literature for this time interval. While the Paleocene Eocene Thermal Maximum (PETM) lies within core gaps at Holes 577* and 577A, the sedimentary record at the site holds other important events and remains crucially relevant to understanding changes in oceanographic conditions from the latest Cretaceous through early Paleogene.

Sedimentation patters in the eastern equatorial Pacific Ocean

The post-middle Miocene evolution of sedimentary patterns in the eastern equatorial Pacific Ocean has been deduced from a compilation and synthesis of CaCO3, opal, and nannofossil assemblage data from 11 sites drilled during Leg 138. Improvements in stratigraphic correlation and time scale development enabled the construction of lithostratigraphic and chronostratigraphic frameworks of exceptional quality. These frameworks, and the high sedimentation rates (often exceeding 4 cm/k.y.) provided a detailed and synoptic paleoceanographic view of a large and highly productive region. The three highlights that emerge are: (1) a middle late Miocene "carbonate crash" (Lyle et al., this volume); (2) a late Miocene-early Pliocene "biogenic bloom"; and (3) an early Pliocene "opal shift". During the carbonate crash, an interval of dissolution extending from -11.2 to 7.5 Ma, CaCO3 accumulation rates declined to near zero over much of the eastern equatorial Pacific, whereas opal accumulation rates remained substantially unchanged. The crash nadir, near 9.5 Ma, was marked by a brief shoaling of the regional carbonate compensation depth by more than 1400 m. The carbonate crash has been correlated over the entire tropical Pacific Ocean, and has been attributed to tectonically-induced changes in abyssal flow through the Panamanian seaway. The biogenic bloom extended from 6.7 to 4.5 Ma, and was characterized by an overall increase in biogenic accumulation and by a steepening of the latitudinal accumulation gradient toward the equator. The bloom has been observed over a large portion of the global ocean and has been linked to increased productivity. The final highlight, is a distinct and permanent shift in the locus of maximum opal mass accumulation rate at 4.4 Ma. This shift was temporally, and perhaps causally, linked to the final closure of the Panamanian seaway. Before 4.4 Ma, opal accumulation was greatest in the eastern equatorial Pacific Basin (near 0°N, 107°W). Since then, the highest opal fluxes in the equatorial Pacific have occurred in the Galapagos region (near 3°S, 92°W).

Distribution of planktonic foraminifera in the Southern Ocean (maps)

There are about 30 species of planktonic Foraminifera, as contrasted with the more than 4200 benthic species in the oceans of the world. Most of the planktonic species belong to the families Globigerinidae and Globorotaliidae. Of the 30 species, 9 occur in Antarctic and Subantarctic waters; however, none of these cold-water species are restricted to the Southern Ocean, except possibly the newly recognized Globorotalia cavernula (Be, 1967b). These species are distributed in broad zones of similar temperature in both the Northern and Southern Hemispheres. Hence, it is not possible to refer to these species as endemic to the Antarctic or Subantarctic, although some of them do appear in very high concentrations of 10 specimens/m**3 or more in the Antarctic regions. The plankton samples upon which the accompanying maps are based were collected between 1960 and 1965 on the research vessels Eltanin of the National Science Foundation (U.S. Antarctic Research Program), and Vema and Conrad of the Lamont Geological Observatory. All surface (0 m to 10 m) and vertical (0 m to 300 m) tows were obtained with plankton nets of uniform mesh size and material (NITEX202 = 202 µm mesh-aperture width) and were provided with flowmeters for quantitative readings of amounts of water filtered.

Stable isotope record during the past 1 Myr of ODP Site 162-980 in the subpolar North Atlantic

Benthic foraminiferal carbon isotope records from a suite of drill sites in the North Atlantic are used to trace variations in the relative strengths of Lower North Atlantic Deep Water (LNADW), Upper North Atlantic Deep Water (UNADW), and Southern Ocean Water (SOW) over the past 1 Myr. During glacial intervals, significant increases in intermediate-to-deep delta13C gradients (commonly reaching >1.2?) are consistent with changes in deep water circulation and associated chemical stratification. Bathymetric delta13C gradients covary with benthic foraminiferal delta18O and covary inversely with Vostok CO2, in agreement with chemical stratification as a driver of atmospheric CO2 changes. Three deep circulation indices based on delta13C show a phasing similar to North Atlantic sea surface temperatures, consistent with a Northern Hemisphere control of NADW/SOW variations. However, lags in the precession band indicate that factors other than deep water circulation control ice volume variations at least in this band.

Late Oligocene through early Pleistocene calcareous nannofossils of ODP Leg 115 holes

The chronostratigraphy, the calcareous nannofossil biochronology, and the biostratigraphy of the Miocene and Pliocene sediments retrieved during Leg 115 in the equatorial western Indian Ocean are presented and discussed. Most of the zonal boundaries of the standard 1971 zonation of Martini and the 1973 zonation of Bukry are easily recognized in these low-latitude sediments. We also comment on the secondary events that are proposed in the literature to improve the biostratigraphic resolution provided by the standard zonations. The study of calcareous nannofossil biostratigraphy and taphonomy of sequences from the Northern Mascarene Plateau area, which was drilled to investigate the Neogene history of carbonate flux and dissolution, indicate that the accumulation of carbonates in this area results from a complex interplay among carbonate bioproductivity, carbonate removal by chemical dissolution and mechanical erosion, and carbonate addition by mass and current transport. In spite of these drawbacks, major changes and trends in carbonate accumulation can be recognized, most of which, if not all, correlate with major steps in the evolution of the Neogene climatic system.